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Corrosion Behavior of MgZnCa Bulk Amorphous Alloys Fabricated by Spark Plasma Sintering

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Acta Metallurgica Sinica (English Letters) Aims and scope

Abstract

Centimeter-sized Mg65Zn30Ca5 bulk amorphous alloys were fabricated by the spark plasma sintering process from the amorphous powders with a size smaller than 5 μ m prepared by ball-milling. The sintered Mg65Zn30Ca5 samples were in an amorphous state when the spark plasma sintering was performed at a temperature of 383 K under a pressure of 600 MPa. The data of polarization curves presented that the sintered Mg65Zn30Ca5 bulk amorphous alloys exhibited higher corrosion resistance than pure Mg and AZ31B alloy owing to high content of Zn and homogeneous structure. A calcium phosphate compound layer was formed on the sintered Mg65Zn30Ca5 bulk amorphous sample after immersion in Hanks’ solution, which is effective in improving corrosion resistance and bioactivity. The sintered MgZnCa bulk amorphous alloys with large dimensions broaden the potential application of bulk amorphous alloys in the biomedical fields.

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Acknowledgments

This work is financially supported by the Natural Science Foundation of China under Grant No. 51301091, the Natural Science Foundation of Jiangsu Province Grant No. BK20151536, the Fundamental Research Funds for the Central Universities No. AE16001 and the Advanced Materials Development and Integration of Novel Structured Metallic and Inorganic Materials from the Ministry of Education, Sport, Culture, Science and Technology, Japan.

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Authors and Affiliations

  1. School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing, 210094, China

    Feng-Xiang Qin & Chuan Ji

  2. Institute for Materials Research, Tohoku University, Sendai, 980-8577, Japan

    Feng-Xiang Qin, Zhen-Hua Dan, Guo-Qiang Xie, Shin-Ichi Yamaura & Mitsuo Niinomi

  3. College of Materials Science and Engineering, Nanjing TECH University, Nanjing, 210009, China

    Zhen-Hua Dan

  4. WPI-AIMR, Tohoku University, Sendai, 980-8577, Japan

    Hao Wang

  5. Dongguan Eontech Co., Ltd, Dongguan, 523662, China

    Yang-De Li

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  1. Feng-Xiang Qin
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  2. Chuan Ji
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  4. Guo-Qiang Xie
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  6. Shin-Ichi Yamaura
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Correspondence to Feng-Xiang Qin or Zhen-Hua Dan.

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Available online at http://link.springer.com/journal/40195

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Qin, FX., Ji, C., Dan, ZH. et al. Corrosion Behavior of MgZnCa Bulk Amorphous Alloys Fabricated by Spark Plasma Sintering. Acta Metall. Sin. (Engl. Lett.) 29, 793–799 (2016). https://doi.org/10.1007/s40195-016-0451-9

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  • DOI: https://doi.org/10.1007/s40195-016-0451-9

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