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Synthesis, characterization, antibacterial activities and theoretical studies of Mn(II) and Cd(II) complexes with new macrocyclic Schiff base ligands incorporating a phenanthroline head unit

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Abstract

Three new hexaaza (N6) macrocyclic Schiff base ligands containing a phenanthroline moiety (L1-L3) have been synthesized and their coordination capability toward perchlorate salts of Mn(II) and Cd(II) have been investigated. The complexes are 18- and 19-membered hexaaza macrocycles, and incorporate a 1,10-phenanthroline unit as an integral part of their cyclic structure. All complexes have been characterized by a variety of methods such as IR, elemental analysis, EI-Mass, and conductivity measurements and in the case of cadmium complexes by 1H and 13C NMR spectroscopy. DFT (BP86) calculation on structures and molecular orbital of Mn(II) and Cd(II) complexes of latter ligands are also reported. Also the synthesized complexes were screened for their antibacterial activities against six bacterial strains and showed antibacterial effects.

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Acknowledgments

We are grateful to the Faculty of Chemistry of Bu-Ali Sina University and Ministry of Science, Research and Technology of Iran, for financial support.

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Authors and Affiliations

  1. Faculty of Chemistry, Bu-Ali Sina University, Hamedan, 65174, Iran

    Hassan Keypour, Mozhdeh Liyaghati-Delshad & Mehdi Bayat

  2. Department of Chemical Engineering, Hamedan University of Technology, Hamedan, 65155, Iran

    Majid Rezaeivala

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  1. Hassan Keypour
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  2. Mozhdeh Liyaghati-Delshad
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  3. Majid Rezaeivala
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  4. Mehdi Bayat
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Correspondence to Hassan Keypour or Majid Rezaeivala.

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Keypour, H., Liyaghati-Delshad, M., Rezaeivala, M. et al. Synthesis, characterization, antibacterial activities and theoretical studies of Mn(II) and Cd(II) complexes with new macrocyclic Schiff base ligands incorporating a phenanthroline head unit. J IRAN CHEM SOC 12, 621–630 (2015). https://doi.org/10.1007/s13738-014-0520-9

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