Abstract
Groundwater evolution and its quality assessment in two contrasting geological terrains of southwestern Nigeria was undertaken. A total of 22 groundwater samples were collected with 11 groundwater samples representative of each geological terrain. The results of the water quality assessment showed that the waters from both environments are generally dominated by Ca2+, Cl−, and HCO3− ions. Okitipupa groundwaters are fresh, more acidic and of better quality due to its lesser total dissolved solids and other dissolved chemical ions that are of health concern than Ore groundwaters. Most of the major anions and cations in the water samples fall within World Health Organization (WHO) permissible limits but Water Quality Index (WQI) of Ore groundwater exhibit poor quality in greater proportion compared to Okitipupa groundwater which are all of good quality. Irrigation water quality results (SAR, MAR, RSC, PI and SSP) revealed that all the water samples from the two environments are suitable for agricultural purposes. However, the basement complex groundwaters are however of low, medium and high salinity hazard (SH) while the coastal sedimentary basin sourced groundwaters are made up of low and medium salinity hazard. Gibbs diagram revealed two similar mechanisms such as evaporation-crystallization and rock-weathering. From the Piper’s trilinear plots for the two environments, Ca–Cl water type predominate but Ca–HCO3 and Ca–SO4 water types can also be found in these environments. Deductions from the hydrogeochemical analysis and different statistical inferences employed for this study resulted in a model that establish the conjunctive imprints of anthropogenic and geogenic activities influencing the increasing dissolved chemical constituents in the groundwaters. This was actually resulted from the contrasting geological environments from where the waters were sourced. Nevertheless, groundwater from the two environments are suitable for domestic and irrigation purposes.
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Abrahao R, Garcia-Garizabal I, Merchan D, Causape J (2015) Climate change and the water cycle in nwelyu irrigated areas. Environ Monit Assess 187:22. https://doi.org/10.1007/s10661-014-4260-1
Aghazadeh N, Mogaddam AA (2011) Investigation of hydrochemical characteristics of groundwater in the Harzandat aquifer, Northwest of Iran. Environ Monit Assess 176:183–195
Ako AA, Shimada J, Hosono T, Ichiyanagi K, Nkeng GE, Eyong GET, Roger NN (2012) Hydrogeochemical and isotopic characteristics of groundwater in Mbanga, Njombe and Penja (Banana Plain)-Cameroon. J Afr Earth Sci 75:25–36
Alagbe SA (2006) Preliminary evaluation of hydrochemistry of the Kalambaina formation, Sokoto basin, Nigeria. Environ Geol 51:39–45
Al-Shaibani AM (2008) Hydrogeology and hydrochemistry of a shallow alluvial aquifer, western Saudi Arabia. Hydrogeology J 16:155–165
Anudu GK, Obrika SE, Onuba LN. Physico-chemical quality of groundwater in Abagana and its environs, Anambra basin, south-eastern Nigeria. Int J Chem Sci. 2008;1(2):296–301.
APHA (1995) Standard methods for the examination of water and waste water. 19th edn. American Public Health Association, Washington, pp 1–67
Appelo CAJ, Postma D (2005) Geochemistry, groundwater, and pollution, 2nd edn. Balkema, Amsterdam
Asiwaju-Bello YA, Olabode FO, Duvbiama OA, Iyamu JO, Adeyemo AA, Onigbinde MT (2013) Hydrochemical evaluation of groundwater in Akure Area, South-western Nigeria, for irrigation purpose. Eur Int J Sci Tech 2(8):235–249
Avannavar SM, Shrihari S (2008) Evaluation of water quality index for drinking purposes for river Netravathi, Mangalore, South India. Environ Monit Assess 143:279–290
Ayers RS, Westcot DW (1985) Water quality for agriculture FAO irrigation and drain paper no. 29(1), pp 1–109
Ayoade JO (1988) Tropical hydrology and water resources. Macmillan Publisher’s Ltd, London
Bozdag A, Gocmez G. Evaluation of groundwater quality in the Cihanbeyli basin, Konya, Central Anatolia, Turkey. Environ Earth Sci. 2013;69(3):921–37.
Bozdag A (2016) Assessment of the hydrogeochemical characteristics of groundwater in two aquifer sysetms in Cumra Plain, Central Anatolia. Environ Earth Sci 75:1–15. https://doi.org/10.1007/s12665-016-5518-4
Cabral JPS (2010) Water Microbiology. Bacterial Pathogens and Water. Int J Environ Res Public Health 7(10):3657–3703
Cey EE, Rudolph DL, Aravena R, Parkin G (1999) Role of the riparian zone in controlling the distribution and fate of agricultural nitrogen near a small stream in southern Ontario. J Contan Hydrol 37:45–67
Chae GT, Kim K, Yun KH, Kim SO, Choi BY, Kim HS, Rhee CW (2004) Hydrogeochemistry of alluvial groundwaters in an agricultural area: an implication for groundwater contamination susceptibility. Chemosphere 55:369–378
Daniele L, Vallejo A, Corbella M, Molina L, Pulido-Bosch A (2013) Hydrogeochemistry and geochemical simulations to assess water rock interactions in complex carbonate aquifers: the case of Aguadulce (SE Spain). Appl Geochem 29:43–54
Doneen LD (1964) Notes on water quality in agriculture. Published as a water science and engineering paper 4001. Department of Water Science and Engineering, University of California, California
Doneen LD (1966) Water quality requirement for agriculture. Proc. national sym. quality standards for natural waters. University of Michigan, Ann. Report, pp 213–218
Eaton FM (1950) Significance of carbonates in irrigation waters. Soil Sci 69:123–133
Ekakite AO, Akpoborie IA, Adaikpoh EO (2000) The quality of groundwater from dug wells in parts of the western Niger delta. J Natl Assoc Adv Knowl 2:72–77
Farnham IM, Johannesson KH, Singh AK, Hodged VF, Stetzenbach KJ (2003) Factor analytical approaches for evaluating groundwater trace element chemistry data, vol 490. Macmillan Publishers, London, pp 123–138
Freeze RA, Cherry JA (1979) Groundwater. Prentice-Hall Inc., Eagle Wood Cliffs, pp 491
Garcia-Garizabal I, Jose Gimeno M, Auque LF, Causape J (2014) Salinity contamination response to changes in irrigation management. Application of geochemical codes. Span J Agric Res 12(2):376–387
Garcia-Ruiz JM, Lopez-Moreno JI, Vicente-Serrano SM, Lasanta-Martinez T, Begueria S (2011) Mediterranean water resources in a global change scenario. Earth Sci Rev 105(3–4):121–139
Ghesquiere O, Walter J, Chesnaux R, Rouleau A. Scenarios of groundwater chemical evolution in a region of the Canadian Shield based on multivariate statistical analysis. J Hydrol Reg Stud. 2015;4:246–66.
Gibbs RJ (1970) Mechanisms controlling world water chemistry. Science 170:1088–1090
Gomo M, vanTonder GJ, Steyi G (2012) Investigation of the hydrochemical processes in an alluvial channel aquifer located in a typical Karoo basin of Southern Africa. Environ Earth Sci. https://doi.org/10.1007/s12665-012-2118-9
Goyer RA (1993) Lead toxicity: current concerns. Environ Health Perspect 100:177–187
Gupta SK, Gupta IC (1987) Management of saline soils and water. Oxford and IBH Publication Coy, New Delhi
Hem JD (1970) Study and interpretation of the chemical characteristics of natural waters. USGS water supply paper 1473, 2nd edn, US Government Printing Office, Washington, DC p 363
Hem JD (1985) Study and interpretation of the chemical characteristics of natural water. United States geological survey water supply paper 2254, 3rd edn, United States Government Printing Office Alexandria VA 22304, p 263
Hounslow AW (1995) Water quality data: analysis and interpretation. Lewis Publishers, New York, p 397
Howari FM, Banat KM (2002) Hydrochemical characteristics of Jordan and Yarmouk river waters: effect of natural and human activities. J Hydrol Hydromech 50(1):50
Irfan M, Said M (2008) Hydrochemical characteristics and the effects of irrigation on groundwater quality in Harran plain, GAP project, Turkey. Environ Geol 54:183–196
Ishaku AA, Ajumobi O, Olayinka A (2013) Implications of coliforms as a major public health problem in Nigeria (Review). J Public Health Epidemol 6(1):1–7
Jones HA, Hockey RD (1964) The geology of part of Southwestern Nigeria. Geol Surv Niger Bull 31:87
Kelley WP (1940) Permissible composition and concentration of irrigation waters. In: Proc. ASCE vol 66, pp 607–613
Kelley WP (1963) Use of saline irrigation water. Soil Sci 95(4):355–391
Kross BC, Hallberg GR, Bruner R, Cherryholmes K, Johnson KJ. The nitrate contamination of private well water in Iowa. Am J Public Health. 1993;83:270–2.
Kumar M, Kumari K, Singh UK, Ramanathan AL (2009) Hydrogeochemical processes in the groundwater environment of Muktsar, Punjab: conventional graphical and multivariate statistical approach. Environ Geol 57:873–884
Kumar M, Rao MS, Kumar B, Ramanathan A. Identification of aquifer-recharge zones and sources in an urban development area (Delhi, India), by correlating isotopic tracers with hydrological features. Hydrogeol J. 2011;19(2):463–74.
Kumar A, Bhawsar NG, Khandelwal S, Sakir SS, Ahuja S (2013) Physico-chemical parameters apply to analysis of drinking water from some selected area of Betul district, Madhya Pradesh. Int J Pharmaceut Chem Biol Sci 3:1109–14.
Kumar SK, Logeskumaran A, Magesh NS, Godson PS, Chnadrasekar N (2014) Hydrogeochemistry and application of water quality index (WQI) for groundwater quality assessment, Anna Nagar, part of Chennai city, Tamil Nadu, India. Appl Water Sci. https://doi.org/10.1007/s13201-014-0196-4
Kumar SV, Amarender B, Dhakate R, Sankaran S, Kumar KR (2016) Assessment of groundwater quality for drinking and irrigation use in shallow hard rock aquifer of Pudunagaram, Palakkad district Kerala. Appl Water Sci 6:149–167
Lloyd JW, Heathcote JA (1985) Natural inorganic hydrochemistry in relation to groundwater. Oxford Press, Oxford, p 296
MacDonald RI, Weber K, Padowski J, Florke M, Schneider C, Green PA, Gleeson T, Eckman S, Lehner B, Balk D, Boucher T, Grill G, Montgomery M (2014) Glob Environ Change 27:96–105
Magesh NS, Krishnakumar S, Chandrasekar N, Soundranayagam JP (2013) Groundwater quality assessment using WQI and GIS techniques, Dindigul district, Tamil Nadu, India. Arab J Geosci 6:4179–4189
Marghade D, Malpe DB, Zade AB (2012) Major ion chemistry of shallow groundwater of a fast growing city of Central India. Environ Monit Assess 184:2405–2418.
Matthess G (1982) The properties of groundwater. Wiley, New York
Mishra PC, Patel RK (2001) Study of the pollution load in the drinking water of Rairangpur, a small tribal dominated town of North Orissa. Indian J Environ Ecoplan 5(2):293–298
Mitra BK, Member ASABE (1998) Spatial and temporal variation of groundwater quality in sand dune area of Aomori prefecture in Japan
Moeller P, Rosenthal E, Geyer S, Guttman J, Dulski P, Rybakov M, Zilberbrand M, Jahnke C, Flexer A (2007) Hydrochemical processes in the lower Jordan valley and in the Dead Sea area. Chem geol 239(1–2):27–49
Mondal GC, Singh AK, Kumar S, Singh TB, Tewary BK, Sinha A (2008) Major ion chemistry, weathering processes and water quality assessment in upper catchment of Damodar river basin, India. Environ Geol 54:745–758
Montcoudiol N, Molson J, Lemieux JM (2014) Groundwater geochemistry of the Outaouasis region (Quebec, Canada): a regional-scale study. Hydrogeol J. https://doi.org/10.1007/s10040-014-1190-5
Mueller DK, Helsel DR (1996) Nutrients in the nation’s waters—too much of a good thing? US Geol Surv Circ 1136:24
Nagarajah S, Emerson NB, Abeykoon V, Yogalingam S (1988) Water quality of some wells in Jaffna and Killinochchi with special reference to nitrate pollution. Trop Agric 44:61–73
Naik S, Purohit KM (2001) Studies on water quality of river Brahmani in Sundargarh district, Orissa. Indian J Environ Ecoplan 5(2):397–402
Nigeria Geological Survey Agency (NGSA) (2006) Published by the Authority of the Federal Republic of Nigeria
NPC (2006) Report of Nigeria’s National Population Commission on the 2006 census. Popul Dev Rev 33(1):206–210
Obiefuna GI, Orazulike DM (2010) Assessment of groundwater quality of Yola area for irrigation purposes. Water Resour J Niger Assoc Hydrogeol 20(1):32–52
Odonkor ST, Ampofo JK (2013) Escherichia Coli as in indicator of bacteriological quality of water: an overview. Microbiol Res 4:1–11
Offodile ME (2014) Hydrogeology: ground water study and development in Nigeria, 3rd edn. Mecon Geology and Engineering Services Ltd., p 636
Okiongbo KS, Douglas RK (2015) Evaluation of major factors influencing the geochemistry using graphical and multivariate statistical methods in Yenagoa city, southern Nigeria. Appl Water Sci 5:27–37
Okogbue CO, Omonona OV, Aghamelu OP (2012) Qualitative assessment of groundwater from Egbe–Mopa basement complex area, north central Nigeria. Environ Earth Sci. https://doi.org/10.1007/s12665-012-1552-z. 10–12
Okosun EA (1998) Review of the early tertiary stratigraphy of southwestern Nigeria. J Min Geol 34:27–35
Olotu Y, Akinro AO, Mogaji KO, Ologunagba B (2009) Evaluation of water poverty index in Ondo State, Nigeria. ARPN J Eng App Sci 4(10):1–10
Omatsola ME, Adegoke OS (1981) Tectonic evolution and cretaceous stratigraphy of the Dahomey basin. J Min Geol 18(1):130–137
Omosuyi GO (2001) Geophysical and Hydrogeological Investigations of Groundwater Prospects in the Southern part of Ondo State, Nigeria. Thesis PhD, Department of Applied Geophysics, Federal University of Technology, Akure
Omosuyi GO, Ojo JS, Olorunfemi MO (2008) Geoelectric sounding to delineate shallow aquifers in the coastal plain sands of Okitipupa area, southwestern Nigeria. Pac J Sci Technol 9(2):562–577
Onwuka MA (1990) Groundwater resources of Lagos state. M.Sc Thesis (unpublished), University of Ibadan
Paliwal KV (1967) Effect of gypsum application on the quality of irrigation waters. Madras Agric J 59:646–647
Panno SV, Hackley KC, Hwang HH, Kelley WR (2001) Determination of the sources of nitrate contamination in karst springs using isotopic and chemical indicators. Chem Geol 179:113–128
Piper AM (1944) A graphic procedure in geochemical interpretation of water analysis. Trans Am Geophysics Union 25(6):914–928
Postma D, Boesen C, Kristiansen H, Larsen F (1991) Nitrate reduction in an unconfined sandy aquifer: water chemistry, reduction processes, and geochemical modeling. Water Resour Res 27:2007–2045
Puntoriero ML, Cirelli AF, Volpedo AV (2015) Geochemical mechanisms controlling the chemical composition of groundwater and surface water in the southwest of the Pampean plain (Argentina). J Geochem Explor 150:64–72
Raghaunath HM (1987) Groundwater. 2nd edn. Wiley, New Delhi, p 563
Rahaman MA (1988) Recent advances in the study of the basement complex of Nigeria Precambrian geology of Nigeria. Geol Surv Niger 3:11-41
Rahaman MA (1989) Review of the basement geology of south-western Nigeria. Department of Geology University of Ife, Ile-Ife, Nigeria. Rock View Ltd. Jos, Nigeria
Rajesh R, Brindha K, Murugan R, Elango L (2012) Influence of hydrogeochemical processes on temporal changes in groundwater quality in a part of Nalgonda district, Andra Pradesh, India. Environ Earth Sci 65:1203–1213
Redwan M, Abdel-Moneim AA (2015) Factors controlling groundwater hydrogeochemisty in the area west of Tahta, Sohag, Upper Egypt. J Afr Earth Sci. https://doi.org/10.1016/j.jafrearsci.2015.10.002
Richards LA (1954) Diagnosis and Improvement of saline and alkali soils. Agric. Handbook 60, USDA and IBH Publishing Company Limited, New Delhi, pp 98–99
Saeed MM, Ashrat M, Iqbal M (2001) Assessment of regional groundwater quality for irrigation: a case study of Jilh aquifer in Saudi Arabia. J Drain Water Manag 5(2):9–18
SarathPrasanth SV, Magesh NS, Jitheshlal KV, Chandrasekar N (2012) Evaluation of groundwater quality and its suitability for drinking and agricultural use in the coastal stretch of Alappuzha district, Kerala, India. Appl Water Sci 2(3):165–175
Sawyer GN, McMcartly DL (1967) Chemistry of sanitary engineers, 2nd edn. McGraw Hill, New York, p 518
Schoeller H (1962) Les eaux. Soutenaines Masson et Cie, Paris
Schoeller H (1964) La classification geochimique des eaux. General assembly of Berkeley 1963, vol 4. IASH Publication, Gentbrugge, pp 16–24
Schoeller H (1967) Qualitative evaluation of groundwater resources, methods and techniques of groundwater investigation and development. Water research, series-33. UNESCO, pp 45–52
Shahidullah SM, Hakim MA, Alam MS, Shansuddoha ATM (2008) Assessment of groundwater quality in a selected area of Bangladesh. Pak J Biol Sci 3(2):246–249
Shugg A (2014) Occurrence of high bicarbonate groundwater in Victoria, Australia. In: Balderer W, Porowski A, Idris H, LaMoreaux J (eds) Thermal and mineral waters. Environ. Earth Sci. Springer, Berlin, Heidelberg, pp 97–110
Siddiqui A, Naseem S, Jalil T (2005) Groundwater quality assessment in and around Kalu Khuhar, super highway, Sindh, Pakistan. J Appl Sci 5(7):1206–1265
Singh DF (1992) Studies on the water quality index of some major rivers of Pune, Maharashtra. Proc Acad Environ Biol 1(10):61–66
Singh AK, Hundal HS, Singh D (2011) Geochemistry and assessment of hydrogeochemical processes in groundwater in the southern part of Bathinda district of Punjab, northwest India. Environ Earth Sci 64:1823–1833
Srinivas Y, Hudson-Oliver D, Stanley RA, Chandrasekar N (2013) Evaluation of groundwater quality in and around Nagercoil town, Tamil Nadu, India: an integrated geochemical and GIS approach. Appl Water Sci 3:631–651
Srinivasamoorthy K, Chidambaram M, Prasanna MV, Vasanthavigar M, John-Peter A, Anandhan P (2008) Identification of major sources controlling groundwater chemistry from hard rock terrain—a case study from Mettur taluk, Salem district Tamilnadu, India. J Earth Syst Sci 117(1):49–58
Su YH, Feng Q, Gao-Feng Z, Si JH, Zhang YW (2007) Identification and evolution of groundwater chemistry in the Ejin sub-basin of the Heihe river, northwest China. Pedosphere 17(3):331–342
Su C, Wang Y, Pan Y (2013) Hydrogeochemical and isotopic evidences of the groundwater regime in Datong basin, Northern China. Environ Earth Sci 70:877–885
Subba Rao N (1997) Studies on water quality index in hard rock terrain of Guntur District, Andhra Pradesh, India. In: National seminar on hydrology of precambrian terrains and hard rock areas, pp 129–134
Subba Rao N (2006) Seasonal variation of groundwater quality in a part of Guntur district, Andhra Pradesh, India. Environ Geol 49:413–429
Subba Rao N, Prakasa Rao J, Devadas J, Srinivasa Rao D, Krishna KV, C., and Nagamalleswara Rao B (2002) Hydrogeochemistry and groundwater quality in a developing urban environment of a semi-arid region, Guntur, Andhra Pradesh, India. J Geol Soc India 59:159–166
Subramani T, Elango L, Damodarasamy SR (2005) Groundwater quality and its suitability for drinking and agricultural use in Chithar river basin, Tamil Nadu, India. Environ Geol 47:1099–1110
Szabolcs I, Darab C (1964) The influence of irrigation water of high sodium carbonate content of soils, vol II. In: Proceedings of 8th International Congress of Isss, Trans, pp 803–812
Tiwari TN, Mishra MA (1985) A preliminary assignment of water quality index of major indian rivers. Indian J Environ Prot 5:276–279
Todd DK (1980) Groundwater hydrology. Wiley, New York
Todd DK (2001) Groundwater hydrology. Wiley, Canada, pp 280–281
USDA (1954) Diagnosis and improvement of saline and alkali soils. USDA handbook no. 60, United States Department of Agriculture, Washington, DC, p 160
Varol S, Davraz A (2014) Assessment of geochemistry and hydrogeochemical processes in groundwater of the Tefenni plain (Burdur/Turkey). Environ Earth Sci 71:4657–4673
Vasanthavigar M, Srinivasamoorthy K, Vijayaravan R, Rajiv Ganthi R, Chidambaram S, Anandham P, Manivannan R, Vasudevan S (2010) Application of water quality index for groundwater quality assessment: Thirumanimuttar sub-basin Tamilnadu, India. Environ Monit Asess 171(1-4):595–609
WHO (1993) Guidelines for drinking-water quality, 2nd edn, vol 1. World Health Organization, Geneva
WHO (2011) Guidelines for drinking water-quality: first addendum to fourth edition volume I recommendation. World Health Organization, Geneva, p 595
Wilcox LV (1950) Classification and use of irrigation waters. USDA Circ. No. 696, Washington DC, p 16
Wilcox LV (1955) Classification and use of irrigation water, US Geological Department Agri Arc, vol 969, p 19
Zhang L, Song X, Jun X, Yuan R, Zhang Y, Liu X, Han D (2011) Major element chemistry of the Huai river basin, China. Appl Geochem 26:293–300
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Olofinlade, W.S., Daramola, S.O. & Olabode, O.F. Hydrochemical and statistical modeling of groundwater quality in two constrasting geological terrains of southwestern Nigeria. Model. Earth Syst. Environ. 4, 1405–1421 (2018). https://doi.org/10.1007/s40808-018-0486-1
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DOI: https://doi.org/10.1007/s40808-018-0486-1