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Performance enhancement of thin film LSCF cathodes by gold current collecting layer

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Abstract

Performance improvement of a thin film lanthanum strontium cobalt iron oxide (La0.6Sr0.4Co0.8Fe0.2O1-δ, LSCF) cathode deposited by pulsed laser deposition (PLD) was achieved by utilizing a sputtered gold (Au) film as a current collecting layer. To improve low inplane electric conductivity of the porous LSCF film due to its columnar structure, fabrication of the well-connected and porous current collector is applied by sputtering. The effects of the Au current collecting layer for solid oxide fuel cells (SOFCs) with the LSCF cathode are electrochemically characterized. The cell without the current collecting layer shows 14 Ω·cm2 of ohmic resistance, while the cell with the current collecting layer exhibits 5.5 Ω·cm2 of ohmic resistance at 550°C. In addition, the cell with the Au layer shows almost four times higher peak power density than the cell without the Au layer. Therefore, the results suggest that the sputtered Au current collecting layer enables fabrication of porous LSCF cathode with enhanced electric conductivity and improves the performance of the fuel cell.

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References

  1. Evans, A., Bieberle-Hütter, A., Rupp, J. L. M., and Gauckler, L. J., “Review on Microfabricated Micro-Solid Oxide Fuel Cell Membranes,” Jouranl of Power Sources, Vol. 194, No. 1, pp. 119–129, 2009.

    Article  Google Scholar 

  2. Shao, Z. and Haile, S. M., “A High-Performance Cathode for the Next Generation of Solid-Oxide Fuel Cells,” Nature, Vol. 431, pp. 170–173, 2004.

    Article  Google Scholar 

  3. Choi, H., Cho, G. Y., and Cha, S. W., “Fabrication and Characterization of Anode Supported YSZ/GDC Bilayer Electrolyte SOFC Using Dry Press Process,” Int. J. Precis. Eng. Manuf.-Green Tech., Vol. 1, No. 2, pp. 95–99, 2014.

    Article  Google Scholar 

  4. Steele, B. C. H., “Survey of Materials Selection for Ceramic Fuel Cells II. Cathodes and Anodes,” Solid State Ionics, Vols. 86–88, Part. 2, pp. 1223–1234, 1996.

    Article  Google Scholar 

  5. Gödickemeier, M., Sasaki, K., Gauckler, L. J., and Riess, I., “Perovskite Cathodes for Solid Oxide Fuel Cells based on Ceria Electrolytes,” Solid State Ionics, Vols. 86–88, Part. 2, pp. 691–701, 1996.

    Article  Google Scholar 

  6. Sun, C., Hui, R., and Roller, J., “Cathode Materials for Solid Oxide Fuel Cells: A Review,” Journal of Solid State Electrochemistry, Vol. 14, No. 7, pp. 1125–1144, 2010.

    Article  Google Scholar 

  7. Lee, J.-W., Liu, Z., Yang, L., Abernathy, H., Choi, S.-H., et al., “Preparation of Dense and Uniform La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF) Films for Fundamental Studies of SOFC Cathodes,” Journal of Power Sources, Vol. 190, No. 2, pp. 307–310, 2009.

    Article  Google Scholar 

  8. Dusastre, V. and Kilner, J. A., “Optimisation of Composite Cathodes for Intermediate Temperature SOFC Applications,” Solid State Ionics, Vol. 126, No. 1–2, pp. 163–174, 1999.

    Article  Google Scholar 

  9. Park, J., Chang, I., Paek, J. Y., Ji, S., Lee, W., et al., “Fabrication of the Large Area Thin-Film Solid Oxide Fuel Cells,” CIRP Annals-Manufacturing Technology, Vol. 63, No. 1, pp. 513–516, 2014.

    Article  Google Scholar 

  10. Huang, Q.-A., Hui, R., Wang, B., and Zhang, J., “A Review of AC Impedance Modeling and Validation in SOFC Diagnosis,” Electrochimica Acta, Vol. 52, No. 28, pp. 8144–8164, 2007.

    Article  Google Scholar 

  11. Fu, C., Sun, K., Zhang, N., Chen, X., and Zhou, D., “Electrochemical Characteristics of LSCF-SDC Composite Cathode for Intermediate Temperature SOFC,” Electrochimica Acta, Vol. 52, No. 13, pp. 4589–4594, 2007.

    Article  Google Scholar 

  12. Baumann, F. S., Fleig, J., Habermeier, H.-U., and Maier, J., “Impedance Spectroscopic Study on Well-Defined (La, Sr)(Co, Fe)O3-δ Model Electrodes,” Solid State Ionics, Vol. 177, No. 11–12, pp. 1071–1081, 2006.

    Article  Google Scholar 

  13. Das, R., Mebane, D., Koep, E., and Liu, M., “Modeling of Patterned Mixed-Conducting Electrodes and the Importance of Sheet Resistance at Small Feature Sizes,” Solid State Ionics, Vol. 178, No. 3–4, pp. 249–252, 2007.

    Article  Google Scholar 

  14. Mebane, D. S., Liu, Y., and Liu, M., “A Two-Dimensional Model and Numerical Treatment for Mixed Conducting Thin Films,” Journal of the Electrochemical Society, Vol. 154, No. 5, pp. A421–A426, 2007.

    Article  Google Scholar 

  15. Boukamp, B. A., Hildenbrand, N., Bouwmeester, H. J. M., and Blank, D. H. A., “Impedance of Thin Film Cathodes: Thickness and Current Collector Dependence,” Solid State Ionics, Vol. 283, pp. 81–90, 2015.

    Article  Google Scholar 

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Correspondence to Suk Won Cha.

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Yu, W., Lee, Y., Lee, Y.H. et al. Performance enhancement of thin film LSCF cathodes by gold current collecting layer. Int. J. of Precis. Eng. and Manuf.-Green Tech. 3, 185–188 (2016). https://doi.org/10.1007/s40684-016-0024-4

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  • DOI: https://doi.org/10.1007/s40684-016-0024-4

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