Skip to main content
Log in

New monatomic layer clusters for advanced catalysis materials

新型的单原子层团簇催化剂

  • Perspectives
  • Published:
Science China Materials Aims and scope Submit manuscript

摘要

“单原子层团簇”催化剂这一新概念, 不同于单原子催化剂和传统的纳米颗粒催化, 是由单原子建造新型的二维单原子层催化剂. 单原子层团簇催化剂的活性中心明确, 且原子间的相互作用会极大提高催化反应的选择性. 因此该催化剂材料不仅具有优异的催化性能, 还具有良好的选择性. 基于此, 作者同时分析和指出了未来的单原子层团簇催化剂的可能重点研究方向以及挑战.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

References

  1. Grirrane A, Corma A, García H. Gold-catalyzed synthesis of aromatic azo compounds from anilines and nitroaromatics. Science, 2008, 322: 1661–1664

    Article  Google Scholar 

  2. Rodriguez JA, Ma S, Liu P, et al. Activity of CeOx and TiOx nanoparticles grown on Au(111) in the water-gas shift reaction. Science, 2007, 318: 1757–1760

    Article  Google Scholar 

  3. Gilroy KD, Ruditskiy A, Peng HC, et al. Bimetallic nanocrystals: syntheses, properties, and applications. Chem Rev, 2016, 116: 10414–10472

    Article  Google Scholar 

  4. Qiao B, Wang A, Yang X, et al. Single-atom catalysis of COoxidation using Pt1/FeOx. Nat Chem, 2011, 3: 634–641

    Article  Google Scholar 

  5. Yang XF, Wang A, Qiao B, et al. Single-atom catalysts: a new frontier in heterogeneous catalysis. Acc Chem Res, 2013, 46: 1740–1748

    Article  Google Scholar 

  6. Bayatsarmadi B, Zheng Y, Vasileff A, et al. Recent advances in atomic metal doping of carbon-based nanomaterials for energy conversion. Small, 2017, 13: 1700191

    Article  Google Scholar 

  7. Tsuji Y, Yamamoto K, Yamauchi K, et al. Near-infrared lightdriven hydrogen evolution from water using a polypyridyl triruthenium photosensitizer. Angew Chem Int Ed, 2018, 57: 208–212

    Article  Google Scholar 

  8. Li H, Wang L, Dai Y, et al. Synergetic interaction between neighbouring platinum monomers in CO2 hydrogenation. Nat Nanotech, 2018, 13: 411–417

    Article  Google Scholar 

  9. Guo X, Fang G, Li G, et al. Direct, nonoxidative conversion of methane to ethylene, aromatics, and hydrogen. Science, 2014, 344: 616–619

    Article  Google Scholar 

  10. Jones J, Xiong H, DeLaRiva AT, et al. Thermally stable single-atom platinum-on-ceria catalysts via atom trapping. Science, 2016, 353: 150–154

    Article  Google Scholar 

  11. Deng D, Chen X, Yu L, et al. A single iron site confined in a graphene matrix for the catalytic oxidation of benzene at room temperature. Sci Adv, 2015, 1: e1500462

    Article  Google Scholar 

  12. Liu P, Zhao Y, Qin R, et al. Photochemical route for synthesizing atomically dispersed palladium catalysts. Science, 2016, 352: 797–800

    Article  Google Scholar 

  13. Wang H, Wang Q, Cheng Y, et al. Doping monolayer graphene with single atom substitutions. Nano Lett, 2012, 12: 141–144

    Article  Google Scholar 

  14. Zhang BW, Sheng T, Wang YX, et al. Platinum–cobalt bimetallic nanoparticles with Pt skin for electro-oxidation of ethanol. ACS Catal, 2017, 7: 892–895

    Article  Google Scholar 

  15. Liu L, Corma A. Metal catalysts for heterogeneous catalysis: from single atoms to nanoclusters and nanoparticles. Chem Rev, 2018, 118: 4981–5079

    Article  Google Scholar 

  16. Guo S, Zhang S, Sun S. Tuning nanoparticle catalysis for the oxygen reduction reaction. Angew Chem Int Ed, 2013, 52: 8526–8544

    Article  Google Scholar 

  17. Stamenkovic VR, Fowler B, Mun BS, et al. Improved oxygen reduction activity on Pt3Ni(111) via increased surface site availability. Science, 2007, 315: 493–497

    Article  Google Scholar 

  18. Tian N, Zhou ZY, Sun SG, et al. Synthesis of tetrahexahedral platinum nanocrystals with high-index facets and high electrooxidation activity. Science, 2007, 316: 732–735

    Article  Google Scholar 

  19. Liu S, Tian N, Xie AY, et al. Electrochemically seed-mediated synthesis of sub-10 nm tetrahexahedral Pt nanocrystals supported on graphene with improved catalytic performance. J Am Chem Soc, 2016, 138: 5753–5756

    Article  Google Scholar 

  20. Tyo EC, Vajda S. Catalysis by clusters with precise numbers of atoms. Nat Nanotechnol, 2015, 10: 577–588

    Article  Google Scholar 

  21. Kaden WE, Wu T, Kunkel WA, et al. Electronic structure controls reactivity of size-selected Pd clusters adsorbed on TiO2 surfaces. Science, 2009, 326: 826–829

    Article  Google Scholar 

  22. Sanchez A, Abbet S, Heiz U, et al. When gold is not noble: nanoscale gold catalysts. J Phys Chem A, 1999, 103: 9573–9578

    Article  Google Scholar 

  23. Jin H, Guo C, Liu X, et al. Emerging two-dimensional nanomaterials for electrocatalysis. Chem Rev, 2018, doi:10.1021/acs. chemrev.7b00689

    Google Scholar 

  24. Huber B, Koskinen P, Häkkinen H, et al. Oxidation of magnesiasupported Pd-clusters leads to the ultimate limit of epitaxy with a catalytic function. Nat Mater, 2006, 5: 44–47

    Article  Google Scholar 

  25. Yao S, Zhang X, Zhou W, et al. Atomic-layered Au clusters on α-MoC as catalysts for the low-temperature water-gas shift reaction. Science, 2017, 357: 389–393

    Article  Google Scholar 

Download references

Acknowledgements

This research was supported by the Australian Research Council (ARC) (DE170100928 and DP170101467), the Commonwealth of Australia through the Automotive Australia 2020 Cooperative Research Centre (AutoCRC), and Baosteel-Australia Joint Research and Development Center (BA14006). The authors acknowledge the use of the facilities at the UOW Electron Microscopy Centre funded by ARC Grants (LE0882813 and LE0237478) and Dr. Tania Silver for her critical reading.

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Yun-Xiao Wang  (王云晓) or Yi Du  (杜轶).

Additional information

Bin-Wei Zhang received his bachelor degree and master degree in the College of Chemistry and Chemical Engineering, Xiamen University in 2012 and 2015, respectively. He is a PhD candidate at the University of Wollongong. His current research interest is renewable energy storage and conversion, including electrocatalysis and lithium/sodium sulfur batteries.

Yun-Xiao Wang is a Research Fellow at the Institute for Superconducting and Electronic Materials (ISEM), University of Wollongong (UOW). She received her bachelor degree (2008) from Hebei Normal University and her master degree (2011) from Xiamen University. She obtained her PhD degree from the University of Wollongong in 2015. Her current research interest is renewable energy storage and conversion, including electrocatalysis, lithium/sodium-ion batteries, and lithium/sodium sulfur batteries.

Yi Du is a Senior Research Fellow at the Institute for Superconducting and Electronic Materials (ISEM), University of Wollongong (UOW). He received his bachelor degree (2004) and master degree (2007) from Beihang University, China. He obtained his PhD degree from the University of Wollongong in 2011. His current research interest is exploration and development of novel two-dimensional materials and their surface physics and chemistry with scanning probe microscopies (STM, AFM and SNOM).

Lei Jiang is currently a Professor at the Institute of Chemistry, Chinese Academy of Sciences (ICCAS), and Dean of the School of Chemistry and Environment, Beihang University. He received his BSc degree (1987), MSc degree (1990), and PhD degree (1994) from Jilin University, China (Jintie Li’s group). He then worked as a postdoctoral fellow in Professor Akira Fujishima’s group in Tokyo University. In 1996, he worked as a senior researcher in Kanagawa Academy of Sciences and Technology under Professor Kazuhito Hashimoto’s group. He joined ICCAS as part of the Hundred Talents Program in 1999. He was elected the academician of the Chinese Academy of Sciences in 2009 and the Academy of Sciences for the Developing World in 2012. His scientific interests are focused on bioinspired, smart, multiscale interfacial (BSMI) materials.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhang, BW., Ren, L., Wang, YX. et al. New monatomic layer clusters for advanced catalysis materials. Sci. China Mater. 62, 149–153 (2019). https://doi.org/10.1007/s40843-018-9317-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40843-018-9317-7

Navigation