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Coordination polymer nanowires/reduced graphene oxide paper as flexible anode for sodium-ion batteries

配位聚合物纳米线/还原氧化石墨烯复合柔性薄 膜电极的构筑及储钠性能研究

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摘要

构建基于有机材料的高性能柔性储钠电极面临诸多挑战. 本 工作通过可控组装及还原的方式, 实现了铁基配位聚合物纳米线/还原氧化石墨烯柔性薄膜的构筑. 多维复合薄膜可直接用作钠离 子电池自支撑负极, 且具有较高的储钠容量(200 mA g−1电流密度 下可逆容量为319 mA h g−1)和优异的倍率性能(3000 mA g−1大电 流密度下比容量可保持在∼120 mA h g−1). 研究表明有机配体(氨 三乙酸)中的羧基及氨基为储钠活性位点, 而配位金属离子(Fe2+)不 参与电化学反应.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (51772127 and 51772131), Taishan Scholars (ts201712050), Major Program of Shandong Province Natural Science Foundation (ZR2018ZB0317), the Natural Science Doctoral Foundation of Shandong Province (ZR2019BEM038) and the Natural Science Doctoral Foundation of the University of Jinan (XBS1830).

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Authors and Affiliations

  1. School of Materials Science & Engineering, University of Jinan, Jinan, 250022, China

    Zehang Sun  (孙泽航), Ke Tan  (谭可), Linrui Hou  (侯林瑞), Yang Liu  (刘洋) & Changzhou Yuan  (原长洲)

Authors
  1. Zehang Sun  (孙泽航)
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  2. Ke Tan  (谭可)
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  3. Linrui Hou  (侯林瑞)
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  4. Yang Liu  (刘洋)
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  5. Changzhou Yuan  (原长洲)
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Corresponding authors

Correspondence to Yang Liu  (刘洋) or Changzhou Yuan  (原长洲).

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Author contributions

Sun Z, Tan K and Hou L performed the experiments; Liu Y and Yuan C designed and engineered the samples, and wrote the paper. All authors contributed to the general discussion.

Conflict of interest

The authors declare no conflict of interest.

Zehang Sun received a BE degree from Liao-Cheng University in 2017. Currently, he is pursuing his MSc degree at the University of Jinan. His research interests focus on the structural design and electrochemical analyses of electrode materials for alkali-ion batteries.

Yang Liu obtained his PhD degree in chemical technology from Dalian University of Technology in 2017. He then joined the University of Jinan in September 2017. His research focuses on lithium ion batteries and the potential alternative energy storage devices.

Changzhou Yuan received a PhD from Nanjing University of Aeronautics and Astronautics in 2009. He is a distinguished professor of Taishan Scholar in the School of Materials Science and Engineering, University of Jinan. He is a Highly Cited Researcher (in Materials Science/Cross-field) by Clarivate Analysis from 2016 to 2019, and a Most Cited Chinese Researchers (in materials science) by Elsevier in 2016–2018. His current research focuses on the design and synthesis of micro/nano-materials for electrochemical energy-related applications.

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Sun, Z., Tan, K., Hou, L. et al. Coordination polymer nanowires/reduced graphene oxide paper as flexible anode for sodium-ion batteries. Sci. China Mater. 63, 1966–1972 (2020). https://doi.org/10.1007/s40843-019-1241-9

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  • DOI: https://doi.org/10.1007/s40843-019-1241-9

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