Abstract
Environmental pollution has become a matter of great concern in the age of modern industrialization. Severe contamination in the form of dyes can cause serious health hazard in the community, killing fishes inside water, damaging fertility of the land and aquatic lives as well. All possible treatment methods are discussed to critically assess the technologies for obtaining ecofriendly discharge. High cost, technical hurdles, potential environmental and human risk are the major challenges faced by different physical, chemical and biological techniques. To overcome these barriers, photocatalysis with semiconductor nanostructured materials is a green technology approach that has been widely functional particularly in environmental remediation field. Nanostructured WO3 used as a photocatalyst that is within the visible light responsive up to ca. 480 nm having multifunctional advantages of cost-effective, harmlessness, durability and stability in acidic conditions as well. It makes us confident that WO3-based nanostructured materials by prudently steering its direction while evading accidental concerns can offer healthy solutions to wastewater treatment challenges.
Similar content being viewed by others
References
Adhikari R, Gyawali G, Sekino T, Lee SW (2013) Microwave assisted hydrothermal synthesis of Ag/AgCl/WO3 photocatalyst and its photocatalytic activity under simulated solar light. J Solid State Chem 197:560–565
Altuntaş EÇ, Turan SL (2018) Awareness of secondary school students about renewable energy sources. Renew Energy 116:741–748
Aslam I, Cao C, Khan WS, Tanveer M, Abid M, Idrees F, Ali Z (2014) Synthesis of three-dimensional WO3 octahedra: characterization, optical and efficient photocatalytic properties. RSC Adv 4(71):37914–37920
Ayyaru S, Dharmalingam S (2014) Enhanced response of microbial fuel cell using sulfonated poly ether ether ketone membrane as a biochemical oxygen demand sensor. Anal Chim Acta 818:15–22
Balaji S, Djaoued Y, Albert A-S, Ferguson RZ, Brüning R (2009) Hexagonal tungsten oxide based electrochromic devices: spectroscopic evidence for the Li ion occupancy of four-coordinated square windows. Chem Mater 21(7):1381–1389
Barka N, Assabbane A, Aît Ichou Y, Nounah A (2006) Decantamination of textile wastewater by powdered activated carbon. J Appl Sci 6:692–695
Barka N, Ouzaouit K, Abdennouri M, El Makhfouk M (2013) Dried prickly pear cactus (Opuntia ficus indica) cladodes as a low-cost and eco-friendly biosorbent for dyes removal from aqueous solutions. J Taiwan Inst Chem Eng 44(1):52–60
Batista LMB, dos Santos AJ, da Silva DR, de Melo Alves AP, Garcia-Segura S, Martínez-Huitle CA (2017) Solar photocatalytic application of NbO2OH as alternative photocatalyst for water treatment. Sci Total Environ 596:79–86
Benedek J, Sebestyén T-T, Bartók B (2018) Evaluation of renewable energy sources in peripheral areas and renewable energy-based rural development. Renew Sustain Energy Rev 90:516–535
Benghazi L, Record E, Suárez A, Gomez-Vidal JA, Martínez J, De La Rubia T (2014) Production of the Phanerochaete flavido-alba laccase in Aspergillus niger for synthetic dyes decolorization and biotransformation. World J Microbiol Biotechnol 30(1):201–211
Boulova M, Lucazeau G (2002) Crystallite nanosize effect on the structural transitions of WO3 studied by Raman spectroscopy. J Solid State Chem 167(2):425–434
Bratkova S, Lavrova S, Angelov A, Nikolova K, Ivanov R, Koumanova B (2018) Treatment of wastewaters containing Fe, Cu, Zn and As by microbial hydrogen sulfide and subsequent removal of COD, N and P. J Chem Technol Metall 53(2):245–257
Chakrapani V, Thangala J, Sunkara MK (2009) WO3 and W2N nanowire arrays for photoelectrochemical hydrogen production. Int J Hydrog Energy 34(22):9050–9059
Chan SHS, Yeong Wu T, Juan JC, Teh CY (2011) Recent developments of metal oxide semiconductors as photocatalysts in advanced oxidation processes (AOPs) for treatment of dye waste-water. J Chem Technol Biotechnol 86(9):1130–1158
Chatterjee D, Dasgupta S (2005) Visible light induced photocatalytic degradation of organic pollutants. J Photochem Photobiol C 6(2–3):186–205
Chen SH, Ting ASY (2015) Biodecolorization and biodegradation potential of recalcitrant triphenylmethane dyes by Coriolopsis sp. isolated from compost. J Environ Manag 150:274–280
Cho IS, Chen Z, Forman AJ, Kim DR, Rao PM, Jaramillo TF, Zheng X (2011) Branched TiO2 nanorods for photoelectrochemical hydrogen production. Nano Lett 11(11):4978–4984
Choi S, Johnston MV, Wang G-S, Huang C (2017) Looking for engineered nanoparticles (ENPs) in wastewater treatment systems: qualification and quantification aspects. Sci Total Environ 590:809–817
Daud SM, Kim BH, Ghasemi M, Daud WRW (2015) Separators used in microbial electrochemical technologies: current status and future prospects. Biores Technol 195:170–179
Di Valentin C, Wang F, Pacchioni G (2013) Tungsten oxide in catalysis and photocatalysis: hints from DFT. Top Catal 56(15–17):1404–1419
Djurišić AB, Leung YH, Ng AMC (2014) Strategies for improving the efficiency of semiconductor metal oxide photocatalysis. Mater Horiz 1(4):400–410
Gerand B, Nowogrocki G, Guenot J, Figlarz M (1979) Structural study of a new hexagonal form of tungsten trioxide. J Solid State Chem 29(3):429–434
Gillet M, Aguir K, Lemire C, Gillet E, Schierbaum K (2004) The structure and electrical conductivity of vacuum-annealed WO3 thin films. Thin Solid Films 467(1–2):239–246
Gogate PR, Pandit AB (2004) A review of imperative technologies for wastewater treatment I: oxidation technologies at ambient conditions. Adv Environ Res 8(3–4):501–551
Gondal M, Bagabas A, Dastageer A, Khalil A (2010) Synthesis, characterization, and antimicrobial application of nano-palladium-doped nano-WO3. J Mol Catal A Chem 323(1–2):78–83
Gu G, Zheng B, Han W, Roth S, Liu J (2002) Tungsten oxide nanowires on tungsten substrates. Nano Lett 2(8):849–851
Gu Z, Ma Y, Yang W, Zhang G, Yao J (2005) Self-assembly of highly oriented one-dimensional h-WO3 nanostructures. Chem Commun 28:3597–3599
Gürses A, Hassani A, Kıranşan M, Açışlı Ö, Karaca S (2014) Removal of methylene blue from aqueous solution using by untreated lignite as potential low-cost adsorbent: kinetic, thermodynamic and equilibrium approach. J Water Process Eng 2:10–21
Hayat H, Mahmood Q, Pervez A, Bhatti ZA, Baig SA (2015) Comparative decolorization of dyes in textile wastewater using biological and chemical treatment. Sep Purif Technol 154:149–153
Hemberg A, Konstantinidis S, Viville P, Renaux F, Dauchot J, Llobet E, Snyders R (2012) Effect of the thickness of reactively sputtered WO3 submicron thin films used for NO2 detection. Sens Actuators B Chem 171:18–24
Hernández-Fernández F, de los Ríos AP, Mateo-Ramírez F, Godínez C, Lozano-Blanco L, Moreno J, Tomás-Alonso F (2015) New application of supported ionic liquids membranes as proton exchange membranes in microbial fuel cell for waste water treatment. Chem Eng J 279:115–119
Ho G, Chua K, Siow D (2012) Metal loaded WO3 particles for comparative studies of photocatalysis and electrolysis solar hydrogen production. Chem Eng J 181:661–666
Hossain M, Mahmud M, Parvez M, Cho HM (2013) Impact of current density, operating time and pH of textile wastewater treatment by electrocoagulation process. Environ Eng Res 18(3):157–161
Huang J, Xu X, Gu C, Fu G, Wang W, Liu J (2012) Flower-like and hollow sphere-like WO3 porous nanostructures: selective synthesis and their photocatalysis property. Mater Res Bull 47(11):3224–3232
Huang J, Xiao L, Yang X (2013) WO3 nanoplates, hierarchical flower-like assemblies and their photocatalytic properties. Mater Res Bull 48(8):2782–2785
Hunge Y, Mahadik M, Mohite V, Kumbhar S, Deshpande N, Rajpure K, Bhosale C (2016) Photoelectrocatalytic degradation of methyl blue using sprayed WO3 thin films. J Mater Sci Mater Electron 27(2):1629–1635
Janáky C, Rajeshwar K, De Tacconi N, Chanmanee W, Huda M (2013) Tungsten-based oxide semiconductors for solar hydrogen generation. Catal Today 199:53–64
Jia J, Wu A, Luan S (2014) Spectrometry recognition of polyethyleneimine towards heavy metal ions. Colloids Surf A 449:1–7
Jin YZ, Zhu YQ, Whitby RL, Yao N, Ma R, Watts PC, Walton DR (2004) Simple approaches to quality large-scale tungsten oxide nanoneedles. J Phys Chem B 108(40):15572–15577
Kim J, Lee CW, Choi W (2010) Platinized WO3 as an environmental photocatalyst that generates OH radicals under visible light. Environ Sci Technol 44(17):6849–6854
Korotaeva NE, Ivanova MV, Suvorova GG et al (2018) The impact of the environmental factors on the photosynthetic activity of common pine (Pinus sylvestris) in spring and in autumn in the region of Eastern Siberia. J For Res 29(6):1465–1473
Kulkarni AN, Kadam AA, Kachole MS, Govindwar SP (2014) Lichen Permelia perlata: a novel system for biodegradation and detoxification of disperse dye Solvent Red 24. J Hazard Mater 276:461–468
Kumar SG, Rao KK (2015) Tungsten-based nanomaterials (WO3 & Bi2WO6): modifications related to charge carrier transfer mechanisms and photocatalytic applications. Appl Surf Sci 355:939–958
Kuti LM, Bhella SS, Thangadurai V (2009) Revisiting tungsten trioxide hydrates (TTHs) synthesis-is there anything new? Inorg Chem 48(14):6804–6811
Lee WH, Lai CW, Hamid SBA (2015) One-step formation of WO3-loaded TiO2 nanotubes composite film for high photocatalytic performance. Materials 8(5):2139–2153
Leong JX, Daud WRW, Ghasemi M, Liew KB, Ismail M (2013) Ion exchange membranes as separators in microbial fuel cells for bioenergy conversion: a comprehensive review. Renew Sustain Energy Rev 28:575–587
Li Q-H, Wang L-M, Chu D-Q, Yang X-Z, Zhang Z-Y (2014) Cylindrical stacks and flower-like tungsten oxide microstructures: controllable synthesis and photocatalytic properties. Ceram Int 40(3):4969–4973
Liu R, Lin Y, Chou LY, Sheehan SW, He W, Zhang F, Wang D (2011) Water splitting by tungsten oxide prepared by atomic layer deposition and decorated with an oxygen-evolving catalyst. Angew Chem Int Ed 50(2):499–502
Lou XW, Zeng HC (2003) An inorganic route for controlled synthesis of W18O49 nanorods and nanofibers in solution. Inorg Chem 42(20):6169–6171
Ma B, Guo J, Dai WL, Fan K (2012) Ag-agcl/WO3 hollow sphere with flower-like structure and superior visible photo-catalytic activity. Appl Catal B Environ 123–124:193–199
Martínez-de la Cruz A, Martínez DS, Cuéllar EL (2010) Synthesis and characterization of WO3 nanoparticles prepared by the precipitation method: evaluation of photocatalytic activity under vis-irradiation. Solid State Sci 12(1):88–94
Monllor-Satoca D, Borja L, Rodes A, Gómez R, Salvador P (2006) Photoelectrochemical behavior of nanostructured WO3 thin-film electrodes: the oxidation of formic acid. ChemPhysChem 7(12):2540–2551
Mu W, Xie X, Li X, Zhang R, Yu Q, Lv K, Jian Y (2014) Characterizations of Nb-doped WO3 nanomaterials and their enhanced photocatalytic performance. RSC Adv 4(68):36064–36070
Potti PR, Srivastava VC (2012) Comparative studies on structural, optical, and textural properties of combustion derived ZnO prepared using various fuels and their photocatalytic activity. Ind Eng Chem Res 51(23):7948–7956
Potti PR, Srivastava VC (2013) Effect of dopants on ZnO mediated photocatalysis of dye bearing wastewater: a review. Paper presented at the materials science forum
Pudukudy M, Yaakob Z, Rajendran R (2013) Visible light active novel WO3 nanospheres for methylene blue degradation. J Pharma Chem 5:208–212
Qamar M, Gondal MA, Yamani ZH (2010) Removal of Rhoda mine 6G induced by laser and catalyzed by Pt/WO3 nano composite. Catal Commun 11:768–772
Qi H, Wang C, Liu J (2003) A Simple method for the synthesis of highly oriented potassium-doped tungsten oxide nanowires. Adv Mater 15(5):411–414
Sadakane M, Sasaki K, Kunioku H, Ohtani B, Abe R, Ueda W (2010) Preparation of 3-D ordered macroporous tungsten oxides and nano-crystalline particulate tungsten oxides using a colloidal crystal template method, and their structural characterization and application as photocatalysts under visible light irradiation. J Mater Chem 20(9):1811–1818
Sadek AZ, Zheng H, Latham K, Wlodarski W, Kalantar-Zadeh K (2008) Anodization of Ti thin film deposited on ITO. Langmuir 25(1):509–514
Sánchez-Martínez D, Martínez-de la Cruz A, López-Cuéllar E (2013) Synthesis of WO3 nanoparticles by citric acid-assisted precipitation and evaluation of their photocatalytic properties. Mater Res Bull 48(2):691–697
Seabold JA, Choi K-S (2011) Effect of a cobalt-based oxygen evolution catalyst on the stability and the selectivity of photo-oxidation reactions of a WO3 photoanode. Chem Mater 23(5):1105–1112
Singh S, Srivastava VC, Mall ID (2013) Mechanism of dye degradation during electrochemical treatment. J Phys Chem C 117(29):15229–15240
Singh S, Srivastava VC, Mall ID (2014) Electrochemical treatment of dye bearing effluent with different anode–cathode combinations: mechanistic study and sludge analysis. Ind Eng Chem Res 53(26):10743–10752
Smith W, Wolcott A, Fitzmorris RC, Zhang JZ, Zhao Y (2011) Quasi-core-shell TiO2/WO3 and WO3/TiO2 nanorod arrays fabricated by glancing angle deposition for solar water splitting. J Mater Chem 21(29):10792–10800
Song T-S, Wang D-B, Wang H, Li X, Liang Y, Xie J (2015) Cobalt oxide/nanocarbon hybrid materials as alternative cathode catalyst for oxygen reduction in microbial fuel cell. Int J Hydrog Energy 40(10):3868–3874
Su J, Feng X, Sloppy JD, Guo L, Grimes CA (2010) Vertically aligned WO3 nanowire arrays grown directly on transparent conducting oxide coated glass: synthesis and photoelectrochemical properties. Nano Lett 11(1):203–208
Sun S, Wang W, Zeng S, Shang M, Zhang L (2010) Preparation of ordered mesoporous Ag/WO3 and its highly efficient degradation of acetaldehyde under visible-light irradiation. J Hazard Mater 178(1–3):427–433
Sun W, Yeung MT, Lech AT, Lin C-W, Lee C, Li T, Kaner RB (2015) High surface area tunnels in hexagonal WO3. Nano Lett 15(7):4834–4838
Tanaka D, Oaki Y, Imai H (2010) Enhanced photocatalytic activity of quantum-confined tungsten trioxide nanoparticles in mesoporous silica. Chem Commun 46(29):5286–5288
Teh CY, Budiman PM, Shak KPY, Wu TY (2016) Recent advancement of coagulation–flocculation and its application in wastewater treatment. Ind Eng Chem Res 55(16):4363–4389
Theerthagiri J, Senthil R, Malathi A, Selvi A, Madhavan J, Ashokkumar M (2015) Synthesis and characterization of a CuS–WO3 composite photocatalyst for enhanced visible light photocatalytic activity. RSC Adv 5(65):52718–52725
Tsai F-C, Ma N, Chiang T-C, Tsai L-C, Shi J-J, Xia Y, Chuang F-S (2014) Adsorptive removal of methyl orange from aqueous solution with crosslinking chitosan microspheres. J Water Process Eng 1:2–7
Tsai Y, Chan Y, Ko F, Yang J (2018) Integrated operation of renewable energy sources and water resources. Energy Convers Manag 160:439–454
Vacchi FI, de Souza Vendemiatti JA, da Silva BF, Zanoni MVB, de Aragão Umbuzeiro G (2017) Quantifying the contribution of dyes to the mutagenicity of waters under the influence of textile activities. Sci Total Environ 601:230–236
Vamvasakis I, Georgaki I, Vernardou D, Kenanakis G, Katsarakis N (2015) Synthesis of WO3 catalytic powders: evaluation of photocatalytic activity under NUV/visible light irradiation and alkaline reaction pH. J Sol–Gel Sci Technol 76(1):120–128
Viswanath B, Rajesh B, Janardhan A, Kumar AP, Narasimha G (2014) Fungal laccases and their applications in bioremediation. Enzyme Res 2014:1–21
Wang G, Ling Y, Li Y (2012a) Oxygen-deficient metal oxide nanostructures for photoelectrochemical water oxidation and other applications. Nanoscale 4(21):6682–6691
Wang G, Ling Y, Wang H, Yang X, Wang C, Zhang JZ, Li Y (2012b) Hydrogen-treated WO3 nanoflakes show enhanced photostability. Energy Environ Sci 5(3):6180–6187
Wen Z, Wu W, Liu Z, Zhang H, Li J, Chen J (2013) Ultrahigh-efficiency photocatalysts based on mesoporous Pt–WO3 nanohybrids. Phys Chem Chem Phys 15(18):6773–6778
Wu S, Fang J, Xu W, Cen C (2013) Hydrothermal synthesis, characterization of visible-light-driven α-Bi2O3 enhanced by Pr3 + doping. J Chem Technol Biotechnol 88(10):1828–1835
Xi G, Yan Y, Ma Q, Li J, Yang H, Lu X, Wang C (2012) Synthesis of multiple-shell WO3 hollow spheres by a binary carbonaceous template route and their applications in visible-light photocatalysis. Chem A Eur J 18(44):13949–13953
Xu C, Wei X, Guo Y, Wu H, Ren Z, Xu G, Shen G, Han G (2009) Surfactant-free synthesis of Bi2WO6 multilayered disks with visible-light-induced photocatalytic activity. Mater Res Bull 44:1635–1641
Xu J, Cao Z, Zhang Y, Yuan Z, Lou Z, Xu X, Wang X (2018) A review of functionalized carbon nanotubes and graphene for heavy metal adsorption from water: preparation, application, and mechanism. Chemosphere 195:351–364
Yang C-H, Shih M-C, Chiu H-C, Huang K-S (2014) Magnetic Pycnoporus sanguineus-loaded alginate composite beads for removing dye from aqueous solutions. Molecules 19(6):8276–8288
Yu J, Yue L, Liu S, Huang B, Zhang X (2009) Hydrothermal preparation and photocatalytic activity of mesoporous Au–TiO2 nanocomposite microspheres. J Colloid Interface Sci 334(1):58–64
Yu J-G, Zhao X-H, Yang H, Chen X-H, Yang Q, Yu L-Y, Chen X-Q (2014) Aqueous adsorption and removal of organic contaminants by carbon nanotubes. Sci Total Environ 482:241–251
Zhang H, Chen G, Bahnemann DW (2009) Photoelectrocatalytic materials for environmental applications. J Mater Chem 19(29):5089–5121
Zhang X, Lu X, Shen Y, Han J, Yuan L, Gong L, Tong Y (2011) Three-dimensional WO3 nanostructures on carbon paper: photoelectrochemical property and visible light driven photocatalysis. Chem Commun 47(20):5804–5806
Zhang Y, Guo Y, Duan H, Li H, Sun C, Liu H (2014) Facile synthesis of V 4 + self-doped,[010] oriented BiVO4 nanorods with highly efficient visible light-induced photocatalytic activity. Phys Chem Chem Phys 16(44):24519–24526
Zheng Y, Chen G, Yu Y, Sun J, Zhou Y, Pei J (2013) Template and surfactant free synthesis of hierarchical WO3·0.33H2O via a facile solvothermal route for photo-catalytic rhb degradation. Cryst Eng Comm 16:6107–6113
Acknowledgements
This work was financed by the Higher Education Commission (HEC) of Pakistan, University of Gujrat, Hafiz Hayat Campus, Gujrat, Pakistan, and Government College University of Faisalabad, Pakistan.
Author information
Authors and Affiliations
Corresponding author
Additional information
Editorial responsibility: M. Abbaspour.
Rights and permissions
About this article
Cite this article
Tahir, M.B., Ali, S. & Rizwan, M. A review on remediation of harmful dyes through visible light-driven WO3 photocatalytic nanomaterials. Int. J. Environ. Sci. Technol. 16, 4975–4988 (2019). https://doi.org/10.1007/s13762-019-02385-5
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13762-019-02385-5