Abstract
Water pollution is one of the most universal problems oppressing people throughout the world, while adsorption is the most widely used method to remove contamination from water. In this paper, we proposed graphene oxide as a suitable adsorbent for the removal of ametryn from Karoon River water, drainage and water obtained from washing of soil samples of sugarcane farm (Hakim Farabi Agro-industrial. Co. Khuzestan province, Iran). To this end, the concentration of ametryn was quantitatively measured by high-performance liquid chromatography (HPLC). The response surface methodology (RSM) was used for the optimization of the effects of four important parameters influencing the removal efficiency of the proposed method. Experimental and modeling results showed that graphene oxide effectively adsorbed ametryn with maximum sorption capacity of 47.2 mg g−1. The adsorption process with ametryn was found to be fitted to pseudo-second-order kinetic equation and the Langmuir adsorption isotherm model. Moreover, the experimental results indicated that GO had good adsorption ability for the removal of ametryn from water and soil samples.
Similar content being viewed by others
References
Y. Chen, L. Bin, L. Chen, H. Bai, Graphene oxide–chitosan composite hydrogels as broad-spectrum adsorbents for water purification. J. Mater. chem. A 1, 1992–2001 (2013)
D.W. Kolpin, J.E. Barbash, R.J. Gilliom, Occurrence of pesticides in shallow groundwater of the united states: initial results from the national water-quality assessment program. Environ Sci. Technol. 32, 558–566 (1998)
R.A. Boyd, Herbicides and herbicide degradates in shallow groundwater and the Cedar River near a municipal well field, Cedar Rapids, Iowa. Sci. Total Environ. 248, 241–253 (2000)
F. Hernandez, C. Hidalgo, J.V. Sancho, F.J. López, Coupled-column liquid chromatography applied to the trace-level determination of triazine herbicides and some of their metabolites in water samples. Anal. Chem. 70, 3322–3328 (1998)
Y. Chen, Z.P. Chen, W. Jin, R.Q. Yu, Quantitative determination of ametryn in river water using surface-enhanced Raman spectroscopy coupled with an advanced chemometric model. Chemometr. Intell. Lab. Syst. 142, 166–171 (2015)
A.E. jacomini, P.B. de Camarge, Determination of ametryn in river water, river sediment and bivalve mussels by liquid chromatography-tandem mass spectrometry. J. Brazil. Chem. Soc. 20, 452–461 (2009)
G.M.F. Pinto, I. Cristina, S.F. Jardim, Use of solid-phase extraction and high-performance liquid chromatography for the determination of triazine residues in water: validation of the method. J. chromatogr. A 869, 463–469 (2000)
G.N. Kasozi, P. Nkedi-kizza, A.R. Zimmerman, Sorption of atrazine and ametryn by carbonatic and non-carbonatic soils of varied origin. Environ. Pollut. 169, 12–19 (2012)
D. Djozan, M. Mehkam, B. Ebrahimi, Preparation and binding study of solid-phase microextraction fiber on the basis of ametryn-imprinted polymer: application to the selective extraction of persistent triazine herbicides in tap water, rice, maize and onion. J. Chromatogr. A 1216, 2211–2219 (2009)
N. Zhao, C. Chen, J. Zhou, Surface plasmon resonance detection of ametryn using a molecularly imprinted sensing film prepared by surface-initiated atom transfer radical polymerization, Sens. Actuator. B 166–167, 473–479 (2012)
D. Chen, H. Feng, J. Li, Graphene oxide: preparation, functionalization, and electrochemical applications. Chem. Rev. 112, 6027–6053 (2012)
L. Chen, Y. Lu, Sh Li, X. Lin, Zh Xu, Zh Dai, Application of graphene-based solid-phase extraction for ultra-fast determination of malachite green and its metabolite in fish tissues. Food Chem. 141, 1383–1389 (2013)
L. Fan, Ch Luo, X. Li, Fabrication of novel magnetic chitosan grafted with graphene oxide to enhance adsorption properties for methyl blue, J. Hazard. Mater. 215–216, 272–279 (2012)
P. Sharma, M. Das, Removal of a cationic dye from aqueous solution using graphene oxide nanosheets: investigation of adsorption parameters. J. Chem. Eng. Data 58, 151–158 (2013)
N. Pan, j Deng, D. Guan, Y. Jin, C. Xia, Adsorption characteristics of Th(IV) ions on reduced graphene oxide from aqueous solutions. Appl. Surf. Sci. 287, 478–483 (2013)
B. Yu, J. Xu, J. Huiliu, S. Yang, J. Luo, Adsorption behavior of copper ions on graphene oxide–chitosan aerogel. J. Environ. Chem. Eng. 1, 1044–1050 (2013)
S. Debnath, A. Maity, K. Pillay, Magnetic chitosan–GO nanocomposite: Synthesis, characterization and batch adsorber design for Cr(VI) removal. J. Environ. Eng. 2, 963–973 (2014)
H. chen, B. Gao, H. Li, Removal of sulfamethoxazole and ciprofloxacin from aqueous solutions by graphene oxide. J. Hazard. Mater. 282, 20–207 (2014)
K.Y. Sh. Chang, C. Lin, Lu, Efficient adsorptive removal of tetramethylammonium hydroxide (TMAH) from water using graphene oxide. Sep. Purif. Technol. 133, 99–107 (2014)
S.W. Nam, C. Jung, H.M. Li, j. Flora, Adsorption characteristics of diclofenac and sulfamethoxazole to graphene oxide in aqueous solution. Chemosphere 136, 20–26 (2015)
Z. Shi, J. Hu, Q. Li, S. Zhang, Graphene based solid phase extraction combined with ultra high performance liquid chromatography–tandem mass spectrometry for carbamate pesticides analysis in environmental water samples. J. Chromatogr. A 1355, 219–227 (2014)
J. Zou, X. Song, J. Ji, W. Xu, J. Chen, Y. Jiang, Y. Wang, X. Chen, Polypyrrole/graphene composite-coated fiber for the solid-phase microextraction of phenols. J. Sep. Sci. 34, 2765–2772 (2011)
X. Ding, Y. Wang, Y. Wang, Q. Pan, J. Chen, Y. Huang, K. Xu, Preparation of magnetic chitosan and grapheme oxide-functional guanidinium ionic liquid composite for the solid-phase extraction ofprotein. Anal. Chim. Acta 861, 36–46 (2015)
M. Asadollahzadeh, H. Tavakoli, M. Torab-Mostaedi, Response surface methodology based on CCD as a chemometric tool for optimization of dispersive-solidification liquid–liquid microextraction for speciation of inorganic arsenic in environmental water samples. Talanta 123, 25–31 (2014)
N. Fiol, I. Villaescusa, Determination of sorbent point zero charge: usefulness in sorption studies. Environ. Chem. 7, 79–84 (2009)
Y.S. Ho, G. McKay, The kinetics of sorption of divalent metal ions onto sphagnum moss peat. Water Res. 34, 735–742 (2000)
Y.S. Ho, G. McKay, Pseudo-second order model for sorption processes. Process Biochem. 34, 451–465 (1999)
Acknowledgements
The authors wish to thank Bureau of Khozestan Standard for financial support and also Shahid Chamran university for technical support of this project (Grant 1395).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Khoshnam, F., Zargar, B. & Moghadam, M.R. Adsorption and removal of ametryn using graphene oxide nano-sheets from farm waste water and optimization using response surface methodology. J IRAN CHEM SOC 16, 1383–1390 (2019). https://doi.org/10.1007/s13738-019-01621-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13738-019-01621-6