Skip to main content
Log in

Hydrogenation of Malaysian Palm Mid Fraction on Pricat Nickel Catalyst Using Pilot and Industrial Units

  • Research Article - Chemical Engineering
  • Published:
Arabian Journal for Science and Engineering Aims and scope Submit manuscript

Abstract

Palm mid fraction produced from Malaysian palm olein was hydrogenated using industrial catalyst (PRICAT 9910) on both pilot and industrial units. Effects of hydrogenation parameters, including temperature, catalyst concentration, reaction time, and circulation rate on final fatty acid composition and trans-fatty acid content were investigated. Mass transfer limitations were indicated particularly in the industrial plant runs. Mass transfer coefficient in the gas–liquid transfer was identified for various circulation rates. The combined mass transfer resistance at the liquid–solid interface and within the catalyst pellet was calculated as a function of different temperatures and circulation rates.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Chong, C.L.: Chemical and physical properties of palm oil and palm kernel Oil. In: Selected readings on palm oil and its uses. Palm Oil Research Institute of Malaysia (PORIM), Kuala Lumpur, 60–77 (1994)

  2. Chakravarty Y., Bhatia S., Saraf DN.: A simulation study of industrial vegetable oil hydrogenation reactors. J. Am. Oil Chem. Soc. 59, 157 (1982)

    Article  Google Scholar 

  3. Fernandez M.B., Tonetto G.M., Crapiste G.H., Damiani D.E.: Revisiting the hydrogenation of sunflower oil over a Ni catalyst. J. Food Eng. 82, 199–208 (2007)

    Article  Google Scholar 

  4. Cepeda E.A., Calvo B.: Sunflower oil hydrogenation: study using response surface methodology. J. Food Eng. 89, 370–374 (2008)

    Article  Google Scholar 

  5. Anderson K., Hell M., Lowendahl L., Scoon N.: J. Am. Oil. Chem. Soc. 51, 171 (1974)

    Article  Google Scholar 

  6. Choo H.P., Liew K.Y., Liu H.F., Seng C.E: Hydrogenation of palm olein catalyzed by polymer stabilized Pt colloids. J. Mol. Catal. A Chem. 165, 127–134 (2001)

    Article  Google Scholar 

  7. Rangel, E.R.: Contribution to the study of heterogeneous catalytic reactions in SCFs: hydrogenation of sunflower oil in Pd catalysts at single-phase conditions. PhD thesis, University Politècnica de Cataluny, Spain (2005)

  8. Savchenko V.I., Makaryan I.A.: Palladium catalyst for the production of pure Margarine: catalyst and new non-filtration technology improve production and quality. Platinum Metal Rev. 43, 74–82 (1999)

    Google Scholar 

  9. Fillion B., Morsi B., Heier K., Machado R.: The kinetics for soybean oil hydrogenation using a commercial Ni/Al2O3. Ind. Eng. Chem. Res. 4, 697–709 (2002)

    Article  Google Scholar 

  10. Choo H.P., Liew Y.K., Liu H., Chye Eng Seng C.E., Mahmood K., Bettahar M.: Activity and selectivity of noble metal colloids for the hydrogenation of polyunsaturated soybean oil. J. Mol. Catal. A Chem. 191, 113–121 (2003)

    Article  Google Scholar 

  11. Manoj A.T., Vijaykumar V. M.: Studies in catalytic transfer hydrogenation of soybean oil using ammonium formate as donor over 5% Pd/C catalyst. Chem. Eng. J. 123, 31–34 (2006)

    Article  Google Scholar 

  12. Armfield: Instruction manual for hydrogenation pilot plant FT67 (1997)

  13. AOCS: Official Methods of Analysis. Association of Official Analytical Chemists, 18th edn., Virginia, USA (2002)

  14. Singh D., Rezac M.E., Prfomm R.P.: Partial hydrogenation of soybean oil with minimal trans fat production using a Pt-deocorated polymeric membrane reactor. J. Am. Oil Chem. Soc. 86, 93–101 (2009)

    Article  Google Scholar 

  15. Yuan W., Hansen A.C., Zhang Q.: Vapor pressure and normal boiling point prediction for pure methyl esters and biodiesel fuels. Fuel 84, 943–950 (2005)

    Article  Google Scholar 

  16. Sander, R.: Compilation of Henry’s law constant for inorganic and organic species of potential importance in environmental chemistry. Air Chemistry Department, Max-Planck Institute of Chemistry, Germany, Version 3, (1999)

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ahmed Mubarak Alsobaai.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Alsobaai, A.M., Shaibani, A.M.A., Moustafa, T. et al. Hydrogenation of Malaysian Palm Mid Fraction on Pricat Nickel Catalyst Using Pilot and Industrial Units. Arab J Sci Eng 38, 2273–2278 (2013). https://doi.org/10.1007/s13369-013-0558-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13369-013-0558-5

Keywords

Navigation