Highlights
-
Polarization is an exceptional physical property of light that carries and differentiates a significant amount of optical information. Perovskite materials are utilized in polarization-sensitive photodetectors owing to their crystal structure anisotropy and controllable orientation growth, in addition to their excellent photovoltaic performance.
-
This paper presents an overview of the structural characteristics and photovoltaic performance of different optical structures and low-dimensional perovskite polarization photodetectors. This summary will contribute to the future development of perovskite-based photodetectors that are sensitive to polarization.
Graphical Abstract
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
Polarization means symmetry loss for light vibration along light propagation direction, which is a particular physical property of light. The polarization state is indecipherable for most polarization-insensitive detectors. Polarization can carry and differentiate light information, and can be used in polarized light detection, polarization imaging, and encryption communication [1]. Photodetectors are the core component of some photoelectric devices [2] used in biomedical sensing, remote sensing, military field, etc.
An excellent photodetector (PD) can recognize all the properties of light, including intensity, frequency, and polarization. PDs capable of detecting polarized light need a specific optical structure or crystal structure. Lately, perovskite was used in polarization-sensitive PDs due to its controllable orientation growth and crystal structure anisotropy. In addition, compared with other polarization-sensitive materials like graphene [3], metal halide perovskites possess excellent photovoltaic performance. The strong light absorption and high carrier mobility of perovskite can be combined with its ability to recognize polarized light, thus yielding self-powered polarization-sensitive perovskite photodetectors (P-PPDs).
CsPbX3 perovskites were found to emit polarized light both in solution and in films in 2016 [4]. The study inspired people to explore the polarization detection capability of perovskites when used in optoelectronic devices. The research of P-PPDs was divided to linearly polarized light (LPL) and circularly polarized light (CPL). The electric field vector of CPL is rotary, so CPL has an axisymmetrically uniform distribution of the scattered field. Unlike CPL, the polarization direction of LPL is fixed, so linearly polarization-sensitive perovskite photodetectors (LP-PPDs) can detect periodic photoelectric signal changes. LP-PPDs can be realized by constructing an optical structure or by controlling crystal structure, which profits from the controllable growth orientation of perovskite and the anisotropy of lattice structure, respectively.
The optical structures of LP-PPDs refer to patterned perovskite active layers, including nanowire (NW) arrays, nanoribbon (NR) arrays, and so on. Most of these structures were fabricated by nano-imprinting, etching, or one-step self-assembly. Tang et al. [5] made LP-PPDs by one-step self-assembly of single-crystalline CH3NH3PbI3 NW arrays. The large length/width ratio of these 1D nanowires led to an anisotropy of 1.3. In addition, they improved the stability of CH3NH3PbI3 NWs by using oleic acid to passivate the surface defect of perovskite, obtaining a detectivity of 2 × 1013 Jones. Jiang et al. [6] prepared a 1D CsPbBr3 single crystal with rigid crystallographic alignment through an effective solution-processing method and assembled it to make LP-PPDs. The device realized an anisotropy ratio of 2.6, a dark current of 8.13 × 10–10 A, and a light on/off ratio of nearly 103. Ko et al. [7] used spin-coating method with solvent treatment to fabricate CH3NH3PbI3 NR arrays and LP-PPDs. Compared with CH3NH3PbI3 thin-film PPDs, NR arrays-based LP-PPDs showed higher detectivity due to effective photon management of grating-like NR structure. In the same year, Tang et al. [8] demonstrated a β-CsPbI3 NW-based LP-PPDs with a high anisotropy ratio of 2.68, which is also suitable for flexible substrate. The flexible device exhibited an anisotropy ratio of 2.17 and a low loss of photoelectric performance after 500 bending cycles. Though the above patterned structure-based LP-PPDs increased the polarization dimension of light, reducing the optical loss is crucial. Li et al. [9] designed a G-PC-PD by bonding a 1D nanograting with porous 2D photonic crystal (PC), which was inspired by the hierarchical architecture of the butterfly. The combination of 2D PC and nanograting contributed to the excellent light-harvesting ability of G-PC-PD, showing more than six times higher responsivity and detectivity than that of flat-film perovskite photodetectors. In 2021, a moiré LP-PPD with a double-nested grating was reported by Li et al. [10] Taking advantage of the waveguide effect of double-nested grating, and enhanced light-harvesting ability of top and bottom grating, a high responsivity of 15.62 A W−1 and a detectivity of 5.58 × 1013 Jones were achieved, respectively. The different optical structures of CH3NH3PbI3 are shown in Fig. 1. There are many other perovskite materials like CH3NH3PbBr3 and CH(NH2)2PbI3 served as surface-patterned LP-PPDs [, 11, 12] (Fig. 2). Though surface artificial nanostructure assists optical management and polarization of PDs, the perovskite instability is inescapable. Table 1 summarizes LP-PPDs based on different optical structures. Recently, Zhang et al. [13] reported PDs with in-situ encapsulated moiré lattice, which consist of two soft templates of nano-grating with rotation angles. The moiré lattice of CH3NH3PbBr3 led to strong light-harvesting capability and high anisotropy. The moiré LP-PPDs showed an ultrahigh detectivity of 1.05 × 1014 Jones, a responsivity of 1026.5 A W−1, and an anisotropy ratio of 9.1.
The structure for low-dimensional perovskites exhibits completely different optoelectronic properties from that of 3D perovskites. The optical anisotropy might be due to different bonding characteristic [14]. Using macromolecules to separate 3D perovskite is an effective way to realize polarization-sensitive detection. In 2019, 2D perovskite (iso-BA)2PbI4 single crystals were prepared to make a narrowband LP-PPD [15]. (iso-BA)2PbI4 possesses enhanced anisotropy, yielding a detectivity of 1.23 × 1010 Jones and an anisotropy ratio of 1.56 (Fig. 3a). Li et al. [16] also designed 2D perovskite [CH(NH2)2][C(NH2)3]PbI4 (FAGPbI4) with corrugated inorganic layer. The high anisotropy of FAGPbI4 was attributed to the existence of [PbI6]4− layer, offering an anisotropy ratio of 2. The polarized light can be produced by some crystal planes through the regulation of temperature. Although hybrid organic–inorganic 2D perovskite came to be used in polarization-sensitive photodetection, the synthetic method for high-quality 2D perovskites is still being explored. Sun et al. prepared 2D perovskite (FPEA)2PbI4 with low trap density by a minute-scale rapid crystallization [17]. And the high anisotropy ratio (2.1) of LP-PPD was thought to be caused by the physical property of 2D quantum-well structure, composed of organic cation barriers and inorganic perovskite wells (Fig. 3b). Besides, 2D inorganic perovskite advances in polarization-sensitive photodetection. In 2020, TRA was used to prepare 2D perovskite, yielding an anisotropy ratio of 2.1, and an on/off current ratio over 104 [18]. Though the crystal structure of 3D CsPbBr3 is isotropy, some molecules' introduction can turn it into anisotropy. Sun et al. also synthesized a Dion-Jacobson (DJ) type 2D perovskite (HDA)CsPb2Br7 by alloying diammonium into 3D CsPbBr3 [19]. The device exhibited an anisotropy ratio of 1.6, a detectivity of 1.5 × 109 Jones, and a high phase stability in environmental conditions. Some other 2D perovskites can improve the performances of LP-PPDs, and the anisotropy ratio reached 6.8 [20] (Fig. 3c), the detectivity and on/off ratio reached 1.53 × 1012 Jones and 3 × 108 [21] (Fig. 3d), respectively. Table 2 summarizes the performance of low-dimensional LP-PPDs.
In short, only specific perovskites can detect light polarization, based on the anisotropic crystal structure or the anisotropy of optical structure. Linearly polarization-sensitive perovskite photodetectors have been advancing since 2016. More efforts are needed to explore the method for achieving high anisotropy and stability.
References
C. Guo, F. Liu, S. Chen, C. Feng, Z. Zeng, Advances on exploiting polarization in wireless communications: channels, technologies, and applications. IEEE Commun. Surv. Tutor. 19(1), 125–166 (2017). https://doi.org/10.1109/COMST.2016.2606639
S. Frans, C.J. Julia, E. Michael, F. Silvano, H. David et al., An overview of polarimetric sensing techniques and technology with applications to different research fields. Proc. SPIE 9099, 90990B (2014). https://doi.org/10.1117/12.2053245
M. Ye, Y. Gao, J.J. Cadusch, S. Balendhran, K.B. Crozier, Mid-wave infrared polarization-independent graphene photoconductor with integrated plasmonic nanoantennas operating at room temperature. Adv. Opt. Mater. 9(6), 2001854 (2021). https://doi.org/10.1002/adom.202001854
D. Wang, D. Wu, D. Dong, W. Chen, J. Hao et al., Polarized emission from CsPbX3 perovskite quantum dots. Nanoscale 8(22), 11565–11570 (2016). https://doi.org/10.1039/C6NR01915C
L. Gao, K. Zeng, J. Guo, C. Ge, J. Du et al., Passivated single-crystalline CH3NH3PbI3 nanowire photodetector with high detectivity and polarization sensitivity. Nano Lett. 16(12), 7446–7454 (2016). https://doi.org/10.1021/acs.nanolett.6b03119
J. Feng, X. Yan, Y. Liu, H. Gao, Y. Wu et al., Crystallographically aligned perovskite structures for high-performance polarization-sensitive photodetectors. Adv. Mater. 29(16), 1605993 (2017). https://doi.org/10.1002/adma.201605993
S. Lim, M. Ha, Y. Lee, H. Ko, Large-area, solution-processed, hierarchical MAPbI3 nanoribbon arrays for self-powered flexible photodetectors. Adv. Opt. Mater. 6(21), 1800615 (2018). https://doi.org/10.1002/adom.201800615
Y. Zhou, J. Luo, Y. Zhao, C. Ge, C. Wang et al., Flexible linearly polarized photodetectors based on all-inorganic perovskite CsPbI3 nanowires. Adv. Opt. Mater. 6(22), 1800679 (2018). https://doi.org/10.1002/adom.201800679
Y. Zhan, Y. Wang, Q. Cheng, C. Li, K. Li et al., A butterfly-inspired hierarchical light-trapping structure towards a high-performance polarization-sensitive perovskite photodetector. Angew. Chem. Int. Ed. 58(46), 16456–16462 (2019). https://doi.org/10.1002/anie.201908743
Q. Song, Y. Wang, F. Vogelbacher, Y. Zhan, D. Zhu et al., Moiré perovskite photodetector toward high-sensitive digital polarization imaging. Adv. Energy Mater. 11(29), 2100742 (2021). https://doi.org/10.1002/aenm.202100742
J. Zhang, J. Zhao, Y. Zhou, Y. Wang, K.S. Blankenagel et al., Polarization-sensitive photodetector using patterned perovskite single-crystalline thin films. Adv. Opt. Mater. 9(17), 2100524 (2021). https://doi.org/10.1002/adom.202100524
X. Tian, R. Wang, Y. Xu, Q. Lin, Q. Cao, Triangular micro-grating via femtosecond laser direct writing toward high-performance polarization-sensitive perovskite photodetectors. Adv. Opt. Mater. 10(19), 2200856 (2022). https://doi.org/10.1002/adom.202200856
S.X. Li, H. Xia, T.Y. Liu, H. Zhu, J.C. Feng et al., In situ encapsulated moiré perovskite for stable photodetectors with ultrahigh polarization sensitivity. Adv. Mater. 35(3), 2207771 (2023). https://doi.org/10.1002/adma.202207771
T. Tong, M.-H. Lee, J. Zhang, Transformation of optical anisotropy origins in perovskite-related materials: a first-principles study. J. Phys. Chem. C 123(51), 31167–31174 (2019). https://doi.org/10.1021/acs.jpcc.9b08478
L. Li, L. Jin, Y. Zhou, J. Li, J. Ma et al., Filterless polarization-sensitive 2D perovskite narrowband photodetectors. Adv. Opt. Mater. 7(23), 1900988 (2019). https://doi.org/10.1002/adom.201900988
C. Fang, M. Xu, J. Ma, J. Wang, L. Jin et al., Large optical anisotropy in two-dimensional perovskite [CH(NH2)2][C(NH2)3]PbI4 with corrugated inorganic layers. Nano Lett. 20(4), 2339–2347 (2020). https://doi.org/10.1021/acs.nanolett.9b04777
M. Li, S. Han, B. Teng, Y. Li, Y. Liu et al., Minute-scale rapid crystallization of a highly dichroic 2D hybrid perovskite crystal toward efficient polarization-sensitive photodetector. Adv. Opt. Mater. 8(9), 2000149 (2020). https://doi.org/10.1002/adom.202000149
Y. Liu, J. Wang, S. Han, X. Liu, M. Li et al., Multilayered 2D cesium-based hybrid perovskite with strong polarization sensitivity: dimensional reduction of CsPbBr3. Chem. Eur. J. 26(16), 3494–3498 (2020). https://doi.org/10.1002/chem.201905531
T. Yang, Y. Li, S. Han, Z. Xu, Y. Liu et al., Highly-anisotropic Dion-Jacobson hybrid perovskite by tailoring diamine into CsPbBr3 for polarization-sensitive photodetection. Small 16(14), 1907020 (2020). https://doi.org/10.1002/smll.201907020
J. Wang, Y. Liu, S. Han, Y. Ma, Y. Li et al., Ultrasensitive polarized-light photodetectors based on 2D hybrid perovskite ferroelectric crystals with a low detection limit. Sci. Bull. 66(2), 158–163 (2021). https://doi.org/10.1016/j.scib.2020.06.018
Z. Han, W. Fu, Y. Zou, Y. Gu, J. Liu et al., Oriented perovskite growth regulation enables sensitive broadband detection and imaging of polarized photons covering 300–1050 nm. Adv. Mater. 33(11), 2003852 (2021). https://doi.org/10.1002/adma.202003852
C. Ji, D. Dey, Y. Peng, X. Liu, L. Li et al., Ferroelectricity-driven self-powered ultraviolet photodetection with strong polarization sensitivity in a two-dimensional halide hybrid perovskite. Angew. Chem. Int. Ed. 59(43), 18933–18937 (2020). https://doi.org/10.1002/anie.202005092
L. Lu, Y. Ma, J. Wang, Y. Liu, S. Han et al., Two-dimensional guanidine-based hybrid perovskites with strong dichroism for multiwavelength polarization-sensitive detection. Chem. Eur. J. 27(36), 9267–9271 (2021). https://doi.org/10.1002/chem.202100691
Acknowledgements
L. Ding thanks the National Key Research and Development Program of China (2022YFB3803300), the open research fund of Songshan Lake Materials Laboratory (2021SLABFK02), and the National Natural Science Foundation of China (21961160720).
Funding
Open access funding provided by Shanghai Jiao Tong University.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
About this article
Cite this article
Sun, J., Ding, L. Linearly Polarization-Sensitive Perovskite Photodetectors. Nano-Micro Lett. 15, 90 (2023). https://doi.org/10.1007/s40820-023-01048-y
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s40820-023-01048-y