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Chelating properties of salicylhydroxamic acid-functionalized polystyrene resins and its application to efficient removal of heavy metal ions from aqueous solutions

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Abstract

Salicylhydroxamic acid(SHA) was covalently bound onto crosslinked polystyrene spheres(CPSs) via the Friedel-Crafts alkylation reaction between chloromethylated CPSs and SHA in the presence of SnCl4 as the Lewis acid catalyst. The resulted SHA-CPSs possessed very strong chelating ability for heavy metal ions. In particular, the saturated adsorption amount of SHA-CPSs for Cu2+ ions could reach as high as 34.2 mg/g at 318 K. The chelating capability of SHA-CPSs towards heavy metal ions was pH and temperature dependent. SHA-CPSs also showed selective metal coordination with the chelating capacity decreasing in the order of Cu2+ >Zn2+>>Pb2+. The adsorption isotherms conformed well to the Langmuir model, and the adsorption process was found to be entropy-driven and endothermic. Besides, SHA-CPSs possessed the excellent reusability.

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References

  1. Dong J. B., Wu J. B., Yang J., Song W., Dai X. J., Ye Z. D., Gong B. L., Chem. J. Chinese Universities, 2013, 34(3), 714

    CAS  Google Scholar 

  2. Chen Y. N., Gao L., He M. F., Wei Y. M., Chem. J. Chinese Universities, 2014, 35(7), 1596

    CAS  Google Scholar 

  3. Zhang Q., Xia K., Liu L., Liu Y. C., Zhang C., Liu X., Xu H., Chen S. J., Chen J. D., Chem. J. Chinese Universities, 2013, 34(11), 2667

    CAS  Google Scholar 

  4. Cao C. Y., Qu J., Yan W. S., Zhu J. F., Wu Z. Y., Song W. G., Langmuir, 2012, 28(9), 4573

    Article  CAS  Google Scholar 

  5. Singh S., Barick K. C., Bahadur D., J. Mater. Chem. A, 2013, 1, 3325

    Article  CAS  Google Scholar 

  6. Yang L., Li Y., Jin X., Ye Z., Ma X., Wang L., Liu Y., Chem. Eng. J., 2011, 168(1), 115

    Article  CAS  Google Scholar 

  7. Xiong C. H., Zheng Y. Q., Feng Y. J., Yao C. P., Ma C. A., Zheng X. M., Jiang J. X., J. Mater. Chem., A, 2014, 2, 5379

    Article  CAS  Google Scholar 

  8. Hasanzadeh R., Moghadam P. N., Samadi N., Polym. Adv. Technol., 2013, 24(1), 34

    Article  CAS  Google Scholar 

  9. Xu J., Franklin S. J., Whisenhun D. W., Raymond K. N., J. Am. Chem. Soc., 1995, 117, 7245

    Article  CAS  Google Scholar 

  10. Zeng W., Zeng G. Y., Qin S. Y., Chin. J. Org. Chem., 2003, 23, 1213

    Article  CAS  Google Scholar 

  11. Jiao J., Fang H., Wang X. J., Guan P., Yuan Y. M., Xu W. F., Eur. J. Med. Chem., 2009, 44, 4470

    Article  CAS  Google Scholar 

  12. Li H. B., Qin C., Liang W., Wang L. P., Hao M. A., Jin B., Liang X. L., Qin S. Y., J. Mol. Catal., 2009, 23(1), 62

    Google Scholar 

  13. De Costa M. D. P., Jayasinghe W. A. P. A., J. Photochem. Photobiol., A, 2004, 162, 591

    Article  CAS  Google Scholar 

  14. Qiu X. Y., Gao Y. D., Nonferrous Metals, 2005, (6), 37

    Google Scholar 

  15. Yan B., Zhou C. C., Zhao X. R., Ren X. C., Light Metals, 2011, (4), 7

    Google Scholar 

  16. Jia L. P., Che X. K., Zheng Q., Zhang L., Metal Mine, 2011, (7), 106

    Google Scholar 

  17. Liu W. G., Wang B. Y., Dai S. J., Ma A. X., Wei D. Z., Non-ferrous Mining and Metallurgy, 2006, 22(4), 25

    Google Scholar 

  18. Lue C. L., Gao B. J., Liu Q., Qi C. S., Colloid Polym. Sci., 2008, 286, 553

    Article  Google Scholar 

  19. Lagergren S., Kung L., Svenska Vetenskapsakademien. Handlingar, 1898, 24, 1

    Google Scholar 

  20. Huang J. H., Jin X. Y., Mao J. L., Yuan B., Deng R. J., Deng S. G., J. Hazard. Mater., 2012, 217/218, 406

    Article  Google Scholar 

  21. Wang H. J., Kang J., Liu H. J., Qu J. H., J. Environ. Sci., 2009, 21, 1473

    Article  CAS  Google Scholar 

  22. Gong H. X., Hu P. Z., Jiang M. Y., Huang X. L., Shen T., Ge W. W., Pan S. D., Shen H. Y., Acta Chimica Sinica, 2011, 69(22), 2673

    CAS  Google Scholar 

  23. Saeed K., Haider S., Oh T. J., Park S. Y., J. Membr. Sci., 2008, 322, 400

    Article  CAS  Google Scholar 

  24. Gao B. J., Gao Y. C., Li Y. B., Chem. Eng. J., 2010, 158, 542

    Article  CAS  Google Scholar 

  25. Cestari A. R., Vieira E. F. S., Mattos C. R. S., J. Chem. Thermodyn., 2006, 38, 1092

    Article  CAS  Google Scholar 

  26. Anjos F. S. C., Vieira E. F. S., Cestaril A. R., J. Colloid Interface Sci., 2002, 253(2), 243

    Article  Google Scholar 

  27. Chen H., Wang A. Q., J. Hazard. Mater., 2009, 165, 223

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. School of Chemical and Environmental Engineering, North University of China, Taiyuan, 030051, P. R. China

    Ruixin Wang, Caiping Lei, Hongjing Wang & Xiaohui Shi

Authors
  1. Ruixin Wang
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  2. Caiping Lei
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  3. Hongjing Wang
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  4. Xiaohui Shi
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Corresponding author

Correspondence to Ruixin Wang.

Additional information

Supported by the National Young Scientists Fund of China(No.21307116), the Natural Science Foundation of Shanxi Province of China(No.2014011017-5), the Project for the Outstanding Innovative Teams of Higher Learning Institutions of Shanxi Province, China(No.201504) and the Fund Program for the Scientific Activities of Selected Returned Overseas Professionals in Shanxi Province, China(No.20140828).

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Wang, R., Lei, C., Wang, H. et al. Chelating properties of salicylhydroxamic acid-functionalized polystyrene resins and its application to efficient removal of heavy metal ions from aqueous solutions. Chem. Res. Chin. Univ. 31, 471–476 (2015). https://doi.org/10.1007/s40242-015-4476-9

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  • DOI: https://doi.org/10.1007/s40242-015-4476-9

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