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Supported vanadium Schiff bases complex on nano silica: a heterogeneous catalyst for the selective oxidation of sulfides and alcohols

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Abstract

A vanadium Schiff base complex on nano silica was prepared by reaction of nano silica NH2-functionalized, 2,4-dihydroxy benzaldehyde and VO(acac)2. The VSBC@NS was used as an efficient and reusable heterogeneous catalyst for the selective oxidation of sulfides to sulfoxides and alcohols to aldehydes with H2O2 as an oxidant in methanol.

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Acknowledgments

We gratefully acknowledge the financial support from the Research Council of Shahid Beheshti University.

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Authors and Affiliations

  1. Department of Chemistry, Shahid Beheshti University, General Campus, Tehran, 1983963113, Iran

    Minoo Dabiri, Majid Koohshari, Fazeleh Shafipour, Melika Kasmaei & Parinaz Salari

  2. Departement of Chemistry, University of New Brunswick, P. O. Box 4400, Fredricton, NB, E3B 5A3, Canada

    David MaGee

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  1. Minoo Dabiri
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  2. Majid Koohshari
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  3. Fazeleh Shafipour
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  4. Melika Kasmaei
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  5. Parinaz Salari
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  6. David MaGee
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Correspondence to Minoo Dabiri.

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Dabiri, M., Koohshari, M., Shafipour, F. et al. Supported vanadium Schiff bases complex on nano silica: a heterogeneous catalyst for the selective oxidation of sulfides and alcohols. J IRAN CHEM SOC 13, 1265–1272 (2016). https://doi.org/10.1007/s13738-016-0840-z

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  • DOI: https://doi.org/10.1007/s13738-016-0840-z

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