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Application of structurally enhanced magnetite cored polyamidoamine dendrimer for knoevenagel condensation

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Abstract

In this paper, the synthesis of magnetic cored amino group terminated dendrimer (Fe3O4@SiO2@PAMAM-G2) through covalent bonding was described. This catalyst was characterized by FT-IR, XRD, FE-SEM, TEM, and TGA detection methods. Next, the catalytic activity of this catalyst was investigated for the Knoevenagel condensation reaction of aldehydes with malononitrile under mild and solvent-free conditions. The Fe3O4@SiO2@PAMAM-G2 could be separated from the reaction mixture by an external magnet and reused five times.

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Authors and Affiliations

  1. Department of Chemistry, Hakim Sabzevari University, Sabzevar, 96179-76487, Iran

    Fatemeh Hajizadeh, Behrooz Maleki, Farrokhzad Mohammadi Zonoz & Amirhassan Amiri

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  1. Fatemeh Hajizadeh
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  2. Behrooz Maleki
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  3. Farrokhzad Mohammadi Zonoz
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  4. Amirhassan Amiri
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Correspondence to Behrooz Maleki.

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Hajizadeh, F., Maleki, B., Zonoz, F.M. et al. Application of structurally enhanced magnetite cored polyamidoamine dendrimer for knoevenagel condensation. J IRAN CHEM SOC 18, 793–804 (2021). https://doi.org/10.1007/s13738-020-02071-1

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  • DOI: https://doi.org/10.1007/s13738-020-02071-1

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