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Preparation of Au nanoparticles decorated polyaniline nanotube and its catalytic oxidation to ascorbic acid

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Abstract

With sulfonated electrospun polystyrene fiber as a template, uniform polyaniline(PANI) nanotubes were fabricated via polymerization of aniline followed by template removal. Au nanoparticles(Aunano) were decorated on the PANI nanotube successfully via auto-reduction of HAuCl4 on the PANI nanotube. The morphology of the nanotubes was characterized by means of scanning electron microscopy(SEM) and transmittance electron microscopy(TEM). By varying precursor concentration and incubation time, Aunano-PANI with different size of Aunano was obtained conveniently. Glassy carbon electrode modified with the Aunano decorated PANI nanotubes (Aunano-PANI/GCE) was prepared and used seccessfully for the catalytic oxidation of ascorbic acid(AA). The results of differential pulse voltammetry indicate that there is a good linear relationship between the peak currents and the concentrations of AA in the range of 5―3000 μmol/L, with the limit of detection of 1 μmol/L(S/N>3). There is no mutual interference between AA and dopamine. The electrode has been successfully applied in the detection of AA in vitamin C tablet sample.

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References

  1. Vonlanthen D., Lazarev P., See K. A., Wudl F., Heeger A. J., Adv. Mater., 2014, 26(30), 5095

    Article  CAS  Google Scholar 

  2. Xiao L. F., Cao Y. L., Xiao J., Schwenzer B., Engelhard M. H., Saraf L. V., Nie Z. M., Exarhos G. J., Adv. Mater., 2012, 24(9), 1176

    Article  CAS  Google Scholar 

  3. Jang J., Adv. Polym. Sci., 2006, 199, 189

    Article  CAS  Google Scholar 

  4. Chang H. X., Yuan Y., Shi N. L., Guan Y. F., Anal. Chem., 2007, 79(13), 5111

    Article  CAS  Google Scholar 

  5. Choudary B. M., Roy M., Roy S., Kantam M. L., Sreedhar B., Kumar K. V., Adv. Synth. Catal., 2006, 348(12/13), 1734

    Article  CAS  Google Scholar 

  6. Gallon B. J., Kojima R. W., Kaner R. B., Diaconescu P. L., Angew Chem. Int. Edit, 2007, 46(38), 7251

    Article  CAS  Google Scholar 

  7. Baker C. O., Shedd B., Tseng R. J., Martinez-Morales A. A., Ozkan C. S., Ozkan M., Yang Y., Kanert R. B., Acs Nano., 2011, 5(5), 3469

    Article  CAS  Google Scholar 

  8. Long Y. Z., Zhang L. J., Ma X. J., Chen Z. J., Wang N. L., Zhang Z., Wan M. X., Macromol Rapid Commun., 2003, 24(16), 938

    Article  CAS  Google Scholar 

  9. Dong H., Prasad S., Nyame V., Jones W. E., Chem Mater., 2004, 16(3), 371

    Article  CAS  Google Scholar 

  10. Parthasarathy R. V., Martin C. R., Chem. Mater., 1994, 6(10), 1627

    Article  CAS  Google Scholar 

  11. Miao Y. E., Fan W., Chen D., Liu T., ACS Appl. Mater. Interfaces, 2013, 5(10), 4423

    Article  CAS  Google Scholar 

  12. Amaya T., Saio D., Hirao T., Macromol. Symp., 2008, 270, 88

    Article  CAS  Google Scholar 

  13. Anilkumar P., Jayakannan M., Langmuir, 2008, 24(17), 9754

  14. Ding S. J., Zhang C. L., Yang M., Qu X. Z., Lu Y. F., Yang Z. Z., Polymer, 2006, 47(25), 8360

    Article  CAS  Google Scholar 

  15. Bao S. Y., Du M. L., Zhang M., Zhu H., Wang P., Yang T. T., Zou M. L., Chem. Eng. J., 2014, 258, 281

    Article  CAS  Google Scholar 

  16. Shirsat M. D., Bangar M. A., Deshusses M. A., Myung N. V., Appl. Phys. Lett., 2009, 94(8), 083502

    Article  Google Scholar 

  17. Liu X., Yang J., Tong L., Zhang Q., Li X., Chen J., Chem. Res. Chinese Universities, 2015, 31(5), 1062

    Article  CAS  Google Scholar 

  18. Bao S., Du M., Zhang M., Zhu H., Wang P., Yang T., Zou L., Chem. Eng. J., 2014, 258, 281

    Article  CAS  Google Scholar 

  19. Tseng R. J., Huang J. X., Ouyang J., Kaner R. B., Yang Y., Nano Letters, 2005, 5(6), 1077

    Article  CAS  Google Scholar 

  20. Li W. G., Jia Q. X., Wang H. L., Polymer, 2006, 47(1), 23

    Article  CAS  Google Scholar 

  21. Han J., Li L. Y., Guo R., Macromolecules, 2010, 43(24), 10636

    Article  CAS  Google Scholar 

  22. Uyar T., Besenbacher F., Polymer, 2008, 49(24), 5336

    Article  CAS  Google Scholar 

  23. You Y., Lee S. J., Min B. M., Park W. H., J. Appl. Polym. Sci., 2006, 99(3), 1214

    Article  CAS  Google Scholar 

  24. Sertchook H., Avnir D., Chem. Mater., 2003, 15(8), 1690

    Article  CAS  Google Scholar 

  25. Huang K., Wan M. X., Chem. Mater., 2002, 14(8), 3486

    Article  CAS  Google Scholar 

  26. McCarthy P. A., Huang J. Y., Yang S. C., Wang H. L., Langmuir, 2002, 18(1), 259

    Article  CAS  Google Scholar 

  27. Li G. C., Zhang Z. K., Macromolecules, 2004, 37(8), 2683

    Article  CAS  Google Scholar 

  28. Trakhtenberg S., Hangun-Balkir Y., Warner J. C., Bruno F. F., Kumar J., Nagarajan R., Samuelson L. A., J. Am. Chem. Soc., 2005, 127(25), 9100

    Article  CAS  Google Scholar 

  29. Neoh K. G., Pun M. Y., Kang E. T., Tan K. L., Synthetic. Met., 1995, 73(3), 209

    Article  CAS  Google Scholar 

  30. Ting Y. P., Neoh K. G., Kang E. T., Tan K. L., J. Chem. Technol. Biotechnol., 1994, 59(1), 31

    Article  CAS  Google Scholar 

  31. Li W., McCarthy P. A., Liu D. G., Huang J. Y., Yang S. C., Wang H. L., Macromolecules, 2002, 35(27), 9975

    Article  CAS  Google Scholar 

  32. Fadley C. S., Shirley D. A., J. Res. Natl. Bur. Stand. A, 1970, 74A, 543

    Article  Google Scholar 

  33. Smith J. A., Josowicz M., Engelhard M., Baer D. R., Janata J., PCCP, 2005, 7(20), 3619

    Article  CAS  Google Scholar 

  34. Sun C. L., Lee H. H., Yang J. M., Wu C. C., Biosens. Bioelectron., 2011, 26, 3450

    Article  CAS  Google Scholar 

  35. Ping J., Wu J., Wang Y., Ying Y., Biosens. Bioelectron., 2012, 34(1) 70

    Article  CAS  Google Scholar 

  36. Teymourian H., Salimi A., Khezrian S., Biosens. Bioelectron., 2013, 49(45), 1

    Article  CAS  Google Scholar 

  37. Kingsley M. P., Desai P. B., Srivastava A. K., J. Electroanal. Chem., 2015, 741, 71

    Article  CAS  Google Scholar 

  38. Ma Y., Zhao M. G., Cai B., Wang W., Ye Z. Z., Huang J. Y., Biosens. Bioelectron., 2014, 59(9), 384

    Article  CAS  Google Scholar 

  39. Wang S. Y., Zhang W., Zhong X., Chai Y. Q., Yuan R., Anal. Methods-UK, 2015, 7, 1471

    Article  CAS  Google Scholar 

  40. Xin Z., Yang C., Sha Y., Yang F., Xi P., Biosens. Bioelectron., 2013, 44(11), 183

    Google Scholar 

  41. Kul D., Ghica M. E., Pauliukaite R., Brett C. M. A., Talanta, 2013, 111(13), 76

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. State Environmental Protection Engineering Center for Pollution Treatment and Control in Textile Industry, College of Environmental Science and Engineering, Donghua University, Shanghai, 201620, P. R. China

    Xiaoyu Ma, Wenshu Cai, Guodong Zhu & Jianyun Liu

  2. Research Center for Analysis & Measurement, Donghua University, Shanghai, 201620, P. R. China

    Jianmao Yang

Authors
  1. Xiaoyu Ma
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  2. Jianmao Yang
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  3. Wenshu Cai
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  4. Guodong Zhu
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  5. Jianyun Liu
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Corresponding author

Correspondence to Jianyun Liu.

Additional information

Supported by the National Natural Science Foundation of China(Nos.21105009 and 21476047) and the Project of the State Key Laboratory of Electroanalytical Chemistry, China(No.SKLEAC201205).

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Ma, X., Yang, J., Cai, W. et al. Preparation of Au nanoparticles decorated polyaniline nanotube and its catalytic oxidation to ascorbic acid. Chem. Res. Chin. Univ. 32, 702–708 (2016). https://doi.org/10.1007/s40242-016-5460-8

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  • DOI: https://doi.org/10.1007/s40242-016-5460-8

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