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Iridium nanoparticles deposited on hypercrosslinked polystyrene: synthesis and application in the hydrogenation of aromatic compounds

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Abstract

A novel method for the incorporation of iridium nanoparticles into a hypercrosslinked polystyrene matrix is developed using supercritical CO2 as reaction medium. The composite has regularly distributed iridium nanoparticles with monomodal size of ca 5 nm. The catalyst shows high activity in the hydrogenation of benzene and can be recycled ten times without any decrease in productivity. The catalyst gave a full conversion in the hydrogenation of toluene to methylcyclohexane and fluoro- and chlorobenzene to cyclohexane.

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References

  1. C. Amiensa, D. Ciuculescu-Pradines, K. Philippot, Coord. Chem. Rev. 308, 409–432 (2016)

    Article  Google Scholar 

  2. S.J.T. Rezaei, A. Shamseddin, A. Ramazani, A.M. Malekzadeh, P.A. Asiabi, Appl. Organomet. Chem. 31, 1–10 (2017)

    Google Scholar 

  3. J. Dupont, J.D. Scholten, Chem. Soc. Rev. 39, 1780–1804 (2010)

    Article  CAS  Google Scholar 

  4. N. Yan, C.X. Xiao, Y. Kou, Coord. Chem. Rev. 254, 1179–1218 (2010)

    Article  CAS  Google Scholar 

  5. R. Mirsafaei, M.M. Heravi, T. Hosseinnejad, S. Ahmadi, Appl. Organomet. Chem. 30, 823–830 (2016)

    Article  CAS  Google Scholar 

  6. G. Schmid, Chem. Rev. 92, 1709–1727 (1992)

    Article  CAS  Google Scholar 

  7. O.A. Belyakova, Y.L. Slovokhotov, Russ. Chem. Bull. 52, 2299–2327 (2003)

    Article  CAS  Google Scholar 

  8. M.A. Gelesky, A.P. Umpierre, G. Machado, R.R.B. Correia, W.C. Magno, J. Morais, G. Ebeling, J. Dupont, J. Am. Chem. Soc. 127, 4588–4589 (2005)

    Article  CAS  Google Scholar 

  9. D. Astruc, F. Lu, J.R. Aranzaes, Angew. Chem. Int. Ed. 44, 7852–7872 (2005)

    Article  CAS  Google Scholar 

  10. C. Pan, K. Pelzer, K. Philippot, B. Chaudret, F. Dassenoy, P. Lecante, M.J. Casanove, J. Am. Chem. Soc. 123, 7584–7593 (2001)

    Article  CAS  Google Scholar 

  11. C.A. Stowell, B.A. Korgel, Nano Lett. 5, 1203–1207 (2005)

    Article  CAS  Google Scholar 

  12. A. Roucoux, J. Schulz, H. Patin, Adv. Synth. Catal. 345, 222–229 (2003)

    Article  CAS  Google Scholar 

  13. J.D. Aiken, Y. Lin, R.G. Finke, J. Mol. Catal. A: Chem. 114, 29–51 (1996)

    Article  Google Scholar 

  14. J.A. Widegren, J.D. Aiken, S. Ozkar, R.G. Finke, Chem. Mater. 13, 312–324 (2001)

    Article  CAS  Google Scholar 

  15. J.L. Pellegatta, C. Blandy, V. Colliere, R. Choukroun, B. Chaudret, P. Cheng, K. Philippot, J. Mol. Catal. A: Chem. 178, 55–61 (2002)

    Article  CAS  Google Scholar 

  16. H.J. Ryu, L. Sanchez, H.A. Keul, A. Raj, M.R. Bockstaller, Angew. Chem. Int. Ed. 47, 7639–7643 (2008)

    Article  CAS  Google Scholar 

  17. Y. Hu, Y.Y. Yu, Z.S. Hou, H. Li, X.G. Zhao, B. Feng, Adv. Synth. Catal. 350, 2077–2085 (2008)

    Article  CAS  Google Scholar 

  18. R.M. Esteban, K. Schütte, P. Brandt, D. Marquardt, H. Meyer, F. Beckert, R. Mülhaupt, H. Kölling, C. Janiak, Nano-Struct. Nano-Objects 2, 11–18 (2015)

    Article  CAS  Google Scholar 

  19. L. Tan, B. Tan, Chem. Soc. Rev. 46, 3322–3356 (2017)

    Article  CAS  Google Scholar 

  20. E. Sulman, V. Matveeva, L. Bronstein, A. Sidorov, N. Lakina, S. Sidorov, P. Valetsky, Green Chem. 5, 205–208 (2003)

    Article  CAS  Google Scholar 

  21. E. Sulman, V. Doluda, S. Dzwigaj, E. Marceau, L. Kustov, O. Tkachenko, A. Bykov, V. Matveeva, M. Sulman, N. Lakina, J. Mol. Catal. A: Chem. 278, 112–119 (2007)

    Article  CAS  Google Scholar 

  22. E.M. Sulman, A.A. Ivanov, V.S. Chernyavsky, M.G. Sulman, A.I. Bykova, A.I. Sidorov, VYu. Doluda, V.G. Matveeva, L.M. Bronstein, B.D. Stein, A.S. Kharitonov, Chem. Eng. J. 176–177, 33–41 (2011)

    Article  Google Scholar 

  23. S.E. Lyubimov, A.A. Vasil’ev, A.A. Korlyukov, M.M. Ilyin, S.A. Pisarev, V.V. Matveev, A.E. Chalykh, S.G. Zlotin, V.A. Davankov, React. Funct. Polym. 69, 755–758 (2009)

    Article  CAS  Google Scholar 

  24. S.E. Lyubimov, E.A. Rastorguev, K.I. Lubentsova, A.A. Korlyukov, V.A. Davankov, Tetrahedron Lett. 54, 1116–1119 (2013)

    Article  CAS  Google Scholar 

  25. J. Dupont, G.S. Fonseca, A.P. Umpierre, P.F.P. Fichtner, S.R. Teixeira, J. Am. Chem. Soc. 124, 4228–4229 (2002)

    Article  CAS  Google Scholar 

  26. G.S. Fonseca, A.P. Umpierre, P.F.P. Fichtner, S.R. Teixeira, J. Dupont, Chem. Eur. J. 9, 3263–3269 (2003)

    Article  CAS  Google Scholar 

  27. S. Kundu, H. Liang, J. Colloid Interface Sci. 354, 597–606 (2011)

    Article  CAS  Google Scholar 

  28. Y. Lin, R.G. Finke, Inorg. Chem. 33, 4891–4910 (1994)

    Article  CAS  Google Scholar 

  29. B.J. Hornstein, R.G. Finke, Chem. Mater. 15, 899–909 (2003)

    Article  CAS  Google Scholar 

  30. A. Goel, N. Rani, Open J. Inorg. Chem. 2, 67–73 (2012)

    Article  Google Scholar 

  31. L. Fu, X. Zeng, C. Huang, P. Cai, G. Cheng, W. Luo, Inorg. Chem. Front. 5, 1121–1125 (2018)

    Article  CAS  Google Scholar 

  32. E.C. Butler, K.F. Hayes, Environ. Sci. Technol. 33, 2021–2027 (1999)

    Article  CAS  Google Scholar 

  33. E.D. Goldberg, Sci. Total Environ. 100, 17–28 (1991)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by Russian foundation for basic research, Grant No. 18-29-06032. Authors thank the Department of structural studies of Zelinsky Institute of organic chemistry (Moscow) for electron microscopy characterization.

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Authors and Affiliations

  1. A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov Str. 28, Moscow, Russia, 119991

    Sergey E. Lyubimov, Marina V. Sokolovskaya, Alexander A. Korlyukov & Vadim A. Davankov

  2. Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky Prospekt 29, Moscow, Russia, 119991

    Oleg P. Parenago

Authors
  1. Sergey E. Lyubimov
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  2. Marina V. Sokolovskaya
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  3. Alexander A. Korlyukov
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  4. Oleg P. Parenago
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  5. Vadim A. Davankov
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Correspondence to Sergey E. Lyubimov.

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Lyubimov, S.E., Sokolovskaya, M.V., Korlyukov, A.A. et al. Iridium nanoparticles deposited on hypercrosslinked polystyrene: synthesis and application in the hydrogenation of aromatic compounds. J IRAN CHEM SOC 17, 1283–1287 (2020). https://doi.org/10.1007/s13738-020-01854-w

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  • DOI: https://doi.org/10.1007/s13738-020-01854-w

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