Abstract
Because of their ultrathin thickness, two-dimensional (2D) materials exhibit unique properties in different fields, such as electronics and catalysis. As one of these materials, a 2D magnet is an ideal platform for fundamental physics research and magnetic device development, making it widely studied. This review provides the details of recent progress of 2D magnetic materials. First, the characterization methods of magnetism are summarized. Then, the categories of 2D magnets and the strategies for regulating 2D magnetism are discussed. Finally, the challenges and opportunities in 2D magnetic material development are pointed out.
Zh
摘要二维材料依靠其超薄的厚度在诸多领域中展现出独特的性能, 如电子学和催化领域. 作为二维材料中的一员, 二维磁性材料是物理学基础研究和磁性器件发展的理想平台. 因此, 二维磁性材料受到了广泛的关注和研究. 本文综述了二维磁性材料的研究进展, 总结了磁性的表征方法, 讨论了常见的二维磁性材料的分类及对二维磁性调控的方法, 并介绍了二维磁性材料的应用. 最后, 展望了二维磁性材料在未来发展中将面临的挑战和机遇.
Similar content being viewed by others
References
Novoselov KS, Geim AK, Morozov SV, et al. Electric field effect in atomically thin carbon films. Science, 2004, 306: 666–669
Manzeli S, Ovchinnikov D, Pasquier D, et al. 2D transition metal dichalcogenides. Nat Rev Mater, 2017, 2: 17033
Lv L, Yang Z, Chen K, et al. 2D layered double hydroxides for oxygen evolution reaction: From fundamental design to application. Adv Energy Mater, 2019, 9: 1803358
Zhang K, Feng Y, Wang F, et al. Two dimensional hexagonal boron nitride (2D-hBN): Synthesis, properties and applications. J Mater Chem C, 2017, 5: 11992–12022
Thurakkal S, Zhang X. Recent advances in chemical functionalization of 2D black phosphorous nanosheets. Adv Sci, 2020, 7: 1902359
Wang Y, Liu L, Ma T, et al. 2D graphitic carbon nitride for energy conversion and storage. Adv Funct Mater, 2021, 31: 2102540
Xiao X, Song H, Lin S, et al. Scalable salt-templated synthesis of two-dimensional transition metal oxides. Nat Commun, 2016, 7: 11296
Wei Y, Zhang P, Soomro RA, et al. Advances in the synthesis of 2D MXenes. Adv Mater, 2021, 33: 2103148
Fiori G, Bonaccorso F, Iannaccone G, et al. Electronics based on two-dimensional materials. Nat Nanotech, 2014, 9: 768–779
Li X, Tao L, Chen Z, et al. Graphene and related two-dimensional materials: Structure-property relationships for electronics and optoelectronics. Appl Phys Rev, 2017, 4: 021306
Deng D, Novoselov KS, Fu Q, et al. Catalysis with two-dimensional materials and their heterostructures. Nat Nanotech, 2016, 11: 218–230
Zhang X, Hou L, Ciesielski A, et al. 2D materials beyond graphene for high-performance energy storage applications. Adv Energy Mater, 2016, 6: 1600671
Kim J, Lee Y, Kang M, et al. 2D materials for skin-mountable electronic devices. Adv Mater, 2021, 33: 2005858
An J, Zhao X, Zhang Y, et al. Perspectives of 2D materials for optoelectronic integration. Adv Funct Mater, 2022, 32: 2110119
Shifa TA, Wang F, Liu Y, et al. Heterostructures based on 2D materials: A versatile platform for efficient catalysis. Adv Mater, 2019, 31: 1804828
Lin L, Chen J, Liu D, et al. Engineering 2D materials: A viable pathway for improved electrochemical energy storage. Adv Energy Mater, 2020, 10: 2002621
Hao Q, Dai H, Cai M, et al. 2D magnetic heterostructures and emergent spintronic devices. Adv Elect Mater, 2022, 8: 2200164
Li H, Ruan S, Zeng YJ. Intrinsic van der Waals magnetic materials from bulk to the 2D limit: New frontiers of spintronics. Adv Mater, 2019, 31: 1900065
Zhang K, Han S, Lee Y, et al. Gigantic current control of coercive field and magnetic memory based on nanometer-thin ferromagnetic van der Waals Fe3GeTe2. Adv Mater, 2021, 33: 2004110
Kumari S, Pradhan DK, Pradhan NR, et al. Recent developments on 2D magnetic materials: Challenges and opportunities. emergent mater, 2021, 4: 827–846
Hossain M, Qin B, Li B, et al. Synthesis, characterization, properties and applications of two-dimensional magnetic materials. Nano Today, 2022, 42: 101338
Li W, Qiu X, Lv B, et al. Free-standing 2D ironene with magnetic vortex structure at room temperature. Matter, 2022, 5: 291–301
Zhang L, Zhou J, Li H, et al. Recent progress and challenges in magnetic tunnel junctions with 2D materials for spintronic applications. Appl Phys Rev, 2021, 8: 021308
Hu J, Luo J, Zheng Y, et al. Magnetic proximity effect at the interface of two-dimensional materials and magnetic oxide insulators. J Alloys Compd, 2022, 911: 164830
Idzuchi H, Pientka F, Huang KF, et al. Unconventional supercurrent phase in Ising superconductor Josephson junction with atomically thin magnetic insulator. Nat Commun, 2021, 12: 5332
Hu T, Zhao G, Gao H, et al. Manipulation of valley pseudospin in WSe2/CrI3 heterostructures by the magnetic proximity effect. Phys Rev B, 2020, 101: 125401
Tu Z, Zhou T, Ersevim T, et al. Spin-orbit coupling proximity effect in MoS2/Fe3GeTe2 heterostructures. Appl Phys Lett, 2022, 120: 043102
Fu H, Liu CX, Yan B. Exchange bias and quantum anomalous Hall effect in the MnBi2Te4/CrI3 heterostructure. Sci Adv, 2020, 6: eaaz0948
Mermin ND, Wagner H. Absence of ferromagnetism or antiferromagnetism in one- or two-dimensional isotropic Heisenberg models. Phys Rev Lett, 1966, 17: 1133–1136
Gong C, Li L, Li Z, et al. Discovery of intrinsic ferromagnetism in two-dimensional van der Waals crystals. Nature, 2017, 546: 265–269
Huang B, Clark G, Navarro-Moratalla E, et al. Layer-dependent ferromagnetism in a van der Waals crystal down to the monolayer limit. Nature, 2017, 546: 270–273
Yang X, Zhou X, Feng W, et al. Tunable magneto-optical effect, anomalous Hall effect, and anomalous Nernst effect in the two-dimensional room-temperature ferromagnet 1T-CrTe2. Phys Rev B, 2021, 103: 024436
Yu Z, Xia W, Xu K, et al. Pressure-induced structural phase transition and a special amorphization phase of two-dimensional ferromagnetic semiconductor Cr2Ge2Te6. J Phys Chem C, 2019, 123: 13885–13891
Ferrenti AM, Klemenz S, Lei S, et al. Change in magnetic properties upon chemical exfoliation of FeOCl. Inorg Chem, 2020, 59: 1176–1182
Sekine T, Jouanne M, Julien C, et al. Light-scattering study of dynamical behavior of antiferromagnetic spins in the layered magnetic semiconductor FePS3. Phys Rev B, 1990, 42: 8382–8393
Mak KF, Shan J, Ralph DC. Probing and controlling magnetic states in 2D layered magnetic materials. Nat Rev Phys, 2019, 1: 646–661
Gong C, Zhang X. Two-dimensional magnetic crystals and emergent heterostructure devices. Science, 2019, 363: eaav4450
Song T, Cai X, Tu MWY, et al. Giant tunneling magnetoresistance in spin-filter van der Waals heterostructures. Science, 2018, 360: 1214–1218
Song T, Fei Z, Yankowitz M, et al. Switching 2D magnetic states via pressure tuning of layer stacking. Nat Mater, 2019, 18: 1298–1302
Lin X, Yang W, Wang KL, et al. Two-dimensional spintronics for low-power electronics. Nat Electron, 2019, 2: 274–283
Liu S, Yuan X, Zou Y, et al. Wafer-scale two-dimensional ferromagnetic Fe3GeTe2 thin films grown by molecular beam epitaxy. npj 2D Mater Appl, 2017, 1: 30
Zhong D, Seyler KL, Linpeng X, et al. Van der Waals engineering of ferromagnetic semiconductor heterostructures for spin and valley-tronics. Sci Adv, 2017, 3: e1603113
Stephens PJ. Magnetic circular dichroism. Annu Rev Phys Chem, 1974, 25: 201–232
Mason WR. Magnetic Circular Dichroism Spectroscopy. Hoboken: John Wiley & Sons, 2007
Jiang S, Shan J, Mak KF. Electric-field switching of two-dimensional van der Waals magnets. Nat Mater, 2018, 17: 406–410
Wang M, Kang L, Su J, et al. Two-dimensional ferromagnetism in CrTe flakes down to atomically thin layers. Nanoscale, 2020, 12: 16427–16432
Huang B, Clark G, Klein DR, et al. Electrical control of 2D magnetism in bilayer CrI3. Nat Nanotech, 2018, 13: 544–548
Jones RR, Hooper DC, Zhang L, et al. Raman techniques: Fundamentals and frontiers. Nanoscale Res Lett, 2019, 14: 231
Kim K, Lee JU, Cheong H. Raman spectroscopy of two-dimensional magnetic van der Waals materials. Nanotechnology, 2019, 30: 452001
Sethi A, Byrum T, McAuliffe RD, et al. Magnons and magnetodielectric effects in CoCr2O4: Raman scattering studies. Phys Rev B, 2017, 95: 174413
Byrum T, Gleason SL, Thaler A, et al. Effects of magnetic field and twin domains on magnetostructural phase mixture in Mn3O4: Raman scattering studies of untwinned crystals. Phys Rev B, 2016, 93: 184418
Rovillain P, Cazayous M, Gallais Y, et al. Magnetic field induced dehybridization of the electromagnons in multiferroic TbMnO3. Phys Rev Lett, 2011, 107: 027202
Lee JU, Lee S, Ryoo JH, et al. Ising-type magnetic ordering in atomically thin FePS3. Nano Lett, 2016, 16: 7433–7438
Tian Y, Gray MJ, Ji H, et al. Magneto-elastic coupling in a potential ferromagnetic 2D atomic crystal. 2D Mater, 2016, 3: 025035
McCreary A, Simpson JR, Mai TT, et al. Quasi-two-dimensional magnon identification in antiferromagnetic FePS3via magneto-Raman spectroscopy. Phys Rev B, 2020, 101: 064416
Shen YR. Optical second harmonic generation at interfaces. Annu Rev Phys Chem, 1989, 40: 327–350
Fiebig M, Pavlov VV, Pisarev RV. Second-harmonic generation as a tool for studying electronic and magnetic structures of crystals: Review. J Opt Soc Am B, 2005, 22: 96–118
Sun Z, Yi Y, Song T, et al. Giant nonreciprocal second-harmonic generation from antiferromagnetic bilayer CrI3. Nature, 2019, 572: 497–501
Aoki T. Photoluminescence Spectroscopy. In: Characterization of Materials, Hoboken: John Wiley & Sons, Inc., 2012: 1–12
Pavliuk MV, Fernandes DLA, El-Zohry AM, et al. Magnetic manipulation of spontaneous emission from inorganic CsPbBr3 perovskites nanocrystals. Adv Opt Mater, 2016, 4: 2004–2008
Qi Z, Sheng F, Zhu L, et al. Annealing effects on Cd0.96Zn0.04Te crystals with Te inclusions probed by photoluminescence spectroscopy. Phys Status Solidi B, 2016, 253: 1612–1615
Seyler KL, Zhong D, Klein DR, et al. Ligand-field helical luminescence in a 2D ferromagnetic insulator Nat Phys, 2018, 14: 277–281
Zhang Z, Shang J, Jiang C, et al. Direct photoluminescence probing of ferromagnetism in monolayer two-dimensional CrBr3. Nano Lett, 2019, 19: 3138–3142
Onoda S, Sugimoto N, Nagaosa N. Intrinsic versus extrinsic anomalous Hall effect in ferromagnets. Phys Rev Lett, 2006, 97: 126602
Lee WL, Watauchi S, Miller VL, et al. Dissipationless anomalous Hall current in the ferromagnetic spinel CuCr2Se4−xBrx. Science, 2004, 303: 1647–1649
Zeng C, Yao Y, Niu Q, et al. Linear magnetization dependence of the intrinsic anomalous Hall effect. Phys Rev Lett, 2006, 96: 037204
Chang CZ, Zhang J, Liu M, et al. Thin films of magnetically doped topological insulator with carrier-independent long-range ferromagnetic order. Adv Mater, 2013, 25: 1065–1070
Tan C, Lee J, Jung SG, et al. Hard magnetic properties in nanoflake van der Waals Fe3GeTe2. Nat Commun, 2018, 9: 1554
Inoue J, Maekawa S. Theory of tunneling magnetoresistance in granular magnetic films. Phys Rev B, 1996, 53: R11927–R11929
Wang Z, Sapkota D, Taniguchi T, et al. Tunneling spin valves based on Fe3GeTe2/hBN/Fe3GeTe2 van der Waals heterostructures. Nano Lett, 2018, 18: 4303–4308
Wang W, Narayan A, Tang L, et al. Spin-valve effect in NiFe/MoS2/NiFe junctions. Nano Lett, 2015, 15: 5261–5267
Iqbal MZ, Iqbal MW, Siddique S, et al. Room temperature spin valve effect in NiFe/WS2/Co junctions. Sci Rep, 2016, 6: 21038
Gibson GA, Schultz S. Magnetic force microscope study of the micromagnetics of submicrometer magnetic particles. J Appl Phys, 1993, 73: 4516–4521
Serri M, Cucinotta G, Poggini L, et al. Enhancement of the magnetic coupling in exfoliated CrCl3 crystals observed by low-temperature magnetic force microscopy and X-ray magnetic circular dichroism. Adv Mater, 2020, 32: 2000566
Guo T, Ma Z, Luo X, et al. Multiple domain structure and symmetry types in narrow temperature and magnetic field ranges in layered Cr2Ge2Te6 crystal measured by magnetic force microscope. Mater Charact, 2021, 173: 110913
Mukasa K, Sueoka K, Hasegawa H, et al. Spin-polarized STM and its family. Mater Sci Eng-B, 1995, 31: 69–76
Chen W, Sun Z, Wang Z, et al. Direct observation of van der Waals stacking-dependent interlayer magnetism. Science, 2019, 366: 983–987
Trainer C, Armitage OR, Lane H, et al. Relating spin-polarized STM imaging and inelastic neutron scattering in the van der Waals ferromagnet Fe3GeTe2. Phys Rev B, 2022, 106: L081405
Rondin L, Tetienne JP, Hingant T, et al. Magnetometry with nitrogen-vacancy defects in diamond. Rep Prog Phys, 2014, 77: 056503
Acosta VM, Bauch E, Ledbetter MP, et al. Diamonds with a high density of nitrogen-vacancy centers for magnetometry applications. Phys Rev B, 2009, 80: 115202
Casola F, van der Sar T, Yacoby A. Probing condensed matter physics with magnetometry based on nitrogen-vacancy centres in diamond. Nat Rev Mater, 2018, 3: 17088
Thiel L, Wang Z, Tschudin MA, et al. Probing magnetism in 2D materials at the nanoscale with single-spin microscopy. Science, 2019, 364: 973–976
Fan C, Zamick L. The sturdiness of the shell model: Informal review. 2022, arXiv:2201.13247
Yusuf SM, Kumar A. Neutron scattering of advanced magnetic materials. Appl Phys Rev, 2017, 4: 031303
Rietveld HM. A profile refinement method for nuclear and magnetic structures. J Appl Crystlogr, 1969, 2: 65–71
Halder M, Yusuf SM, Kumar A, et al. Crossover from antiferromagnetic to ferromagnetic ordering in the semi-Heusler alloys Cu1−xNixMnSb with increasing Ni concentration. Phys Rev B, 2011, 84: 094435
Yusuf SM, Chakraborty KR, Kumar A, et al. Magnetic ordering: Neutron diffraction and depolarization studies at Dhruva reactor. Neutron News, 2014, 25: 22–25
Hellman F, Hoffmann A, Tserkovnyak Y, et al. Interface-induced phenomena in magnetism. Rev Mod Phys, 2017, 89: 025006
Granata C, Vettoliere A. Nano superconducting quantum interference device: A powerful tool for nanoscale investigations. Phys Rep, 2016, 614: 1–69
Martínez-Pérez MJ, Koelle D. NanoSQUIDs: Basics & recent advances. Phys Sci Rev, 2017, 2: 5001
Wernsdorfer W. From micro- to nano-SQUIDs: Applications to nanomagnetism. Supercond Sci Technol, 2009, 22: 064013
Berger J. The stationary SQUID. J Low Temp Phys, 2018, 191: 330–343
Tomar S, Ghosh B, Mardanya S, et al. Intrinsic magnetism in monolayer transition metal trihalides: A comparative study. J Magn Magn Mater, 2019, 489: 165384
McGuire M. Crystal and magnetic structures in layered, transition metal dihalides and trihalides. Crystals, 2017, 7: 121
Soriano D, Katsnelson MI, Fernández-Rossier J. Magnetic two-dimensional chromium trihalides: A theoretical perspective. Nano Lett, 2020, 20: 6225–6234
Klein DR, MacNeill D, Song Q, et al. Enhancement of interlayer exchange in an ultrathin two-dimensional magnet. Nat Phys, 2019, 15: 1255–1260
Xue F, Hou Y, Wang Z, et al. Two-dimensional ferromagnetic van der Waals CrCl3 monolayer with enhanced anisotropy and Curie temperature. Phys Rev B, 2019, 100: 224429
Huang C, Zhou J, Wu H, et al. Quantum anomalous Hall effect in ferromagnetic transition metal halides. Phys Rev B, 2017, 95: 045113
Hirakawa K, Kadowaki H, Ubukoshi K. Study of frustration effects in two-dimensional triangular lattice antiferromagnets-neutron powder diffraction study of VX2, X≡Cl, Br and I. J Phys Soc Jpn, 1983, 52: 1814–1824
Abdul Wasey AHM, Karmakar D, Das GP. Frustrated non-collinearity in the magnetic behaviour of layered VX2 [X = Cl, Br, I] systems. AIP Conf Proc, 2013, 1512: 1114–1115
Tang H, Huang Y, Yuan H, et al. Layered TiCl2 monolayer as an antiferromagnetic semiconductor. SPIN, 2022, 12: 2250004
Prayitno TB, Ishii F. First-principles study of spiral spin density waves in monolayer MnCl2 using generalized bloch theorem. J Phys Soc Jpn, 2019, 88: 104705
Zhou X, Brzostowski B, Durajski A, et al. Atomically thin 1T-FeCl2 grown by molecular-beam epitaxy. J Phys Chem C, 2020, 124: 9416–9423
Botana AS, Norman MR. Electronic structure and magnetism of transition metal dihalides: Bulk to monolayer. Phys Rev Mater, 2019, 3: 044001
Lu M, Yao Q, Xiao C, et al. Mechanical, electronic, and magnetic properties of NiX2 (X = Cl, Br, I) layers. ACS Omega, 2019, 4: 5714–5721
Wang S, Wang J, Khazaei M. Discovery of stable and intrinsic antiferromagnetic iron oxyhalide monolayers. Phys Chem Chem Phys, 2020, 22: 11731–11739
Feng Y, Peng R, Dai Y, et al. Antiferromagnetic ferroelastic multiferroics in single-layer VOX (X = Cl, Br) predicted from first-principles. Appl Phys Lett, 2021, 119: 173103
Xu S, Jia F, Zhao G, et al. A two-dimensional ferroelectric ferromagnetic half semiconductor in a VOF monolayer. J Mater Chem C, 2021, 9: 9130–9136
Miao N, Xu B, Zhu L, et al. 2D intrinsic ferromagnets from van der Waals antiferromagnets. J Am Chem Soc, 2018, 140: 2417–2420
Xu C, Zhang J, Guo Z, et al. A first-principles study on the electronic property and magnetic anisotropy of ferromagnetic CrOF and CrOCl monolayers. J Phys-Condens Matter, 2021, 33: 195804
Zhang Y, Chu J, Yin L, et al. Ultrathin magnetic 2D single-crystal CrSe. Adv Mater, 2019, 31: 1900056
Li N, Zhu L, Shang H, et al. Controlled synthesis and Raman study of a 2D antiferromagnetic p-type semiconductor: α-MnSe. Nanoscale, 2021, 13: 6953–6964
Zou J, Yang Y, Hu D, et al. Controlled growth of ultrathin ferromagnetic β-MnSe semiconductor. SmartMat, 2022, 3: 482–490
Kriegner D, Výborný K, Olejník K, et al. Multiple-stable anisotropic magnetoresistance memory in antiferromagnetic MnTe. Nat Commun, 2016, 7: 11623
Kim W, Park IJ, Kim HJ, et al. Room-temperature ferromagnetic property in MnTe semiconductor thin film grown by molecular beam epitaxy. IEEE Trans Magn, 2009, 45: 2424–2427
Liang F, Wang C, Luo C, et al. Ferromagnetic CoSe broadband photodetector at room temperature. Nanotechnology, 2020, 31: 374002
Kang L, Ye C, Zhao X, et al. Phase-controllable growth of ultrathin 2D magnetic FeTe crystals. Nat Commun, 2020, 11: 3729
Gan LY, Zhang Q, Cheng Y, et al. Two-dimensional ferromagnet/semiconductor transition metal dichalcogenide contacts: p-type Schottky barrier and spin-injection control. Phys Rev B, 2013, 88: 235310
Ma Y, Dai Y, Guo M, et al. Evidence of the existence of magnetism in pristine VX2 monolayers (X = S, Se) and their strain-induced tunable magnetic properties. ACS Nano, 2012, 6: 1695–1701
Li B, Wan Z, Wang C, et al. Van der Waals epitaxial growth of air-stable CrSe2 nanosheets with thickness-tunable magnetic order. Nat Mater, 2021, 20: 818–825
Meng L, Zhou Z, Xu M, et al. Anomalous thickness dependence of Curie temperature in air-stable two-dimensional ferromagnetic 1T-CrTe2 grown by chemical vapor deposition. Nat Commun, 2021, 12: 809
Kan M, Adhikari S, Sun Q. Ferromagnetism in MnX2 (X = S, Se) monolayers. Phys Chem Chem Phys, 2014, 16: 4990–4994
Chen W, Zhang J, Nie Y, et al. Tuning magnetic properties of single-layer MnTe2via strain engineering. J Phys Chem Solids, 2020, 143: 109489
Cui F, Zhao X, Xu J, et al. Controlled growth and thickness-dependent conduction-type transition of 2D ferrimagnetic Cr2S3 semiconductors. Adv Mater, 2020, 32: 1905896
Zhu X, Liu H, Liu L, et al. Spin glass state in chemical vapor-deposited crystalline Cr2Se3 nanosheets. Chem Mater, 2021, 33: 3851–3858
Wen Y, Liu Z, Zhang Y, et al. Tunable room-temperature ferromagnetism in two-dimensional Cr2Te3. Nano Lett, 2020, 20: 3130–3139
Chua R, Zhou J, Yu X, et al. Room temperature ferromagnetism of monolayer chromium telluride with perpendicular magnetic anisotropy. Adv Mater, 2021, 33: 2103360
Kurita N, Nakao K. Band structures and physical properties of magnetic layered semiconductors MPS3. J Phys Soc Jpn, 1989, 58: 610–621
Ouvrard G, Brec R, Rouxel J. Structural determination of some MPS3 layered phases (M = Mn, Fe, Co, Ni and Cd). Mater Res Bull, 1985, 20: 1181–1189
Wang YM, Zhang JF, Li CH, et al. Raman scattering study of magnetic layered MPS3 crystals (M = Mn, Fe, Ni). Chin Phys B, 2019, 28: 056301
Liu Q, Wang L, Fu Y, et al. Magnetic order in XY-type antiferromagnetic monolayer CoPS33 revealed by Raman spectroscopy. Phys Rev B, 2021, 103: 235411
Kim K, Lim SY, Lee JU, et al. Suppression of magnetic ordering in XXZ-type antiferromagnetic monolayer NiPS3. Nat Commun, 2019, 10: 345
Kim K, Lim SY, Kim J, et al. Antiferromagnetic ordering in van der Waals 2D magnetic material MnPS3 probed by Raman spectroscopy. 2D Mater, 2019, 6: 041001
Zhuang HL, Zhou J. Density functional theory study of bulk and single-layer magnetic semiconductor CrPS4. Phys Rev B, 2016, 94: 195307
Baranava MS, Hvazdouski DC, Skachkova VA, et al. Magnetic interactions in Cr2Ge2Te6 and Cr2Si2Te6 monolayers: Ab initio study. Mater Today-Proc, 2020, 20: 342–347
Lin MW, Zhuang HL, Yan J, et al. Ultrathin nanosheets of CrSiTe3: A semiconducting two-dimensional ferromagnetic material. J Mater Chem C, 2016, 4: 315–322
Roemer R, Liu C, Zou K. Robust ferromagnetism in wafer-scale monolayer and multilayer Fe3GeTe2. npj 2D Mater Appl, 2020, 4: 33
Yang X, Zhou X, Feng W, et al. Strong magneto-optical effect and anomalous transport in the two-dimensional van der Waals magnets FenGeTe2 (n = 3, 4, 5). Phys Rev B, 2021, 104: 104427
Yan JQ, Liu YH, Parker DS, et al. A-type antiferromagnetic order in MnBi4Te7 and MnBi6Te10 single crystals. Phys Rev Mater, 2020, 4: 054202
Li J, Li Y, Du S, et al. Intrinsic magnetic topological insulators in van der Waals layered MnBi2Te4-family materials. Sci Adv, 2019, 5: eaaw5685
Li Y, Jiang Z, Li J, et al. Magnetic anisotropy of the two-dimensional ferromagnetic insulator MnBi2Te4. Phys Rev B, 2019, 100: 134438
Jiang S, Li L, Wang Z, et al. Controlling magnetism in 2D CrI3 by electrostatic doping. Nat Nanotech, 2018, 13: 549–553
Ren W, Jin K, Wang J, et al. Tunable electronic structure and magnetic anisotropy in bilayer ferromagnetic semiconductor Cr2Ge2Te6. Sci Rep, 2021, 11: 2744
Wang Z, Zhang T, Ding M, et al. Electric-field control of magnetism in a few-layered van der Waals ferromagnetic semiconductor. Nat Nanotech, 2018, 13: 554–559
Deng Y, Yu Y, Song Y, et al. Gate-tunable room-temperature ferromagnetism in two-dimensional Fe3GeTe2. Nature, 2018, 563: 94–99
Wang N, Tang H, Shi M, et al. Transition from ferromagnetic semiconductor to ferromagnetic metal with enhanced Curie temperature in Cr2Ge2Te6via organic ion intercalation. J Am Chem Soc, 2019, 141: 17166–17173
Zhang L, Tang C, Sanvito S, et al. Hydrogen-intercalated 2D magnetic bilayer: Controlled magnetic phase transition and half-metallicity via ferroelectric switching. ACS Appl Mater Interfaces, 2022, 14: 1800–1806
Li T, Jiang S, Sivadas N, et al. Pressure-controlled interlayer magnetism in atomically thin CrI3. Nat Mater, 2019, 18: 1303–1308
Ci W, Yang H, Xue W, et al. Thickness-dependent and strain-tunable magnetism in two-dimensional van der Waals VSe2. Nano Res, 2022, 15: 7597–7603
Wang Y, Wang C, Liang SJ, et al. Strain-sensitive magnetization reversal of a van der Waals magnet. Adv Mater, 2020, 32: 2004533
Wang H, Xu R, Liu C, et al. Pressure-dependent intermediate magnetic phase in thin Fe3GeTe2 flakes. J Phys Chem Lett, 2020, 11: 7313–7319
Dong XJ, You JY, Gu B, et al. Strain-induced room-temperature ferromagnetic semiconductors with large anomalous Hall conductivity in two-dimensional Cr2Ge2Se6. Phys Rev Appl, 2019, 12: 014020
Gu Y, Zhang S, Zou X. Tunable magnetism in layered CoPS3 by pressure and carrier doping. Sci China Mater, 2021, 64: 673–682
Dolui K, Petrović MD, Zollner K, et al. Proximity spin-orbit torque on a two-dimensional magnet within van der Waals heterostructure: Current-driven antiferromagnet-to-ferromagnet reversible nonequilibrium phase transition in bilayer CrI3. Nano Lett, 2020, 20: 2288–2295
Zhang L, Huang X, Dai H, et al. Proximity-coupling-induced significant enhancement of coercive field and curie temperature in 2D van der Waals heterostructures. Adv Mater, 2020, 32: 2002032
Idzuchi H, Llacsahuanga Allcca AE, Pan XC, et al. Increased Curie temperature and enhanced perpendicular magneto anisotropy of Cr2 Ge2Te6/NiO heterostructures. Appl Phys Lett, 2019, 115: 232403
Stanciu CD, Hansteen F, Kimel AV, et al. All-optical magnetic recording with circularly polarized light. Phys Rev Lett, 2007, 99: 047601
Zhang P, Chung TF, Li Q, et al. All-optical switching of magnetization in atomically thin CrI3. Nat Mater, 2022, 21: 1373–1378
Kim HH, Yang B, Patel T, et al. One million percent tunnel magnetoresistance in a magnetic van der Waals heterostructure. Nano Lett, 2018, 18: 4885–4890
Klein DR, MacNeill D, Lado JL, et al. Probing magnetism in 2D van der Waals crystalline insulators via electron tunneling. Science, 2018, 360: 1218–1222
Jiang S, Li L, Wang Z, et al. Spin tunnel field-effect transistors based on two-dimensional van der Waals heterostructures. Nat Electron, 2019, 2: 159–163
Worledge DC, Geballe TH. Magnetoresistive double spin filter tunnel junction. J Appl Phys, 2000, 88: 5277–5279
Lado JL, Fernández-Rossier J. On the origin of magnetic anisotropy in two dimensional CrI3. 2D Mater, 2017, 4: 035002
Irkhin VY, Katanin AA. Kosterlitz-Thouless and magnetic transition temperatures in layered magnets with a weak easy-plane anisotropy. Phys Rev B, 1999, 60: 2990–2993
McGuire MA, Dixit H, Cooper VR, et al. Coupling of crystal structure and magnetism in the layered, ferromagnetic insulator CrI3. Chem Mater, 2015, 27: 612–620
Wang X, Du K, Fredrik Liu YY, et al. Raman spectroscopy of atomically thin two-dimensional magnetic iron phosphorus trisulfide (FePS3) crystals. 2D Mater, 2016, 3: 031009
Alghamdi M, Lohmann M, Li J, et al. Highly efficient spin-orbit torque and switching of layered ferromagnet Fe3GeTe2. Nano Lett, 2019, 19: 4400–4405
Buzdin AI. Proximity effects in superconductor-ferromagnet heterostructures. Rev Mod Phys, 2005, 77: 935–976
Lee C, Katmis F, Jarillo-Herrero P, et al. Direct measurement of proximity-induced magnetism at the interface between a topological insulator and a ferromagnet. Nat Commun, 2016, 7: 12014
Tong Q, Liu F, Xiao J, et al. Skyrmions in the moiré of van der Waals 2D magnets. Nano Lett, 2018, 18: 7194–7199
Ding B, Li Z, Xu G, et al. Observation of magnetic skyrmion bubbles in a van der Waals ferromagnet Fe3GeTe2. Nano Lett, 2020, 20: 868–873
Seyler KL, Zhong D, Huang B, et al. Valley manipulation by optically tuning the magnetic proximity effect in WSe2/CrI3 heterostructures. Nano Lett, 2018, 18: 3823–3828
Acknowledgements
This work was financially supported by the National Natural Science Foundation of China (22175184 and 22105207).
Author information
Authors and Affiliations
Contributions
Author contributions Dai C summarized the literature and wrote the review; He P, Luo L, and Zhan P participated in the writing of the review; Zheng J and Guan B provided some valuable suggestion. All authors contributed to the general discussion.
Corresponding authors
Ethics declarations
Conflict of interest The authors declare that they have no conflict of interest.
Additional information
Chuying Dai received her BSc degree from Jilin University in 2015. Currently, she is a PhD student under the supervision of Prof. Jian Zheng at the Institute of Chemistry, Chinese Academy of Sciences (ICCAS). Her research interests focus on the preparation and magnetic properties of 2D materials.
Jian Zheng is a professor at the Organic Solids Laboratory, ICCAS. He received his PhD degree in organic chemistry in 2011 under the supervision of Prof. Daoben Zhu and Prof. YunQi Liu from ICCAS. His research interests are focused on the preparation, organic hybridization and self-assembly of novel 2D materials based on chemical methods and the application and research of 2D materials in the fields of optical, electrical and energy devices.
Rights and permissions
About this article
Cite this article
Dai, C., He, P., Luo, L. et al. Research progress of two-dimensional magnetic materials. Sci. China Mater. 66, 859–876 (2023). https://doi.org/10.1007/s40843-022-2298-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40843-022-2298-0