Abstract
The influences of added Fe element on the microstructures and properties of AlCoCrFe x Ni high-entropy alloys (x denoted the atomic fraction of Fe element at 0.2, 0.4, 0.6, 0.8, 1.2, 1.4, 1.6, 1.8, and 2.0) were investigated. When x = 0.2, the alloy exhibited dendrites morphology, but as the Fe content increased, the AlCoCrFe x Ni HEAs transformed to equiaxed grains morphology. Inside the equiaxed grains and dendritic grains, spinoidal decomposition microstructure could be clearly observed. The microstructures changed from Cr3Ni2 + B2 + BCC structures to B2 + BCC mixed structures as x exceeded 0.6, the hardness declined from HV637.2 to HV460.2, and the compressive fracture strength showed a slight decrease, whereas the plastic property showed a distinct improvement with the addition of Fe element. The maximum compression strength was 2335MPa when x = 0.2, and the maximum compression ratio was 36% when x = 2.0. The alloys transformed from paramagnetic to ferromagnetic as the content of Fe element increased, and all of the alloys exhibited soft magnetic behaviors.
Similar content being viewed by others
References
Lin J.P., Zhao L.L., Chen Y.G.: Effect of Nb on oxidation behaviour of high Nb containing TiAl alloys. Intermetallics 19, 698–706 (2011)
Haseeb A.S.M.A., Leng T.S.: Effects of Co nanoparticle addition to Sn-3.8Ag-0.7Cu solder on interfacial structure after reflow and aging. Intermetallics 19, 707–712 (2011)
Zhang Y., Zuo T.T., Tang Z.: Microstructures and properties of high-entropy alloys. Prog. Mater. Sci. 64, 1–93 (2014)
Cantor B., Chang I.T.H., Knight P.: Microstructural development in equi-atomic multicomponent alloys. Mater. Sci. Eng. A 375-377, 213–218 (2004)
Yeh J.W., Chen Y.L., Lin S.J.: Nanostructured high-entropy alloys with multiple principle elements: Novel alloy design concept and outcomes. Adv. Eng. Mater. 6, 299 (2004)
Gludovatz B., Hohenwarter A., Catoor D., Chang E.H., George E.P., Ritchie R.O.: A fracture-resistant high-entropy alloy for cryogenic applications. Science 345, 1153–1158 (2014)
Koželj P., Vrtnik S., Jelen A., Jazbec S., Jagličić Z., Maiti S., Feuerbacher M., Steurer W., Dolinšek J.: Effects of Nb addition on structural evolution and properties of the CoFeNi2V0.5 high-entropy alloy. Phys. Rev. Lett. 113, 107001-1-5 (2014)
Hsu C.Y., Yeh J.W., Chen S.K.: Wear resistance and high-temperature compression strength of fcc CuCoNiCrAl0.5Fe alloy with boron addition. Metall. Mater. Trans. A 35, 1465–1469 (2004)
Dogan O.N., Benjamin C.N., Jeffrey A.H.: Elevated-temperature corrosion of CoCrCuFeNiAl0.5B high-entropy alloys in simulated syngas containing H2S. Oxid. Met. 80, 177–190 (2013)
Li C., Li J.C., Zhao M.: Microstructure and properties of AlTiNiMnB x high entropy alloys. Mater. Sci. Technol. 24, 376–378 (2008)
Zhang H., He Y.Z., Pan Y.: Enhanced hardness and fracture toughness of the laser-solidified FeCoNiCrCuTiMoAlSiB0.5 high-entropy alloy by martensite strengthening. Scr. Mater. 69, 342–345 (2013)
Zhou Y.J., Zhang Y., Wang Y.L.: Solid solution alloys of AlCoCrFeNiTi x with excellent room-temperature mechanical properties. Appl. Phys. Lett. 90, 181904 (2007)
Zhu J.M., Fu H.M., Zhang H.F.: Microstructures and compressive properties of multicomponent AlCoCrFeNiMo x alloys. Mater. Sci. Eng. A 527, 6975–6979 (2010)
Zhu J.M., Fu H.M., Zhang H.F.: Synthesis and properties of multiprincipal component AlCoCrFeNiSi x alloys. Mater. Sci. Eng. A 527, 7210–7214 (2010)
Ma S.G., Zhang Y.: Effect of Nb addition on the microstructure and properties of AlCoCrFeNi high-entropy alloy. Mater. Sci. Eng. A 532, 480–486 (2012)
Zhu J.M., Fu H.M., Zhang H.F.: Microstructure and compressive properties of multiprincipal component AlCoCrFeNiC x alloys. J. Alloys Compd. 509, 3476–3480 (2011)
Dong Y., Zhou K.Y., Lu Y.P.: Effect of vanadium addition on the microstructure and properties of AlCoCrFeNi high entropy alloy. Mater. Des. 57, 67–72 (2014)
Lee C.P., Chen Y.Y., Hsu C.Y.: The effect of boron on the corrosion resistance of the high entropy alloys Al0.5CoCrCuFeNiB x s. J. Electrochem. Soc. 154, C424–C430 (2007)
Zhu J.M., Fu H.M., Zhang H.F., Wang A.M., Li H., Hu Z.Q.: Microstructure and compressive properties of multiprincipal component AlCoCrFeNiC x alloys. J. Alloys Compd. 509, 3476–3480 (2011)
Qiao J.W., Ma S.G., Huang E.W.: Microstructural characteristics and mechanical behaviors of AlCoCrFeNi high-entropy alloys at ambient and cryogenic temperatures. Nano-Scale Amour. Mater. 688, 419–425 (2011)
Selmi A., M’nassri R., Cheikhrouhou-Koubaa W.: Effects of partial Mn-substitution on magnetic and magnetocaloric properties in Pr0.7Ca0.3Mn0.95X0.05O3 (Cr, Ni, Co and Fe) manganites. J. Alloys Compd. 619, 627–633 (2015)
Wang, Y.P.: Microstructure and properties of AlCrFeCoNiCu multiprincipal-element alloys and its composites. Ph.D. thesis. School of Materials Science and Engineering, HIT, China (2009)
Ma S.G., Zhang Y.: Effect of Nb addition on the microstructure and properties of AlCoCrFeNi high-entropy alloy. Mater. Sci. Eng. A 532, 480–486 (2012)
Kittel C.: Introduction to Solid State Physics, 7th edn. Wiley, New York (1996)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Chen, Q., Zhou, K., Jiang, L. et al. Effects of Fe Content on Microstructures and Properties of AlCoCrFe x Ni High-Entropy Alloys. Arab J Sci Eng 40, 3657–3663 (2015). https://doi.org/10.1007/s13369-015-1784-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13369-015-1784-9