Abstract
Four coumarin glycosides(1–4) and four coumarin triazoylglycosides(5–8) were synthesized by phase transfer catalytic glycosylation and copper-catalyzed azide-alkyne cycloaddition(CuAAC) respectively from 4-methyl-7-hydroxyl coumarin(4-methylumbelliferone). The structures were characterized by 1H NMR, MS or IR. The fluorescent properties of the coumarin glycosides and triazoylglycosides were studied in different solvents and compared to those of 4-methyl-7-hydroxyl coumarin.
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Support by the Personal Training Funds in National Basic Science of China(No.J1103312/J0104) and the Project of Science and Technology of Department of Education of Hunan Province, China(No.10B012).
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Wu, Z., Fu, Xl., Yang, N. et al. Synthesis and fluorescence properties of coumarin glycosides and triazoylglycosides. Chem. Res. Chin. Univ. 29, 460–465 (2013). https://doi.org/10.1007/s40242-013-2487-y
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DOI: https://doi.org/10.1007/s40242-013-2487-y