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EPDM recycling assisted by γ-processing

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An Erratum to this article was published on 23 December 2016

Abstract

The integration of waste ethylene–propylene–diene terpolymer (EPDM), containing carbon black into pristine EPDM can be achieved by γ-irradiation as a versatile procedure to process ethylene–propylene elastomers. The presence of acrylic acid in the material formulation allows the formation of intermolecular bridges by threefold increase in gel content. The possibility of achieving greater stability by the addition of acrylic acid in EPDM systems was analyzed. The start materials were EPDM containing 30 and 50 phr of EPDM powder loaded with 40 phr of carbon black aged by pre-exposure to electron beam irradiation. The advanced γ-irradiation exceeding 100 kGy represented the optimal radiation processing condition. Two procedures of chemiluminescence under isothermal and non-isothermal regimes for the evaluation of radiation stability were applied on γ-irradiated samples. The thermal strength of irradiated samples was characterized based on the radiolysis mechanism of EPDM. The variation in the activation energy required for the thermal oxidation of these samples and the modification in gel contents due to the gelation action of acrylic acid were presented for the validation of proposed recycling radiochemical technique. Charlesby–Pinner representation provided different values for the ratios between radiochemical yields of cross-linking and scission, proving that the presence of acrylic acid promoted the conversion of EPDM wastes into valuable materials.

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Authors and Affiliations

  1. Advanced Research, Excellence Center in Radiochemistry, R&D Institute for Electrical Engineering, 313 Splaiul Unirii, 030138, Bucharest, Romania

    Traian Zaharescu & Marius Eduard Lungulescu

  2. Nuclear Research Institute, IPEN-CNEN/SP, Ciudade Universitaria, 2242 Av. Lineu Prestes, Sao Paulo, SP, 05508-000, Brazil

    Ludmila I. P. Kayan, Declerc F. Parra & Ademar B. Lugão

Authors
  1. Traian Zaharescu
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  2. Ludmila I. P. Kayan
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  3. Marius Eduard Lungulescu
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  4. Declerc F. Parra
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  5. Ademar B. Lugão
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Correspondence to Traian Zaharescu.

Additional information

An erratum to this article is available at http://dx.doi.org/10.1007/s13726-016-0494-9.

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Zaharescu, T., Kayan, L.I.P., Lungulescu, M.E. et al. EPDM recycling assisted by γ-processing. Iran Polym J 25, 725–730 (2016). https://doi.org/10.1007/s13726-016-0460-6

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  • DOI: https://doi.org/10.1007/s13726-016-0460-6

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