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Extraction, Characterization and Anticorrosion Potential of an Essential Oil from Orange Zest as Eco-friendly Inhibitor for Mild Steel in Acidic Solution

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Abstract

Current research efforts now focus on the development of novel, cheaper, nontoxic, highly efficient and eco-friendly corrosion inhibitors as alternatives to different inorganic and organic compounds. In this context, orange zest essential oil (OZEO) was investigated as corrosion inhibitor for mild steel in 1 M HCl medium utilizing different techniques such as gas chromatography–mass spectrometry (GC–MS), mass loss, electrochemical and scanning electron microscope (SEM) associated with energy-dispersive X-ray spectroscopy (EDX). The obtained results indicated that this OZEO acted as an efficient corrosion inhibitor and the inhibition efficiency reached up to 75.64% at 2.5 g L−1 of OZEO. The potentiodynamic curves revealed that OZEO acted as mixed inhibitor with a predominantly anodic action, facilitating the formation of an adsorbed film over the mild steel surface. The adsorption data is fitted to Langmuir, Flory–Huggins, Freundlich, El-Awady, Temkin, Frumkin, Langmuir–Freundlich and Dubinin–Radushkevich isotherms models and involve chemisorption mechanism. SEM examination and EDX analysis of the mild steel surface confirmed the existence of a protective adsorbed film.

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Authors and Affiliations

  1. Laboratoire d’Ingénierie des Matériaux, de Modélisation et d’Environnement (LIMME), Université Sidi Mohamed Ben Abdellah USMBA, Faculté des Sciences, BP 1796, 30000, Fez-Atlas, Morocco

    Zakariae Bensouda, El Hassan El Assiri & Mouhcine Sfaira

  2. Laboratoire d’Ingénierie des Matériaux et Environnement: Modélisation et Application, Faculté des Sciences, Université Ibn Tofaïl, BP 133, 14000, Kenitra, Morocco

    Mohamed Ebn Touhami

  3. Laboratoire de Chimie Organique Appliquée, Université Sidi Mohamed Ben Abdellah USMBA, Faculté des Sciences et Techniques, Route Immouzer Fez, Fès, Morocco

    Abdellah Farah

  4. LCAE‒URAC18, Faculté des Sciences, Université Mohamed Premier, BP 717, 60000, Oujda, Morocco

    Belkhir Hammouti

Authors
  1. Zakariae Bensouda
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  2. El Hassan El Assiri
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  3. Mouhcine Sfaira
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  4. Mohamed Ebn Touhami
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  5. Abdellah Farah
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  6. Belkhir Hammouti
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Correspondence to Zakariae Bensouda.

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Bensouda, Z., El Assiri, E.H., Sfaira, M. et al. Extraction, Characterization and Anticorrosion Potential of an Essential Oil from Orange Zest as Eco-friendly Inhibitor for Mild Steel in Acidic Solution. J Bio Tribo Corros 5, 84 (2019). https://doi.org/10.1007/s40735-019-0276-y

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  • DOI: https://doi.org/10.1007/s40735-019-0276-y

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