Skip to main content
Log in

Study on Micron Porous Copper Prepared by Physical Vacuum Dealloying

  • Published:
Acta Metallurgica Sinica (English Letters) Aims and scope

Abstract

Porous copper was prepared successfully by physical vacuum dealloying method using the CuZn alloy precursors (Cu30Zn70, Cu40Zn60 and Cu50Zn50 alloys). The micron porous copper showed a three-dimensional continuous porous structure with 1–5 μm pore size. With the increase of the Zn content in the CuZn alloy, the pore structure of the porous copper was more uniform and ordered. Temperature was the key factor for physical dealloying, and the optimized temperature was 500 °C for the CuZn alloy. The pores would fuse and disappear when the temperature was over 500 °C. Physical vacuum dealloying was an effective preparation method for porous copper, which can be used to prepare other porous metals based on the sublimation and the Kirkendall effect.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. H. Nakajima, Prog. Mater. Sci. 52, 1091 (2007)

    Article  Google Scholar 

  2. P. Liu, B. Yu, A. Hu, K. Liang, S. Gu, J. Mater. Sci. Technol. 18, 299 (2002)

    Article  Google Scholar 

  3. B. Li, X. Lu, Acta Metall. Sin. (Engl. Lett.) 27, 338 (2014)

    Article  Google Scholar 

  4. A. Smith, D. Trimm, Annu. Rev. Mater. Res. 35, 127 (2005)

    Article  Google Scholar 

  5. Y. Zhao, T. Fung, L. Zhang, Scr. Mater. 52, 295 (2005)

    Article  Google Scholar 

  6. R. Mao, S. Liang, X. Wang, Q. Yang, B. Han, Corros. Sci. 60, 231 (2012)

    Article  Google Scholar 

  7. Y. Lin, C. Tai, I. Sun, J. Electrochem. Soc. 154, D316 (2007)

    Article  Google Scholar 

  8. J. Li, H. Jiang, N. Yu, C. Xu, H. Geng, Corros. Sci. 90, 216 (2015)

    Article  Google Scholar 

  9. C. Zhao, Z. Qi, X. Wang, Z. Zhang, Corros. Sci. 51, 2120 (2009)

    Article  Google Scholar 

  10. J. Hayes, A. Hodge, J. Biener, A. Hamza, K. Sieradzki, J. Mater. Res. 21, 2611 (2006)

    Article  Google Scholar 

  11. H. Lu, Y. Li, F. Wang, Scr. Mater. 56, 165 (2007)

    Article  Google Scholar 

  12. J. Erlebacher, M. Aziz, A. Karma, N. Dimitrov, K. Sieradzki, Nature 410, 450 (2001)

    Article  Google Scholar 

  13. A. Chen, S. Shi, Y. Qiu, X. Xie, H. Ruan, J. Gu, D. Pan, Microporous Mesoporous Mater. 202, 50 (2015)

    Article  Google Scholar 

  14. Y. Ren, Y. Sun, K. Xiao, K. Yang, Chinese invention patent. 201410181273.0 (2014)

  15. Y. Sun, Y. Ren, K. Yang, Mater. Lett. 165, 1 (2016)

    Article  Google Scholar 

  16. Y. Sun, Y. Ren, Vacuum 122, 215 (2015)

    Article  Google Scholar 

  17. R.E. Honig, D.A. Kramer, RCA Rev. 30, 285 (1969)

    Google Scholar 

  18. E. Kirkendall, L. Thomassen, C. Upthegrove, Trans. AIME 133, 186 (1939)

    Google Scholar 

  19. Y. Yin, R. Rioux, C. Erdonmez, S. Hughes, G. Somorjai, A. Alivisatos, Science 304, 711 (2004)

    Article  Google Scholar 

  20. H. Fan, U. Gösele, M. Zacharias, Small 3, 1660 (2007)

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by the National Natural Science Foundation of China (Grant No. 31370976) and the National Basic Research Program of China (Grant No. 2012CB619101).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yi-Bin Ren.

Additional information

Available online at http://link.springer.com/journal/40195

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ren, YB., Sun, YX. & Yang, K. Study on Micron Porous Copper Prepared by Physical Vacuum Dealloying. Acta Metall. Sin. (Engl. Lett.) 29, 1144–1147 (2016). https://doi.org/10.1007/s40195-016-0505-z

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40195-016-0505-z

Keywords

Navigation