Abstract
Hydroxyapatite (camel bone, CB) was used for production of low cost activated carbon (CBC) and applied for vanadium removal from aqueous solution. Nitric acid, phosphoric acid and hydrogen peroxide were used as chemical catalysts to prepare the developed activated carbon. CB and CBC adsorbents were characterized using different available techniques such as SEM, FTIR, N2 adsorption and desorption isotherms, as well as TGA-DTA thermal analysis. The efficiency of the prepared adsorbent was investigated using batch adsorption method. At optimum pH, CBC could adsorb 85% of vanadium after 30 min. Three isotherm models, namely Freundlich, Langmuir and Dubinin–Radushkevich, were used to analyze the sorption equilibrium data. The process was found to follow Langmuir adsorption isotherm model, indicating that vanadium ions adsorption process had physical character. The kinetic studies manifested that the adsorption process follows the pseudo-second-order reaction. The CBC adsorbent exhibited a feasible capacity (19.45 mg/g) for vanadium adsorption compared to the other works published in the literature. In addition, thermodynamic studies explained that adsorption process is spontaneous, exothermic and occurs preferably via physisorption mechanism. 0.5 M HCl solution was successfully used as eluting agent for vanadium desorption.
Similar content being viewed by others
References
S.A. Traceyc, G.R. Willsky, E.S. Takeuchi, Chemistry, Biochemistry, Pharmacology and Practical Applications. Chemistry, Biochemistry, Pharmacology and Practical Applications, 1st edn. (CRC Press, Boca Raton, 2007)
G. Bauer, V. Güther, H. Hess, Vanadium and vanadium compounds, in Ullmann's Encyclopedia of Industrial Chemistry, ed. by C. Ley (Wiley-VCH Verlag, Weinheim, Germany, 2017)
M. Costigan, R. Cary, S. Dobson, Concise international chemical assessment document 29. In: Vanadium pentoxide and other inorganic vanadium compounds, (Geneva, World Health Organization, ISBN 92 4 153029 4, 2001)
P. Ferna’ndez-A’lvarez, J. Vila, J.M. Garrido, M. Grifoll, G. Feijoo, J.M. Lema, J. Hazard. Mater. 147(3), 914–922 (2007)
A. Parasuraman, T.M. Lim, C. Menictas, M. Skyllas-Kazacos, Electrochim. Acta 101, 27–40 (2013)
A. Giovanni, C. Chiara, D. Angela, A. Grasso, R. Fallico, S. Sciacca, M. Fiore, M. Ferrante, J. Water Health 13, 522–530 (2015)
A. Bhatnagar, A.K. Minocha, D. Pudasainee, H.K. Chung, S.H. Kim, H.S. Kim, G. Lee, B. Min, B.H. Jeon, Chem. Eng. J. 144, 197–204 (2008)
S.E. Rizk, M.M. Hamed, Desalin. Water. Treat. 56, 1536–1546 (2015)
Q. He, S. Si, J. Zhao, H. Yan, B. Sun, Q. Cai, Y. Yu, Saudi. J. Biol. Sci. 25, 1664–1669 (2018)
L.S. Oliveira, A.S. Franca, Activated Carbon Classifications, Properties and Applications (Nova Science Publishers, 2012).
M.M. Hamed, J. Radioanal. Nucl. Chem. 302, 303–313 (2014)
H. Sharififard, M. Soleimani, F.Z. Ashtiani, Desalin. Water Treat. 57, 15714–15723 (2016)
H.M. Gad, M.M. Hamed, H.M.M. Abo Eldahab, M.E. Moustafa, S.A. El-Reefy, J. Mol. Liq. 231, 45–55 (2017)
H. Sharififard, M. Soleimani, F.Z. Ashtiani, Desalin. Water Treat. 72, 343–353 (2017)
H. Sharififard, M. Soleimani, F. Pepe, Res. Chem. Intermediat. 43(4), 2253–2272 (2017)
H. Sharififard, M. Soleimani, RSC Adv. 5(98), 80650–80660 (2015)
C. Namasivayam, D. Sangeetha, Adsorption 12, 103–117 (2006)
S.S.M. Hassan, N.S. Awwad, H.A. Aboterika, J. Hazard. Mater. 154, 992–997 (2008)
A.A. Alqadami, M.A. Khan, M. Otero, M.R. Siddiqui, B.H. Jeon, K.M. Batooet, J. Clean. Prod. 178, 293–304 (2018)
S.M. Wabaidur, M.A. Khan, M.R. Siddiqui, Z.A. Alothman, S. Vasudevan, M.S. Al-Gamdi, I.H. Al-Sohami, Desalin. Water Treat. 67, 357–370 (2017)
H.S.M. Abd-Rabboh, K.F. Fawy, N.S. Awwad, Desalin. Water Treat. 164, 300–309 (2019)
M.N. Rashed, A.A. Gad, N.M. Fathy, Adv. J. Chem. A 2(4), 347–364 (2019)
S.M.M. Ali, N. El-Said, B.S. Girgis, Int. J. Comput. Eng. Res. 4, 70–78 (2014)
O. Budevsky, R. Pribil, Talanta 11(9), 1313–1318 (1964)
A.K. Krishnan, K.G. Sreejalekshmi, V. Vimexen, V. Dev, Ecotox. Environ. Saf. 124, 418–425 (2016)
J.W. Weber, J.V. Morris, J. Sanıt. Eng. Dıv. Asce. 89, 31–60 (1963)
N. Kocak, M. Sahin, I. Gubbuk, J. Inorg. Organomet. P. 22, 852–859 (2012)
J. Rouquerol, D. Avnir, C.W. Fairbridge, D.H. Everett, J.H. Haynes, N. Pernıcone, J.D.F. Ramsay, K.S.W. Sing, K.K. Unger, Pure Appl. Chem. 66(8), 1739–1758 (1994)
C. Djilani, R. Zaghdoudi, F. Djazi, B. Bouchekima, A. Lallam, P. Magri, Desalin. Water Treat. 57, 70–79 (2016)
Z. Jiang, Y. Liu, X. Sun, F. Tian, F. Sun, C. Liang, W. You, C. Han, C. Li, Langmuir 19, 731–736 (2003)
S. Dimović, I. Smičiklas, I. Plećaš, D. Antonović, M. Mitrić, J. Hazard. Mater. 164, 279–287 (2009)
M.S. Fernando, A.K.D.V.K. Wimalasiri, S.P. Ratnayake, J.M.A.R.B. Jayasinghe, G.R. William, D.P. Dissanayake, K.M.N. de Silva, R.M. de Silva, RSC Adv. 9, 35588 (2019)
A.K.D. Veromee, K. Wimalasiri, M.S. Fernando, G.R. Williams, D.P. Dissanayake, K.M.N. de Silva, R.M. de Silva, Mater. Chem. Phys. 257, 123712 (2021)
S. Koutsopoulos, J. Biomed. Mater. Res. 62(4), 600–612 (2002)
M.S. Fernando, R.M. de Silva, K.M. Nalin de Silva, Appl. Surf. Sci. 351, 95–103 (2015)
H.D.A.C. Jayaweera, I. Siriwardane, K.M. Nalin de Silva, R.M. de Silva, Chem. Cent. J. 12, 18 (2018)
D.M. Imam, S.I. Moussa, M.F. Attallah, J. Radioanal. Nucl. Ch. 319, 997–1012 (2019)
J.L. Bellamy, The Infrared Spectra of Complex Molecules, 3rd edn. (Chapman and Hall, 1975).
M.M. Hamed, M.M.S. Ali, M. Holiel, J. Environ. Radioactiv. 164, 113–124 (2016)
R. Goren, H. Gocmez, C. Ozgur, Ceram. Int. 32, 407–409 (2006)
H.J. Huang, F.F. Huang, L. Evans, S. Glasauer, Chem. Geol. 417, 68–89 (2015)
D.C. Crans, S.T. Alan, The chemistry of vanadium in aqueous and nonaqueous solution vanadium compounds, chemistry, biochemistry, and therapeutic applications. ACS Symp. 711, 2–29 (1998)
N.H. Mthombeni, S. Mbakop, S.M. Onyango, Int. J. Environ. Sci. Te. 6, 602–605 (2015)
D.C. Crans, Pure Appl. Chem. 77, 1497–1527 (2005)
H. Deng, Y. Li, Y.Y. Huang, X. Ma, L. Wu, T. Cheng, Chem. Eng. J. 286, 25–35 (2016)
K.W. George, A. Serdar, G. Sinan, Adsorpt. Sci. Technol. 36, 963–952 (2017)
H.I. Gomes, A. Jones, M. Rogerson, G.M. Greenway, D.F. Lisbona, I.T. Burke, W.M. Mayes, J. Environ. Manag. 187, 384–392 (2017)
M.M. Hamed, M.I. Aly, A.A. Nayl, Chem. Ecol. 32, 38–87 (2016)
L.S. Hsia, J.R. Shin, J. Environ. Manage. 90(3), 1336–1349 (2009)
A. Padilla-Rodríguez, J.A. Hernández-Viezcas, J.R. Peralta-Videa, J.L. Gardea-Torresdey, O. Perales-Pérez, F.R. Román-Velázquez, Microchem. J. 118, 1–11 (2015)
K. Prathap, C. Namasivayam, Environ. Chem. Lett. 8, 363–371 (2010)
A. Mojiri, W. Hui, K.A. Arshad, A.R.M. Ridzuan, N.H.A. Hamid, H. Farraji, A. Gholami, A.H. Vakili, Adv. Environ. Res. 6, 173–187 (2017)
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Rights and permissions
About this article
Cite this article
Ali, M.M.S., Imam, D.M. & El-Nadi, Y.A. Vanadium(V) removal and recovery by adsorption onto modified activated carbon derived from natural hydroxyapatite. J IRAN CHEM SOC 18, 2771–2784 (2021). https://doi.org/10.1007/s13738-021-02227-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13738-021-02227-7