Skip to main content
Log in

Geochemical evolution of groundwater along flow path in Upper Vellar sub basin, Tamilnadu, India: an integrated approach using hydrochemistry, modeling and statistical techniques

  • Original Article
  • Published:
Modeling Earth Systems and Environment Aims and scope Submit manuscript

Abstract

Hydrochemical, multivariate statistical, geochemical inverse and flow modeling techniques were attempted to examine groundwater recharge, flow and hydro chemical evolution along groundwater flow path in upper vellar hard rock aquifers. A total of 74 groundwater samples were collected and analyzed for different chemical constituents. Results revealed that three types of water facies were isolated as young, intermediate and matured type. Both hydrochemical and multivariate statistical analyses indicate groundwater in higher elevation observed with lower ionic ratios, plain and low lying areas with medium and higher ionic ratios respectively. Inverse geochemical modeling signify silicate minerals as precipitating and gypsum anhydride and NaCl species tend to dissolve due to limited availability of ions. Hydrochemical alteration seems to be influenced by rock water interaction, ion exchange and anthropogenic processes. .

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  • Aghazadeh N, Mogaddam AA (2011) Investigation of hydrochemical characteristics of groundwater in the Harzandat aquifer, Northwest of Iran. Environ Monit Assess. https://doi.org/10.1007/s10661-010-15754

    Google Scholar 

  • APHA (1995) Standard methods for the examination of water and wastewater, 19th edn. American Public Health Association, Washington

    Google Scholar 

  • Appelo CAJ, Postma D (1996) Geochemistry, groundwater and pollution. Balkema, Rotterdam

    Google Scholar 

  • Ashley RP, Lloyd JW (1978) An example of the use of factor analysis and cluster analysis in groundwater chemistry interpretation. J Hydrol. https://doi.org/10.1016/0022-1694(78)90011-2

    Google Scholar 

  • Belkhiri L, Mouni L, Tiri A (2011) Water–rock interaction and geochemistry of groundwater from the Ain Azel aquifer. Environ Geochem Health. https://doi.org/10.1007/s10653-011-9376-4

    Google Scholar 

  • Brindha K, Elango L (2013) Geochemistry of fluoride rich groundwater in a weathered granitic rock region, Southern India Water Qual Expo Health. https://doi.org/10.1007/s12403-013-0096-0

  • Chen K, Jiao JJ, Huang J, Huang R (2006) Multivariate statistical evaluation of trace elements in groundwater in a coastal area in Shenzhen, China. https://doi.org/10.1016/j.envpol.2006.09.002

  • Coetsiers M, Walraevens K (2006) Chemical characterization of the Neogene Aquifer, Belgium.” Hydrogeol J 14:1556–1568

    Article  Google Scholar 

  • Cruz JV, Franc Z (2006) Hydro geochemistry of thermal and mineral water springs of the Azores archipelago (Portugal). J of Volcanol Geothermal Res. https://doi.org/10.1016/j.jvolgeores.2005.09.001

    Google Scholar 

  • Demlie M, Wohnlich S, Wisotzky F (2007) Groundwater recharge, flow and hydrogeochemical evolution in a complex volcanic aquifer system, central Ethiopia. https://doi.org/10.1007/s10040-007-0163-3

  • Drever JI (1997) The geochemistry of natural waters. Prentice-Hall, New Jersey, 436p

    Google Scholar 

  • Guler C, Thyne GD (2004) Hydrologic and geologic factors controlling surface and groundwater chemistry in Indian Wells-Owens Valley area, southeastern California, USA. J Hydrol 285:177–198

    Article  Google Scholar 

  • Jayabalan M, Umamaheswaran G, Suresh A (2012) Petrology and geochemistry of Doloerite dykes of Dharmapuri and Salem districts of Tamil Nadu. Journal of Applied Geochemistry 14:52–68

    Google Scholar 

  • Ju XT, Kou CL, Zhang FS, Christie P (2006) Nitrogen balance and groundwater nitrate contamination: comparison among three intensive cropping systems on the North China. Plain Environ Pollut. https://doi.org/10.1016/j.envpol.2005.11.005

    Google Scholar 

  • Keurnenr DC, Bonrno M (1982) Halogen-bearing minerals from Airport Hill, Visakhapatnam, India. American Mineralogist, vol 67:pp 1001–1004

  • Lakshmanan E, Kannan R, Senthil Kumar M (2003) Major ion chemistry and identification of hydrogeochemical processes of ground water in a part of Kancheepuram district, Tamil Nadu, India. Environ Geosci https://doi.org/10.1306/eg100403011

    Google Scholar 

  • Langmuir D (1997) Aqueous environmental geochemistry. Prentice Hall Inc, p 601

  • Liu CW, Lin KH, Kuo YM (2003) Application of factor analysis in the assessment of groundwater quality in a blackfoot disease area in Taiwan. Sci Total Environ. https://doi.org/10.1016/S0048-9697(02)00683-6

    Google Scholar 

  • Moncaster SJ, Bottrell SH, Tellam JH, Lloyd JW, Konhause KO (2000) Migration and attenuation of agrochemical pollutants: insights from isotopic analysis of groundwater sulphate. J Contaminant Hydrol J Contaminant Hydrol 43:147–163

    Article  Google Scholar 

  • Motalane MP, Strydom CA (2004) Potential groundwater contamination by fluoride from two South African phosphor gypsums, ISSN 0378–4738 = Water SA vol 30 No

  • Nagaraju A, Sunil Kumar K, Thejaswi A (2014) Assessment of groundwater quality for irrigation: a case study from Bandalamottu lead mining area, Guntur District, Andhra Pradesh, South India. Appl Water Sci. https://doi.org/10.1007/s13201-014-0154-1

    Google Scholar 

  • Nageswara Rao PV, Appa Rao S, Subba Rao N (2015) Geochemical evolution of groundwater in the Western Delta region of River Godavari, Andhra Pradesh, India. Appl Water Sci. https://doi.org/10.1007/s13201-015-0294-y

    Google Scholar 

  • Nolan BT, Healy RW, Taber PE, Perkins K, Hitt KJ, Wolock DM (2007) Factors influencing ground-water recharge in the eastern United States. J Hydrol 332:187–205

    Article  Google Scholar 

  • Pekey H, Karaka D, Bakoglu M (2004) Source apportionment of trace metals in surface waters of a polluted stream using multivariate statistical analyses. Mar Pollut Bull 49:809–818

    Article  Google Scholar 

  • Pereiraa HG, Rencab S, Saraivaa J (2002) A case study on geochemical anomaly identification through principal components analysis supplementary projection

  • Power JF, Schepers JS (1989) Nitrate contamination of groundwater in North America agriculture, ecosystems and environment. https://doi.org/10.1016/0167-8809(89)90012-1

  • Prasanna MV, Chidambaram S, Hameed AS, Srinivasamoorthy K (2009) Study of evaluation of groundwater in Gadilam basin using hydrogeochemical and isotope data. Environ Monit Assess. https://doi.org/10.1007/s10661-009-1092-5

    Google Scholar 

  • Rajendrana S, Thirunavukkarasu A, Balamurugan G, Shankar K (2011) Discrimination of iron ore deposits of granulite terrain of Southern Peninsular India using ASTER data. J Asian Earth Sci. https://doi.org/10.1016/j.jseaes.2011.01.004

    Google Scholar 

  • Rao NS (2002) Geochemistry of groundwater in parts of Guntur district of AP, India. Environ Geol. https://doi.org/10.1007/s00250100431

    Google Scholar 

  • Rogers JR, Bennett PC (2003) Mineral stimulation of subsurface microorganisms: release of limiting nutrients from silicates. https://doi.org/10.1016/j.chemgeo.2003.09.00

  • Rupa Kumar K, Pant GB, Parthasarathy B, Sontakke NA (1992) Spatial and sub seasonal patterns of the long term trends of Indian summer monsoon rainfall. Int J Climatol. https://doi.org/10.1002/joc.3370120303

    Google Scholar 

  • Saravanan K, Srinivasamoorthy K, Prakash R, Gopinath S, Suma CS (2015) An evaluation of hydrogeochemistry of groundwater in Upper Vellar Sub-basin using mineral stability and solute transport modelling. https://doi.org/10.1016/j.aqpro.2015.02.142

  • Sharif MU, Davis RK, Steele KF, Kim B, Kresse TM, Fazio JA (2008) Inverse geochemical modeling of groundwater evolution with emphasis on arsenic in the Mississippi River Valley alluvial aquifer, Arkansas (USA. J of Hydrology. https://doi.org/10.1016/j.jhydrol.2007.11.027

    Google Scholar 

  • Singhal DC, Niwas S, Singhal BB (1998) Integrated approach to aquifer delineation in hard rock terrains—a case study from The Banda District, India. https://doi.org/10.1016/0022-1694(88)90212-0

  • Spalding RF, Exner ME (1993) Occurrence of nitrate in groundwater—a review. Published J Environ Qual 22:392–402

    Article  Google Scholar 

  • Srinivasamoorthy K, Nanthakumar C, Vasanthavigar M, Vijayaraghavan K, Rajivgandhi R, Chidambaram S, Anandhan P, Manivannan R, Vasudevan S (2009) Groundwater quality assessment from a hard rock terrain, Salem district of Tamilnadu, India. Arab J Geosci. https://doi.org/10.1007/s12517-009-0076

    Google Scholar 

  • Subba Rao N (2002) Geochemistry of groundwater in parts of Guntur districts in Andhra Pradesh, India. Environ Geol. https://doi.org/10.1007/s002540100431

    Google Scholar 

  • Subba Rao N, Surya Rao P, Venktram Reddy G, Nagamani M, Vidyasagar G, Satyanarayana NLVV (2011) Chemical characteristics of groundwater and assessment of groundwater quality in Varaha River Basin, Visakhapatnam District, Andhra Pradesh, India. Environ Monit Assess. https://doi.org/10.1007/s10661-011-2333-y

    Google Scholar 

  • Subburaj A (2008) District groundwater Brochure Salem District, Tamil Nadu, Government of India Ministry of Water Resources Central Ground Water Board

  • Subramani T, Rajmohan N, Elango L (2010) Groundwater geochemistry and identification of hydrogeochemical processes in a hard rock region, Southern India. Environ Monit Assess: 162:123–137. https://doi.org/10.1007/s10661-009-0781-4

    Article  Google Scholar 

  • Thirukumaran V, Kumanan CJ, Biswal TK (2014) Geoinformatic modeling of groundwater resource mapping of shear zone regions—a case study on Attur Valley, Tamil Nadu, India. J Indian Soc Rem Sens. https://doi.org/10.1007/s12524-014-0375-7

    Google Scholar 

  • Verma S, Phansalkar SJ (2007) India’s water future (2050) potential deviations from business-as-usual. Int J Rural Manag. https://doi.org/10.1177/097300520700300107

    Google Scholar 

  • Wada Y, van Beek LP, Sperna Weiland FC, Chao BF, Wu YH, Bierkens MF (2012) Past and future contribution of global groundwater depletion to sea-level rise. Geophys Res Lett. https://doi.org/10.1029/2012GL051230

    Google Scholar 

  • Yidanaa SM, Ophoria D, Banoeng-Yakubob B (2008) Multivariate statistical analysis of surface water chemistry data. The Ankobra Basin, Ghana. J of Environ Manag. https://doi.org/10.1016/j.jenvman.2006.11.023

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to K. Srinivasamoorthy.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Saravanan, K., Srinivasamoorthy, K., Gopinath, S. et al. Geochemical evolution of groundwater along flow path in Upper Vellar sub basin, Tamilnadu, India: an integrated approach using hydrochemistry, modeling and statistical techniques. Model. Earth Syst. Environ. 4, 647–658 (2018). https://doi.org/10.1007/s40808-017-0400-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40808-017-0400-2

Keywords

Navigation