Abstract
In this study, based on a regression of the crack tip displacements, the stress intensity range in fatigue is quantitatively determined for the shape memory alloy Ni2FeGa. The results are compared to the calculated stress intensity ranges with a micro-mechanical analysis accounting for the transformation-induced tractions. The effective stress intensity ranges obtained with both methods are in close agreement. Also, the fatigue crack closure levels were measured as 30 % of the maximum load using virtual extensometers along the crack flanks. This result is also in close agreement with the regression and micro-mechanical modeling findings. The current work pointed to the importance of elastic moduli changes and the residual transformation strains playing a role in the fatigue crack growth behavior. Additional simulations are conducted for two other important shape memory alloys, NiTi and CuZnAl, where the reductions in stress intensity range were found to be lower than Ni2FeGa.
Similar content being viewed by others
Avoid common mistakes on your manuscript.
Introduction
The shape memory alloys used in engineering and biomedical applications undergo repeated (cyclic) deformation [1, 2]. These alloys undergo reversible, thermo-elastic phase transformations at the macro-scale, while a degree of irreversibility exists when slip occurs locally at micro-scale. The fatigue damage tolerance of these alloys has been a tremendous concern, yet an understanding remains elusive as of today. This is partly because our knowledge of fatigue crack growth is built upon untransforming alloys, while the transformation behavior modifies the driving force parameters. In the case of untransforming materials, the stress intensity factor and the crack tip displacements are used to characterize fatigue crack growth. In the case of shape memory alloys, these parameters change but the exact nature of the changes in the driving force that occur has not been derived.
Table 1 illustrates the mechanisms that have been forwarded to modify the driving forces in the presence of phase transformation from austenite to martensite. The modifications in driving force due to internal tractions (first row) have been derived by Rice–McMeeking–Evans [3, 4] using weight function theory. The transformation strains drive these tractions. Also as shown in Table 1 (second row), there have been several efforts attempting to calculate the redistribution of stress fields ahead of the crack tip due to the phase transformation. These analyses [5], similar to the work of Irwin on plastic zone size correction [6], propose a change in effective crack length, resulting in a change in the stress intensity factor. A number of recent works on the numerical [7–9] determination of transformation zones under monotonic deformation have been undertaken. The local driving forces are found to differ compared to remotely evaluated levels.
There have been previous fundamental works on fatigue crack initiation in shape memory alloys [10–16] describing the role of slip, the origin of irreversibilities, and residual martensite, but much less work has been undertaken on fatigue crack growth behavior. Systematic efforts have been undertaken by Ritchie and his students [17–19] on experimental fatigue crack growth studies on NiTi alloys. Overall, the measured threshold stress intensity levels were rather low (less than 3 \( {\text{MPa}}\sqrt {\text{m}} \)) in NiTi. Other papers confirmed the low fatigue crack growth resistance of shape memory alloys in general [13, 20, 21]; however, the calculation of effective stress intensity in fatigue remains unresolved.
We note that under cycling loading eigenstrains (misfit strains) arise when transformation develops in the matrix. Under fatigue conditions both the maximum stress intensity and minimum stress intensity levels are modified due to the transformation effects. The maximum stress intensity (Fig. 1a) is reduced as \( K_{\text{red{-}max}} \) while the minimum stress intensity is decreased by \( K_{\text{red{-}min}} \) resulting in a net reduction of the stress intensity range, rendering an effective range denoted as \( \Delta K_{\text{eff}} = \Delta K - \Delta K_{\text{red}} \) (shaded region). In this work, we propose a calculation methodology for these quantities. The effective stress intensity range would remain the same if the reductions of stress intensity at maximum and minimum loads were identical.
Because we are considering the differential reduction in maximum and minimum stress intensity, the consideration of moduli difference between martensite and austenite domains becomes significant. The martensite under consideration is ‘oriented martensite’ and not the ‘thermally induced martensite’ [22]. The elastic moduli of oriented martensite differ from the thermally induced one and also from the austenite moduli, and this difference cannot be ignored. The martensite crystal moduli tensor (monoclinic or tetragonal depending on the alloys considered here) has higher number of independent constants than the cubic austenite. Also, in this study, our experiments utilize single crystals of austenite permitting precise knowledge of the elastic constants.
In Fig. 1b, the main variables that influence the transformation mediated fatigue crack growth rate are listed. The equivalent eigenstrain, \( e_{mn}^{**} \), is calculated from Eshelby’s equivalent inclusion principle; the crack length, a; transformation height in the crack wake, w; the elastic moduli of the austenite, \( C_{ijkl} \); and martensite, \( C_{ijkl}^{'} \), phases respectively (see Fig. 1b). Because the stress state at the crack tip is rather complex, the resulting strain distribution is difficult to predict but it can be measured experimentally. Even though the residual strain per one cycle is very small, it accumulates over many fatigue cycles. The crack length and transformation zone height in the wake can also be obtained through experiments. The elastic moduli can also be measured for the austenite single crystals, while density function theory (DFT) calculations need to be utilized in the case of martensite. Considering all the factors, we postulate that the fatigue crack growth rate is given as a function of \( C_{ijkl}^{'} \), \( C_{ijkl} \), a, w, and \( e_{mn}^{**} \), as \( \frac{{{\text{d}}a}}{{{\text{d}}N}} = f(\Delta K_{\text{eff}} (C_{ijkl}^{'} ,\;C_{ijkl} ,\;a,\;w,\;e_{mn}^{**} )) \). Experimentally, crack tip displacements field measurements can be used to extract stress intensity levels. In the first approach (Method I) of the current work, the displacement fields are measured in the vicinity of crack tip during fatigue experiments with digital image correlation (DIC). These displacement results can be utilized in turn to determine the ‘effective stress intensity’ levels. In the case of transforming alloys, these measured displacement fields would naturally reflect the crack tip driving force modification in the presence of transformation strains. As an extension of the method using regression, it is worthwhile to measure the contact of crack surfaces during fatigue resulting in crack closure. Such experiments are now possible with the use of virtual extensometers behind the crack tip in conjunction with digital image correlation studies. We explore this possibility as well in the current work accounting for a full range of mechanisms. The results from regression and virtual extensometers agreed in untransforming alloys, and a similar agreement is expected in shape memory materials. Alternately, in the second approach (Method II), we compute the modified stress intensity in transforming alloys due to internal tractions. In fatigue loading, one needs to consider tractions at both maximum and minimum loads imposed on the transforming regions by the surrounding untransformed domains. Ideally, both approaches (I and II) should render an ‘effective stress intensity range’ that is comparable in magnitude resulting in the true value of the driving force in fatigue.
To develop an appreciation of the length scales for the experimental and modeling work pursued in this work, we include Fig. 2. At the smallest length scales, atomistic simulations provide a critical resource to establish the elastic constants [22–24] of austenite and martensite which can be substantially different. At the higher length scale, a micro-mechanics analysis is undertaken to determine the closure forces in the wake of the crack tip. Consideration of the theoretical transformation strains and experimentally measured transformation strains are taken into account. The modeling results are verified by precise measurements of crack tip displacements with DIC, and closure stress levels are determined with virtual extensometers at the macro-scale. The paper will cover the entire length scales in Fig. 2 with theory and experimentation.
In summary, the driving force for fatigue crack growth in shape memory alloys (the effective stress intensity range) requires additional calculations and depends on the closure forces at both maximum and minimum load, the elastic moduli of austenite and martensite and their anisotropy. The irreversible (residual) strain accumulates with cycles and the residual transformation strain in the crack wake produces closure forces. In turn, such forces contribute significantly to setting an ‘effective stress intensity range’ lower than the theoretical one. In the present work utilizing anisotropic elasticity theory, Eshelby’s equivalent inclusion principle [25], weight function methods for anisotropic media [26], density functional theory (DFT) calculations, extensive digital image correlation results for displacements in crack wake and in transformation zones, we establish the modified stress intensity factor for fatigue crack growth in \( {\text{Ni}}_{54} {\text{Fe}}_{19} {\text{Ga}}_{27} \) shape memory alloy. The elastic moduli and details of the fatigue crack growth experiments are presented in “Materials, Elastic Moduli and Fatigue Crack Growth Experiment Details” section. In “Digital Image Correlation of the Crack Tip Strains in Cyclic Loading” section, experimental determinations of strain fields at crack tips obtained via DIC and strain irreversibility are demonstrated. Then, in “Method I: Extraction of Stress Intensity Factor from Displacements Using Anisotropic Elasticity via Regression” section, Method I (regression to extract effective stress intensity range) is described. In “Method II: Calculation of the Driving Force Changes Due to Transformation Shielding in Crack Wake-Equivalent Eigenstrain Determination-Minimum and Maximum Load” section, Method II (modeling to determine effective stress intensity range) is outlined and the results are extended to two other shape memory alloys. The modification in stress intensity obtained from Method I and Method II and the experimental fatigue crack growth rates are given in “Fatigue Crack Growth Experiments and Corrections to Stress Intensity” section. Finally, in “Virtual Extensometer Results: Determination of Crack Opening Load” section, the measurements of crack opening and closure loads with virtual extensometers are presented.
Materials, Elastic Moduli, and Fatigue Crack Growth Experiment Details
Material
The material studied experimentally in this study is \( \text{Ni}_{{\text{54}}} \text{Fe}_{{\text{19}}} \text{Ga}_{{\text{27}}} \) (hereafter referred to as Ni2FeGa for the sake of simplicity) which undergoes cubic to tetragonal transformation (Fig. 3). It is a new class of shape memory alloys which exhibits multi-martensites with strain levels exceeding 10 % [27–29]. The materials undergoes L21 to 10 M to 14 M to L10 tetragonal transformation. The typical stress–strain response for \( {\text{Ni}}_{2} {\text{FeGa}} \) is summarized in Fig. 4a and b for deformation in tension. Figure 4a shows orientation dependence and the modulus difference among the three crystallographic orientations analyzed in this study. Figure 4b shows the two-stage transformation and transformation strain levels exceeding 10 %. More details are provided in Appendix 4.
Based on the lattice deformation theory calculations [30], the maximum transformation strains are known for all three orientations. Among the three orientations considered in this study, the [001] strain is as high as 12 %, while the [011] strain is 3.5 %, and the [123] strain is 4.5 %. The magnitude of the residual or accumulated strain is a fraction of the maximum strain, and based on careful measurements, we measured this strain as slightly less than 0.8 %.
The elastic moduli tensors for austenite and tetragonal martensite phases need to be known for the calculations. The austenite constants can be determined experimentally and are given in Table 4 (also graphically plotted in Fig. 5a), but the martensite elastic constants need to be evaluated from atomistic simulations. DFT calculations were made for the martensitic state (L10).
DFT Simulation Setup
In order to calculate the elastic constants of martensitic Ni2FeGa, a cell structure consisting a total of 8 atoms was used. The cell consisted of four Ni, two Fe and two Ga atoms, thus maintaining an atomic ratio of Ni, Fe, and Ga as 2:1:1. We employed first principles calculations based on the DFT to obtain the total-energy of the system. We utilized the Vienna ab initio simulations package (VASP) with the projector augmented wave (PAW) method and the generalized gradient approximation (GGA) as implementations of DFT [31]. In our calculations, we used a 12 × 12 × 12 Monkhorst–Pack k-point meshes for the Brillouion-zone integration to ensure the convergence of results. The energy cut-off of 500 eV was used with the plane-wave basis set and a conjugate gradient algorithm was performed for ionic relaxation ensuring an energy convergence to less than \( 5 \times 10^{ - 3} \,{\text{eV}} \)/Å.
To calculate the elastic constants of the martensitic (L10-non-modulated Ni2FeGa), we obtained the total energy variation of the crystal as a function of the volume subjected to six different distortions (strain). The deformation tensors given in Voigt notation and the corresponding energy densities are given in Table 2. The strain parameter \( \delta \) in Table 2 for each deformation was varied from −0.03 to 0.03 in the present analysis. After obtaining the total energies \( E \) and \( E_{0} \) for the strained and the unstrained lattice respectively, the parameter \( (E - E_{0}) /V_{0} \) values were then plotted as a function of strain (\( \varepsilon \)), where \( V_{0} \) is the equilibrium volume. The elastic constants were then extracted from the second-order coefficient fit of the following equation:
where \( C_{ij} \), \( \sigma_{i} \), \( \varepsilon_{i} \) are the elastic constants, stress, and strain in Voigt notation. The results are shown in Fig. 5, and the modulus tensor for martensite is provided in Table 3. The total energies to obtain \( \left( {C_{33} /2} \right)\delta^{2} + O(\delta^{4} ) \) are discussed in Appendix 5.
In addition to the elastic moduli of martensites, the anisotropy factor is included in the Table 3. The results for NiTi and CuZnAl, two well-known studied alloys in terms of fatigue resistance, are also included in Table 3. The plots of the elastic moduli for NiTi and CuZnAl are given in Appendix 3. The NiTi results are obtained from [22] and the CuZnAl constants are obtained from [32]. The elastic constants for the three materials in the austenitic state are listed in Table 4. The anisotropy factor is also included in Table 4. The procedure for calculating the anisotropy ratio can be found in the work Ostoja-Starzewski [34]. It is important to note that these set of constants meet the mechanical stability criteria for the elastic moduli. We note that the moduli values for both austenite and martensite are strongly orientation dependent. This information is of fundamental importance for precise calculation of the internal forces acting on the crack surfaces and for determination of the stress intensity levels when displacements are measured.
Fatigue Crack Growth Experiments
Fatigue crack growth experiments were conducted on the \( {\text{Ni}}_{2} {\text{FeGa}} \) single crystals for three-crystal orientations: [001], [123], and [011]. The tensile dog-bone-shaped specimens utilized in this study were cut using EDM and have nominal 1.50-mm × 3-mm-gage section, 10-mm-gage length and a 0.5-mm notch. Prior to testing, the specimens were polished using SiC paper (from P800 to P1500). Successively, a fine speckle pattern adapted for image correlation was deposited using an Iwata micron B airbrush and black paint. Three experiments were conducted separately on the single crystals. The fatigue crack growth experiment on [001] \( {\text{Ni}}_{54} {\text{Fe}}_{19} {\text{Ga}}_{27} \) was conducted under MTS Landmark Servo Hydraulic Load Frame to capture the relationship between stress intensity factor range and crack growth rate. For the other two orientations, [011] and [123], two experimental set-ups were prepared. (i) Under the same servo hydraulic load frame, we initially pre-cracked the specimens utilizing constant amplitude loadings in order to induce a fatigue crack from the notch. For this experimental configuration, the images used for crack length measurements and displacements (in x and y directions) and strain fields correlations were captured using an IMI model IMB-202 FT CCD camera (1600 × 1200 pixel) with a Navitar optical lens, providing an average resolution of approximately 2 µm/px [35]. (ii) Successively, the cracked specimens were loaded under a 4.5 kN EBSD SEMTester which was herein fitted under an Olympus BX51M microscope (Olympus lens). This set-up is shown in Fig. 6 and was utilized for obtaining images at higher magnifications (from 0.44 up to 0.22 µm/px). This set-up allows precisely obtaining the strains at crack tip and the extent of the residual transformation zone. For these three experiments, initial images of the virgin specimens were captured prior to loading (reference images) in order to calculate the accumulated strain in the further analyses.
Digital Image Correlation of the Crack Tip Strains in Cyclic Loading
Displacement and strain fields were monitored in the vicinity of the crack as the crack advances. These measurements were made at maximum load, minimum load, and at intermediate loads. As the crack advances into a zone of transformed material is generated in the wake of the crack. This zone height and the strains are readily measured from the digital image correlation results. An example of the strains in the crack wake is shown in Figs. 7 and 8. In Fig. 7, the axial strain fields at the beginning of the cycle (point A) and at the end of the cycle (point B) are shown for the [011] crystal orientation. The strain maps were obtained adopting two image resolutions. Utilizing the 0.44 µm/px set-up the full-field strain field of the notch region can be analyzed, and the extent of the crack wake can be readily obtained. Images captured at higher resolutions (0.22 µm/px for the example reported) are then necessary in order to characterize the crack-tip strain field. From the high-resolution strain fields marked as A and B in Fig. 7, it is possible to calculate the accumulation of the local strains in front of the crack tip following the fatigue cycle.
Providing these strain measurements for different crack lengths, in Fig. 8, we report the strain accumulation during crack propagation in terms of the equivalent strain at the crack tip. The equivalent strain at the crack tip was calculated via averaging the strain tensor components over a region of approximately 50 µm × 50 µm in front of the crack tip for different crack lengths. That is, within this confined region ahead of the crack tip, the strain components, e xx , e yy , and e xy , can be extracted from digital image correlation results. Consequently, the corresponding equivalent strain, e Equivalent, can be calculated from Eq. (2). The difference between levels of strain at point A and point B, in Fig. 8, yields the equivalent strain accumulation in one fatigue cycle
A comparison of the strain fields at peak and minimum load for the three crystal orientations [001], [123], and [011] is illustrated in Fig. 9. The shapes of the transformation region determined using these strain fields will be used to evaluate the reduction in stress intensity factor for each orientation.
Stress Intensity Determination via Regression and Modeling, Fatigue Crack Growth Rates, Virtual Extensometers, and Key Variables for Modeling
Method I: Extraction of Stress Intensity Factor from Displacements Using Anisotropic Elasticity via Regression
The displacement fields from the digital image correlation are shown in Fig. 10. In Figs. 10a and b, the displacements normal and parallel to the crack tip are shown respectively for fatigue crack growth in [001] oriented specimens. These results are fitted to the anisotropic displacement fields for cubic crystals. Such solutions are available by Sih et al. [26]. It is possible to extract the stress intensity by regression fit to the following set of equations, Eqs. (3) and (4). We note that the equations include the elastic constants and T stress term. We also note that the orientation of the crack in the [001] specimen is 45° to the loading axis. In this case, both Mode I and Mode II stress intensities can be extracted. In the case of [123] and [011]-oriented single crystals, the crack grew nearly normal to the loading axis and the Mode II stress intensity is small. The crack tip displacements for the [123]-oriented specimens are shown in Fig. 10c. Figures 10a–c demonstrate the comparison between experimental and regression displacement fields. A video was attached to this paper to illustrate such comparison during one fatigue cycle.
The stress intensity factors, K 1 and K 2, can be extracted from horizontal and vertical displacements, u 1 and v 1, through the following equations
where Re represents the real part of a complex number, T is the T-stress, A is the rigid body rotation, B u and B v are the rigid body translations in u 1 and v 1 directions, respectively, a 11, a 12, a 16, a 22, a 26, and a 66 are the compliance components, r and θ are the polar coordinates with their origin at the crack tip, and μ 1 and μ 2 are the roots of Eq. (5). The p i and q j in Eqs. (3) and (4) are the anisotropic terms defined in the following ways
Method II: Calculation of the Driving Force Changes Due to Transformation Shielding in Crack Wake-Equivalent Eigenstrain Determination-Minimum and Maximum Load
The strain level measured via DIC is shown in Fig. 9 for different single-crystal orientations. Since the transformed area is surrounded by the matrix material, the DIC result can be interpreted as the total strain, \( e_{mn}^{t} \) which is the sum of constrained strain and far field strain. The intrinsic transformation strain, \( e_{kl}^{p} \) can be calculated by following equation
where \( e_{mn}^{o} \) is the far-field strain and \( S_{ijkl} \) the Eshelby’s tensor for cubic crystal material. The \( S_{ijkl} \) represents the geometry of the martensite platelets and is treated as a flat ellipsoidal shape. It can be obtained as
where the specific terms, \( \bar{G}_{ipjq} \), are given a book by Mura [38] and also in Appendix 1 for completeness.
Assuming the minimum load to be near zero, the misfit strain due to modulus mismatch can be neglected. As a result, in the case of minimum load, \( e_{kl}^{p} \) is the equivalent eigenstrain that needs to be calculated. Therefore, the corresponding stress, T ij , on the transformation contour can be obtained via
When the maximum load is applied, the eigenstrain effect due to modulus mismatch, \( e_{mn}^{*} \) needs to be taken into account. The equivalent eigenstrain, \( e_{mn}^{**} \), which is the sum of \( e_{mn}^{*} \) and \( e_{kl}^{p} \) can be calculated through Eshelby’s equivalent method described below
where \( C_{ijkl} \) and \( C^{\prime}_{ijkl} \) are the elastic moduli of cubic austenite and tetragonal martensite for Ni2FeGa, respectively. These tensors are given in “DFT Simulation Setup” section. We note that all tensors are given in the cubic coordinate frame, and the rotations associated with the transformation are accounted for when the moduli are determined.
Upon calculation of the equivalent eigenstrains, the corresponding stress, T ij , in the transformation zone can be ascertained as
Using equation above, it is possible to determine the internal tractions along the transformation contour using the Cauchy formula. Further details are given in Appendix 1.
Knowing the tractions on the surface of transformation zone, we can numerically calculate the stress intensity change for a specific loading case. By implementing the weight function technique proposed by Bueckner and Rice [4], the stress intensity factor due to the internal tractions, ΔK I , can be written as
where n i is the outward normal of the transformation zone, dS p is the line element on the perimeter of the zone, and h j is the anisotropic weight function which is going to be determined.
According to Rice, the weight function can be readily obtained through Eq. (13) if the displacement fields, u 1 and v 1, and stress intensity factor, K 1 and K 2, in a reference load system are known
The solution for stress intensity factors due to tractions on the crack surface in Fig. 11 can be found via Eq. (14) and displacement fields are provided by Sih et al. [26] as
where α o and β o are the real and imaginary component of the roots for Eq. (5), i.e., for \( \mu_{1} = \alpha_{o} + \beta_{o} i\;{\text{and}}\;\mu_{2} = - \alpha_{o} + \beta_{o} i \).
The elastic moduli, H, can be represented in Eq. (15)
Once weight functions are obtained, the corresponding stress intensity factor in that loading system can be determined through Eq. (13). The summation of stress intensity factors obtained from different parts of the transformation contour (Fig. 11) yields the change of stress intensity factor due to transformation effect. Further details are given in Appendix 2.
The net reduction in stress intensity factor as the applied loading is increased is given in Table 5. The contributions from different sectors of the transformation zone are provided. It is noted that the Zone 2 provides negligible contribution while Zones 1 and 3 provide a smaller contribution compared to Zone 4. These results are further presented in the next section.
Fatigue Crack Growth Experiments and Corrections to Stress Intensity
The experimental fatigue crack growth rate results and predictions of fatigue crack growth rates upon correction of stress in intensity range are shown in Fig. 12. The effective stress intensity range upon regression of the entire displacement field is also included in Fig. 12. The agreement for the theory and regression-based stress intensity range is excellent. The reduction in the stress intensity range is approximately 35 % of the full range based on regression and also based on theory. We show virtual extensometer results of crack opening displacements confirming the crack closure in the next section.
Virtual Extensometer Results: Determination of Crack Opening Load
The virtual extensometer method is another technique for determining the crack closure levels which is complimentary to ‘regression.’ The technique is illustrated in Fig. 13a. The relative displacements across the crack faces are measured during loading and unloading. Therefore, DIC measurements allow the determination of the crack opening displacements during loading and unloading. By making such measurements over fine increments, it is possible to precisely determine the applied load level at which the crack opening occurs. These results are shown in Fig. 13b for two crack lengths. The crack opening load is determined as 35 % of the maximum load.
Sensitivity of Results to \( a/w \) Ratio and the Moduli Levels
Three other shape memory alloys were assessed to evaluate the propensity of K reduction. The results are shown in Tables 6 and 7. In the first set of simulations (Table 6), the \( a/w \) ratio was maintained at 2. In Table 7, we consider the reductions in K at both maximum and minimum loads for different \( a/w \) ratios. A noteworthy point is that the reduction in K occurs at both maximum and minimum load. However, since the reduction is higher at the maximum load, this results in a net decrease in stress intensity range.
The sensitivity of the simulations on the variations in the \( a/w \) ratio and martensite moduli magnitude is studied in Fig. 14a and b. The basis for these simulations is the Ni2FeGa alloy. We note that as the \( a/w \) ratio increases, with all other parameters constant, the reduction in both minimum and maximum stress intensity is noted. The overall reduction in stress intensity range saturates with increasing \( a/w \) ratio. In Fig. 14b, the martensite modulus is pre-multiplied by a factor. The factor F = 1 corresponds to the \( {\text{Ni}}_{2} {\text{FeGa}} \) case. As the factor increases the reduction in stress intensity range increases.
Discussion of Results
Fatigue crack growth experiments were conducted on the new Ni2FeGa shape memory alloy. Extensive experimental results and measurements for fatigue crack growth were obtained in the course of this study. Three single-crystal orientations of \( {\text{Ni}}_{2} {\text{FeGa}} \) shape memory alloy were tested in tension–tension fatigue. The experimental results were obtained at room temperature where the material deforms under ‘pseudoelastic’ conditions. The crack advance was measured as a function of the effective stress intensity range and the threshold stress intensity range was precisely established as \( 8.3\;{\text{MPa}}\sqrt {\text{m}} \).
Reduction in stress intensity range (of the order of 30 %) was established by calculating the closure forces (Method II—“Method II: Calculation of the Driving Force Changes Due to Transformation Shielding in Crack Wake-Equivalent Eigenstrain Determination-Minimum and Maximum Load” section) via a micro-mechanical analysis. The closure forces arise due to residual strains in the wake of the crack. The calculated crack tip stress intensity range is in agreement with the experimental measurements of the effective stress intensity range. We used two experimental measurements for measuring the effective stress intensity range. In the first one, the crack tip displacement fields were utilized to establish the stress intensity range with a least square fitting procedure (Method I—“Method I: Extraction of Stress Intensity Factor from Displacements Using Anisotropic Elasticity via Regression” section). This method resulted in establishment of the effective stress intensity range 30 % smaller than the theoretical one. The difference is attributed to shielding due to residual displacements in the crack wake. In the second one, by using virtual extensometers along the crack faces (“Virtual Extensometer Results: Determination of Crack Opening Load” section), the crack opening and crack closure loads were measured and found to be also at nearly 30 % of the maximum load.
A combined experimental-theoretical methodology is outlined for a better understanding of the driving force for fatigue crack growth in shape memory alloys. The choice of single crystals allowed precise knowledge of the elastic moduli in the austenitic and martensitic phases. In turn, the moduli tensors were used in a micro-mechanical analysis to determine the equivalent eigenstrains in the transformed regions. The equivalent eigenstrain was used to determine the internal tractions at maximum load of the cycle. This led to the calculation of the reduction in stress intensity, hence a modified range of stress intensity was determined. The calculations presented represent an advancement by accounting for elastic moduli difference and with the experimental determination of strain fields at minimum and maximum loads.
To put perspective on the results, the simulations were repeated on two well-known shape memory materials, the NiTi and CuZnAl. The reductions in stress intensity range were lower in NiTi compared to Ni2FeGa, while the reduction in CuZnAl was substantially lower than NiTi and Ni2FeGa. These results cannot be directly compared with experiments in the literature, since there is no reported CuZnAl fatigue crack growth data to our knowledge. The literature on NiTi shows threshold levels that are lower compared to Ni2FeGa.
Fatigue crack growth behavior in shape memory alloys remains a complex topic. The elastic moduli evolves continuously; it is strongly orientation dependent in both austenite and martensite. The moduli tensors decide the equivalent eigenstrains, hence the closure forces. The closure forces vary as a function of cycles accompanying the residual transformation strains. In this study, we established the modification in stress intensity and established a rigorous estimate of the stress intensity range. In future studies, the crack growth rate needs to be predicted based on the magnitude of the irreversibility in displacements at crack tips [39, 40]. This would require knowledge of the slip and transformation energy barriers in the material [41]. This approach would need to be taken with care because both transformation and plasticity can occur simultaneously at the crack tips. In the present calculations no explicit consideration of plastic slip was included [41]. Plasticity can occur at high stress levels and it needs to be considered in future work.
Finally, we comment on the role of martensite to austenite modulus change. Evidence of higher martensite modulus relative to austenite is well documented [42]. On the other hand, the martensite modulus is taken as less than the austenite modulus in most constitutive models. The martensite moduli upon deformation in fatigue and fracture studies are the oriented martensite and not the self-accomodated one [22]. Also, the constitutive models utilized have been simple for the ease of implementation in FEM codes. This creates some difficulty when residual strain buildup due to residual martensite or plastic deformation needs to be considered. There is no provision for these mechanisms in most constitutive models. Finally, there is the matter of orientation dependence. A highly anisotropic material cannot be represented accurately as isotropic with two elastic constants. Constitutive models will need to incorporate these characteristics.
Conclusions
The work supports the following conclusions:
-
(1)
The new shape memory alloy Ni2FeGa displays unusually high fatigue thresholds (\( 8.3\;{\text{MPa}}\sqrt {\text{m}} \)) and excellent fatigue crack growth resistance. The reduction of the stress intensity range associated with the transformation is considerable as shown with an anisotropic micro-mechanics calculation.
-
(2)
Excellent quantitative correlation is achieved between theory and the experimental measurements of stress intensity range reduction. Utilizing crack tip displacement fields with digital image correlation methods allowed evaluation of the effective stress intensity range in agreement with the virtual extensometers along the crack flanks. These results show that the reduction in stress intensity is 35 % of the full range.
-
(3)
Comparisons were made between three shape memory alloys to assess their propensity for shielding associated with phase transformations. It was found that the Ni2FeGa produced higher levels of stress intensity reduction compared to NiTi and CuZnAl alloys. The work underscored the role of elastic moduli in the martensitic and austenitic phases on the calculations of the reduction in stress intensity range.
References
Duerig TW, Melton K, Stockel D, Wayman C (1990) Engineering aspects of shape memory alloys. Butterworth-Heinemann, London
Otsuka K, Wayman CM (eds) (1998) Shape memory materials. Cambridge University Press, Cambridge
McMeeking RM, Evans AG (1982) Mechanics of transformation-toughening in brittle materials. J Am Ceram Soc 65:242–246
Rice JR (1972) Some remarks on elastic crack-tip stress fields. Int J Solids Struct 8:751–758. doi:10.1016/0020-7683(72)90040-6
Xiong F, Liu Y (2007) Effect of stress-induced martensitic transformation on the crack tip stress-intensity factor in Ni-Mn-Ga shape memory alloy. Acta Mater 55:5621–5629. doi:10.1016/j.actamat.2007.06.031
Irwin GR (1960) Plastic zone near a crack and fracture toughness. In: Proceedings of the Sagamore Res Ord Materials Section IV, pp 63–71
Baxevanis T, Parrinello AF, Lagoudas DC (2013) On the fracture toughness enhancement due to stress-induced phase transformation in shape memory alloys. Int J Plast 50:158–169. doi:10.1016/j.ijplas.2013.04.007
Lexcellent C, Thiebaud F (2008) Determination of the phase transformation zone at a crack tip in a shape memory alloy exhibiting asymmetry between tension and compression. Scripta Mater 59:321–323. doi:10.1016/j.scriptamat.2008.03.040
Stam G, van der Giessen E (1995) Effect of reversible phase transformations on crack growth. Mech Mater 21:51–71. doi:10.1016/0167-6636(94)00074-3
Brown LC (1979) The fatigue of pseudoelastic single crystals of α-CuAINi. Metall Mater Trans A 10:217–224. doi:10.1007/BF02817631
Delaey L, Janssen J, Van de Mosselaer D, Dullenkopf G, Deruyttere A (1978) Fatigue properties of pseudoelastic Cu·Zn·Al alloys. Scripta Metall. 12:373–376. doi:10.1016/0036-9748(78)90302-2
Hornbogen E, Eggeler G (2004) Surface aspects in fatigue of shape memory alloys (SMA). Mater. Werkst 35:255–259. doi:10.1002/mawe.200400759
Melton KN, Mercier O (1979) Fatigue of NiTi thermoelastic martensites. Acta Metall 27:137–144
Miyazaki S, Mizukoshi K, Ueki T, Sakuma T, Liu Y (1999) Fatigue life of Ti–50 at.% Ni and Ti–40Ni–10Cu (at.%) shape memory alloy wires. In: ICOMAT 98. International conference on martensitic transformations, 7–11 Dec. 1998. Elsevier, pp 658–663. doi:10.1016/s0921-5093(99)00344-5
Sade M, Hornbogen E (1988) Fatigue of single- and polycrystalline—CuZn-base shape memory alloys. Z Metall 79:782–787
Yang NYC, Laird C, Pope DP (1977) The cyclic stress–strain response of polycrystalline, pseudoelastic Cu-14.5 wt pct Al-3 wt pct Ni alloy. Metall Mater Trans A 8:955–962. doi:10.1007/BF02661579
McKelvey AL, Ritchie RO (1999) Fatigue-crack propagation in Nitinol, ashape-memory and superelastic endovascular stent material. J Biomed Mater Res 47:301–308
McKelvey AL, Ritchie RO (2001) Fatigue-crack growth behavior in the superelastic and shape-memory alloy nitinol. Metall Mater Trans A 32:731–743. doi:10.1007/s11661-001-1008-7
Robertson SW, Mehta A, Pelton AR, Ritchie RO (2007) Evolution of crack-tip transformation zones in superelastic nitinol subjected to in situ fatigue: a fracture mechanics and synchrotron X-ray microdiffraction analysis. Acta Mater 55:6198–6207
Holtz RL, Sadananda K, Imam MA (1996) Near-threshold fatigue crack growth behavior of nickel-titanium shape memory alloys. In: Johannes Weertman symposium. Proceedings of a symposium held during the TMS annual meeting, 4–8 Feb. 1996, Warrendale, pp 297–299
Vaidyanathan R, Dunand DC, Ramamurty U (2000) Fatigue crack-growth in shape-memory NiTi and NiTi–TiC composites. Mater Sci Eng A 289:208–216. doi:10.1016/S0921-5093(00)00882-0
Wang J, Sehitoglu H (2014) Martensite modulus dilemma in monoclinic NiTi-theory and experiments. Int J Plast 61:17–31. doi:10.1016/j.ijplas.2014.05.005
Hatcher N, Kontsevoi OY, Freeman AJ (2009) Role of elastic and shear stabilities in the martensitic transformation path of NiTi. Phys Rev B 80:144203
Wagner MFX, Windl W (2008) Lattice stability, elastic constants and macroscopic moduli of NiTi martensites from first principles. Acta Mater 56:6232
Eshelby JD (1957) The determination of the elastic field of an ellipsoidal inclusion, and related problems. Proc R Soc Lond Ser A Math Phys Sci 241:376–396. doi:10.2307/100095
Sih GC, Paris PC, Irwin GR (1965) On cracks in rectilinearly anisotropic bodies. Int J Fract Mech 1:189–203. doi:10.1007/BF00186854
Efstathiou C, Sehitoglu H, Carroll J, Lambros J, Maier HJ (2008) Full-field strain evolution during intermartensitic transformations in single-crystal NiFeGa. Acta Mater 56:3791–3799. doi:10.1016/j.actamat.2008.04.033
Efstathiou C, Sehitoglu H, Lambros J (2010) Multiscale strain measurements of plastically deforming polycrystalline titanium: role of deformation heterogeneities. Int J Plast 26:93
Hamilton ARF, Sehitoglu H, Efstathiou C, Maier HJ (2007) Mechanical response of NiFeGa alloys containing second-phase particles. Scripta Mater 57:497–499
Saburi T, Nenno S (1981) The shape memory effect and related phenomena. In: Aaronson HI, Laughlin DE, Sekerka RF, Wayman CM (eds) International conference on solid-solid phase transformations, Pittsburgh, pp 1455–1479
Kresse G, Furthmuller J (1996) Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys Rev B 54:11169
Rodriguez PL, Lovey FC, Guenin G, Pelegrina JL, Sade M, Morin M (1993) Elastic constants of the monoclinic 18R martensite of a CuZnAl alloy. Acta Metall Mater 41(11):3307–3310
Verlinden B, Suzuki T, Delaey L, Guenin G (1984) Third order elastic constants of β Cu-Zn-Al as a function of the temperature. Scripta Metall 18:975–979
Ranganathan SI, Ostoja-Starzewski M (2008) Universal elastic anisotropy index. Phys Rev Lett 101(5):055504
Carroll J, Efstathiou C, Lambros J, Sehitoglu H, Hauber B, Spottswood S, Chona R (2009) Investigation of fatigue crack closure using multiscale image correlation experiments. Eng Fract Mech 76(15):2384–2398
Pérez-Landazábal JI, Recarte V, Sánchez-Alarcos V, Rodríguez-Velamazán JA, Jiménez-Ruiz M, Link P, Cesari E, Chumlyakov YI (2009) Lattice dynamics and external magnetic-field effects in Ni-Fe-Ga alloys. Phys Rev B 80(14):144301
Ren X, Miura N, Zhang J, Otsuka K, Tanaka K, Koiwa M, Suzuki T, Chumlyakov YI, Asai M (2001) A comparative study of elastic constants of Ti-Ni based alloys prior to martensitic transformation. Mater Sci Eng A 312:196–206
Mura T (1987) Micromechanics of defects in solids, vol 3. Springer
Chowdhury PB, Sehitoglu H, Rateick RG (2014) Predicting fatigue resistance of nano-twinned materials: Part I—role of cyclic slip irreversibility and Peierls stress. Int J Fatigue 68:277–291
Chowdhury PB, Sehitoglu H, Rateick RG (2014) Predicting fatigue resistance of nano-twinned materials: Part II—effective threshold stress intensity factor range. Int J Fatigue 68:292–301
Sehitoglu H, Wang J, Maier HJ (2012) Transformation and slip behavior of Ni2FeGa. Int J Plast 39:61–74
Sehitoglu H, Zhang XY, Chumlyakov YI, Karaman I, Gall K, Maier HJ (2002) Observations on stress-induced transformations in NiTi alloys. In: IUTAM symposium on mechanics of martensitic phase transformation in solids. Springer, New York, pp 103–109
Sehitoglu H, Karaman I, Anderson R, Zhang X, Gall K, Maier HJ, Chumlyakov Y (2000) Compressive response of NiTi single crystals. Acta Mater 48(13):3311–3326
Acknowledgments
The work was supported by Nyquist Chair funds at University of Illinois. The authors acknowledge the assistance of Mr. George Li.
Author information
Authors and Affiliations
Corresponding author
Electronic Supplementary Material
Below is the link to the electronic supplementary material.
Appendices
Appendix 1: Eshelby Tensor for Anisotropic Media
The treatment follows that given by Mura [38]. The Eshelby’s tensor calculation is introduced in Eq. (8)
For the case of cubic material, the definition of \( \bar{G}_{ipjq} \) is presented in Eq. (16)
Specific terms in Eq. (16) can be represented as the following,
where λ is C 12, μ is C 44, μ′ is C 11–C 12–2C44, a 1, a 2, and a 3 are the semi axis align with the coordinate x, y and z. For the case of flat ellipsoid (a 1 > a 2 > a 3 ), ρ is assumed to be infinity (Fig. 15).
Appendix 2: The Weight Functions
Earlier, the calculation of weight function was introduced as the following.
Horizontal displacement u 1 and vertical displacement v 1 can be found earlier. The stress intensity factor K 1 is presented earlier as well as the elastic modulus H. A schematic showing a point load with a distance r and oriented at an angle of θ from the crack tip is presented in Fig. 16.
The weight function can be calculated as follows:
Appendix 3: 3D Elastic Moduli Representation
The elastic moduli tensor is represented with 3D images in Fig. 5 for Ni2FeGa. For completeness, we provide the moduli images for the two other alloys, NiTi and CuZnAl (Fig. 17).
Appendix 4: Transformation Strains
The lattice constants of three of the alloys considered result in the following transformation matrix which can be used to establish the transformation strains (Table 8).
The following equation can be used to establish the transformation strains, \( \varepsilon = \sqrt {\hat{e}^{T} F^{T} F\hat{e}} - 1 \) where \( F \) is the deformation gradient and is related to the transformation matrix given below by a unique rotation (\( F = RU\;{\text{and}}\;RR^{T} = I \)), and \( \hat{e} \) is any direction in which the transformation strain is calculated.
More detailed explanations can be found in Saburi and Nenno [30], Sehitoglu et al. [34] and in a textbook by Bhattacharya [43]. The volumetric strain can be obtained as \( \det (U) - 1 \). This volumetric strain was used to estimate the transformation strain in the third dimension when in-plane strains were measured via DIC.
The entire stereographic triangle for the three alloys is given in Fig. 18 showing the maximum transformation strains. We calculated the \( {\text{Ni}}_{2} {\text{FeGa}} \) and CuZnAl transformation strain stereographic triangles in this study while the NiTi stereographic triangle (the detwinning strain version) was published previously [43].
The important observation is that the transformation strains in all shape memory alloys considered are as high as 10 %. We point out that transformation strains were measured for the Ni2FeGa at the maximum and minimum loads and were used in the calculations. Because we do not have the experimental results of DIC measurements during fatigue crack growth for NiTi and CuZnAl, these strains were assumed to be the same magnitude as Ni2FeGa. Admittedly, this is a considerable effort that needs to be undertaken in future studies.
Appendix 5: Elastic Moduli Determination
An example of the energy variation as a function of the applied displacement fields is illustrated in Fig. 19 to establish the elastic constants in tetragonal Ni2FeGa.
In the following analysis, we demonstrate how to calculate the C 33 for tetragonal Ni2FeGa. We applied small strain (δ) varying from −0.03 to 0.03 to minimize the errors from higher order terms in the following equation:
The distortion matrix to calculate C 33 (see Table 2) is given by
Therefore, Eq. (20) becomes
We calculate the energy variation of the crystal subjected to different magnitudes of strain and the results are shown in Fig. 19b. The blue curve is a second-order polynomial function to fit these values, and can be written as follows:
We equate the second-order coefficient of Eq. (22) to the C 33 elastic constant in Eq. (21) (note that the energy unit is eV, and 1 eV = 1.6 × 10−19 J), and calculate the C 33 as follows:
Substituting the volume of the crystal (V o) to be 94.69 Å = 94.69 × 10−30 m3 into Eq. (23), we calculate the C 33 to be 212 GPa. All other elastic constants are calculated following similar procedure.
Rights and permissions
About this article
Cite this article
Wu, Y., Ojha, A., Patriarca, L. et al. Fatigue Crack Growth Fundamentals in Shape Memory Alloys. Shap. Mem. Superelasticity 1, 18–40 (2015). https://doi.org/10.1007/s40830-015-0005-4
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40830-015-0005-4