Skip to main content
SpringerLink
Log in

Thermodynamic and Electrochemical Investigation of Pantoprazole: {(RS)-6-(difluoromethoxy)-2- [(3,4-dimethoxypyridin-2-yl)methylsulfinyl]-1H-benzo[d]-imidazole} as Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Solution

  • Research Article - Chemistry
  • Published:
Arabian Journal for Science and Engineering Aims and scope Submit manuscript

Abstract

The effect of Pantoprazole on mild steel corrosion in 1.0M HCl was studied by using weight loss, electrochemical impedance spectroscopy and Tafel polarization measurements. The inhibitor showed maximum inhibition efficiency 97.78 % at optimum concentration 60 ppm. Potentiodynamic polarization studies suggested that it is a mixed-type inhibitor. Atomic force microscopy observation supported the formation of inhibitor film over the mild steel surface. Adsorption of inhibitor molecules on the mild steel surface in hydrochloric acid obeyed the Langmuir adsorption isotherm. Thermodynamic parameters, value of activation energy (E a ), enthalpy of activation (ΔH *), adsorption constant (K ads), enthalpy of adsorption \({({\Delta H_{{\rm ads}}^{0}})}\), entropy of adsorption \({({\Delta S_{{\rm ads}}^0})}\) and free energy of adsorption \({({\Delta G_{{\rm ads}}^0})}\), were calculated and discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Schmitt G.: Application of inhibitors in acid media. Br. Corros. J. 19, 165–176 (1984)

    Google Scholar 

  2. Fouda A.S., Ellithy A.S.: Inhibition effect of 4-phenylthiazole derivatives on corrosion of 304L stainless steel in HCl solution. Corros. Sci. 51, 868–875 (2009)

    Article  Google Scholar 

  3. Shukla S.K., Quraishi M.A.: 4-Substituted anilinomethylpropionate: New and efficient corrosion inhibitors for mild steel in hydrochloric acid solution. Corros. Sci. 51, 1990–1997 (2009)

    Article  Google Scholar 

  4. Bentiss F., Lagrenee M., Traisnel M., Hornez J.C.: The corrosion inhibition of mild steel in acidic media by a new triazole derivative. Corros. Sci. 41, 789–803 (1999)

    Article  Google Scholar 

  5. Ayers R.C. Jr., Hackerman N.: Corrosion Inhibition in HCl Using Methyl Pyridines. J. Electrochem. Soc. 110, 507–513 (1963)

    Article  Google Scholar 

  6. Quraishi M.A., Shukla S.K.: Poly(aniline-formaldehyde): a new and effective corrosion inhibitor for mild steel in hydrochloric acid. Mater. Chem. Phys 113, 685–689 (2009)

    Article  Google Scholar 

  7. Ansari F.A., Quraishi M.A.: Inhibitive effect of some gemini surfactants as corrosion inhibitors for mild steel in acetic acid media. Arab. J. Sci. Eng. 36, 11–20 (2011)

    Article  Google Scholar 

  8. Norr E.: The inhibition of mild steel corrosion in phosphoric acid solutions by some N-heterocyclic compounds in the salt form. Corros. Sci. 47, 33–55 (2005)

    Article  Google Scholar 

  9. Ait Chikh Z., Chebabe D., Dharmraj A., Hajjaji N., Srhirri A., Montemor M.F., Ferreira M.G.S., Bastos A.C.: Electrochemical and analytical study of corrosion inhibition on carbon steel in HCl medium by 1,12-bis(1,2,4-triazolyl)dodecane. Corros. Sci. 47, 447–459 (2005)

    Article  Google Scholar 

  10. Lagrenee M., Mernari B., Bouanis M., Traisnel M., Bentiss F.: Study of the mechanism and inhibiting efficiency of 3,5-bis (4-methylthiophenyl)-4H-1,2,4-triazole on mild steel corrosion in acidic media. Corros. Sci. 44, 573–588 (2002)

    Article  Google Scholar 

  11. Quraishi M.A., Sardar R.: Aromatic triazoles as corrosion inhibitors for mild steel in acidic environments. Corrosion 58, 748–755 (2002)

    Article  Google Scholar 

  12. Bentiss F., Bovanis M., Mernari B., Traisnel M., Vezin H., Lagrenee M.: Understanding the adsorption of 4H-1,2,4-triazole derivatives on mild steel surface in molar hydrochloric acid. Appl. Surf. Sci. 253, 3696–3704 (2007)

    Article  Google Scholar 

  13. Shukla S.K., Quraishi M.A.: Cefalexin drug: a new and efficient corrosion inhibitor for mild steel in hydrochloric acid solution. Mater. Chem. Phys. 120, 142–147 (2010)

    Article  Google Scholar 

  14. Ferreira E.S., Giacomelli C., Giacomelli F.C., Spinelli A.: Evaluation of the inhibitor effect of l-ascorbic acid on the corrosion of mild steel. Mater. Chem. Phys. 83, 129–134 (2004)

    Article  Google Scholar 

  15. El-Naggar M.M.: Corrosion inhibition of mild steel in acidic medium by some sulfa drugs compounds. Corros. Sci. 49, 2226–2236 (2007)

    Article  Google Scholar 

  16. Singh A.K., Quraishi M.A.: Effect of Cefazolin on the corrosion of mild steel in HCl solution. 52, 1552–1560 (2010)

  17. Ahamad I., Prasad R., Quraishi M.A.: Inhibition of mild steel corrosion in acid solution by Pheniramine drug: Experimental and theoretical study. Corros. Sci. 52, 3033–3041 (2010)

    Article  Google Scholar 

  18. Moretti G., Guidi F., Grion G.: Tryptamine as a green iron corrosion inhibitor in 0.5 M deaerated sulphuric acid. Corros. Sci. 46, 387–403 (2004)

    Article  Google Scholar 

  19. Steinijans V.W., Huber R., Hartmann M., Zech K., Bliesath H., Wurst W., Radtke H.W.: Lack of pantoprazole drug interactions in man: An updated review. Int. J. Clin. Pharmacol. Ther. 34, 243–262 (1996)

    Google Scholar 

  20. Meyer U.A.: Metabolic interactions of the proton-pump inhibitors lansoprazole, omeprazole and pantoprazole with other drug. Eur. J. Gastroenterol. Hepatol. 8, 21–25 (1996)

    Article  Google Scholar 

  21. Singh A.K., Quraishi M. A.: Investigation of adsorption of isoniazid derivatives at mild steel/hydrochloric acid interface: Electrochemical and weight loss methods. Mater. Chem. Phys. 123, 666–677 (2010)

    Article  Google Scholar 

  22. Fouda A.S., Al-Sarawy A.A., El-Katori E.E.: Pyrazolone derivatives as corrosion inhibitors for C-steel in hydrochloric acid solution. Desalination 201, 1–13 (2006)

    Article  Google Scholar 

  23. Bouklah M., Hammouti B., LagrenTe M., Bentiss F.: Thermodynamic properties of 2,5-bis(4-methoxyphenyl)-1,3,4-oxadiazole as a corrosion inhibitor for mild steel in normal sulfuric acid medium. Corros. Sci. 48, 2831–2842 (2006)

    Article  Google Scholar 

  24. Juttner K.: Electrochemical impedance spectroscopy (EIS) of corrosion processes on inhomogeneous surfaces. Electrochim. Acta 35, 1501–5108 (1990)

    Article  Google Scholar 

  25. Elayyachy M., El Idrissi A., Hammouti B.: New thio-compounds as corrosion inhibitor for steel in 1 M HCl. Corros. Sci. 48, 2470–2479 (2006)

    Article  Google Scholar 

  26. Quraishi M.A., Rawat J., Ajmal M.: Technical note: synergistic effect of iodide ions on inhibitive performance of substituted dithiobiurets during corrosion of mild steel in hot hydrochloric acid. Corrosion 55, 919–923 (1999)

    Article  Google Scholar 

  27. Goncalves, R.S.; Azambuja, D.S.: Serpa Lucho, A.M.: Electrochemical studies of propargyl alcohol as corrosion inhibitor for nickel, copper, and copper/nickel (55/45) alloy. Corros. Sci. 44, 467–479 (2002)

    Google Scholar 

  28. Amin M.A., Abd El-Rehim S.S., El-Sherbini E.E.F., Bayyomi R.S.: The inhibition of low carbon steel corrosion in hydrochloric acid solutions by succinic acid: part I. Weight loss, polarization, EIS, PZC, EDX and SEM studies. Electrochim. Acta 52, 3588–3600 (2007)

    Google Scholar 

  29. Lenderrink H.J.W., Linden M.V.D., De Wit J.H.W.: Corrosion of aluminium in acidic and neutral solutions. Electrochim. Acta 38, 1989–1992 (1993)

    Article  Google Scholar 

  30. Veloz M.A., Gonzáaalez I.: Electrochemical study of carbon steel corrosion in buffered acetic acid solutions with chlorides and H2S. Electrochim. Acta 48, 135–144 (2002)

    Article  Google Scholar 

  31. Sherif E.M., Park S.M.: Effects of 1,4-naphthoquinone on aluminum corrosion in 0.50 M sodium chloride solutions. Electrochim. Acta 51, 1313–1321 (2006)

    Article  Google Scholar 

  32. Hassan H.H., Amin M.A., Gubbala S., Sunkara M.K.: Participation of the dissolved O2 in the passive layer formation on Zn surface in neutral media. Electrochim. Acta 52, 6929–6937 (2007)

    Article  Google Scholar 

  33. Singh A.K., Quraishi M.A.: Inhibiting effects of 5-substituted isatin-based Mannich bases on the corrosion of mild steel in hydrochloric acid solution. J. Appl. Electrochem. 40, 1293–1306 (2010)

    Article  Google Scholar 

  34. Singh A.K., Quraishi M.A.: The effect of some bis-thiadiazole derivatives on the corrosion of mild steel in hydrochloric acid. Corros.Sci. 52, 1373–1385 (2010)

    Article  Google Scholar 

  35. Kedam M., Mattos O.R., Takenouti H.: Reaction model for iron dissolution studied by electrode impedance. J. Electrochem. Soc. 128, 257–266 (1981)

    Article  Google Scholar 

  36. Hassan H.H.: Perchlorate and oxygen reduction during Zn corrosion in a neutral medium. Electrochim. Acta 51, 5966–5972 (2006)

    Article  Google Scholar 

  37. McCafferty E., Hackerman N.: Double layer capacitance of iron and corrosion inhibition with polymethylene diamines. J. Electrochem. Soc. 119, 146–154 (1972)

    Article  Google Scholar 

  38. Riggs O.L. Jr.: Corrosion Inhibitors, 2nd edn. C. C. Nathan, Houston (1973)

    Google Scholar 

  39. Li X.H., Deng S.D., Mu G.N., Fu H., Yang F.Z.: Inhibition effect of nonionic surfactant on the corrosion of cold rolled steel in hydrochloric acid. Corros. Sci. 50, 420–430 (2008)

    Article  Google Scholar 

  40. Li X.H., Deng S.D., Fu H., Mu G.N.: Synergistic inhibition effect of rare earth cerium(IV) ion and anionic surfactant on the corrosion of cold rolled steel in H2SO4 solution. Corros. Sci. 50, 2635–2645 (2008)

    Article  Google Scholar 

  41. Ahamad I., Prasad R., Quraishi M.A.: Adsorption and inhibitive properties of some new Mannich bases of Isatin derivatives on corrosion of mild steel in acidic media. Corros. Sci. 52, 1472–1481 (2010)

    Article  Google Scholar 

  42. Szauer T., Brand A.: Adsorption of oleates of various amines on iron in acidic solution. Electrochim. Acta 26, 1253–1256 (1981)

    Article  Google Scholar 

  43. Guan N.M., Xueming L., Fei L.: Synergistic inhibition between o-phenanthroline and chloride ion on cold rolled steel corrosion in phosphoric acid. Mater. Chem. Phys. 86, 59–68 (2004)

    Article  Google Scholar 

  44. Flis J., Zakroczymski T.: Impedance study of reinforcing steel in simulated pore solution with tannin. J. Electrochem. Soc. 143, 2458–2464 (1996)

    Article  Google Scholar 

  45. Abboud Y., Abourriche A., Saffaj T., Berrada M., Charrouf M., Bennamara A., Hannache H.: A novel azo dye, 8-quinolinol-5-azoantipyrine as corrosion inhibitor for mild steel in acidic media. Desalination 237, 175–189 (2009)

    Article  Google Scholar 

  46. Donahue F.M., Nobe K.: Theory of Organic Corrosion Inhibitors. J. Electrochem. Soc. 112, 886–891 (1965)

    Article  Google Scholar 

  47. Bentiss F., Traisnel M., Chaibi N., Mernari B., Vezin H., Lagreneáae M.: 2,5-Bis(n-methoxyphenyl)-1,3,4-oxadiazoles used as corrosion inhibitors in acidic media: correlation between inhibition efficiency and chemical structure. Corros. Sci. 44, 2271–2289 (2002)

    Article  Google Scholar 

  48. Tang L., Mu G., Liu G.: The effect of neutral red on the corrosion inhibition of cold rolled steel in 1.0 M hydrochloric acid. Corros. Sci. 45, 2251–2262 (2003)

    Article  Google Scholar 

  49. Benali O., Larabi L., Harek Y.: Adsorption and inhibitive corrosion properties of thiourea derivatives on cold rolled steel in 1 M HClO4 solutions. J. Appl. Electrochem. 39, 769–778 (2009)

    Article  Google Scholar 

  50. Hermas A.A., Morad M.S., Wahdan M.H.: Effect of PgTPhPBr on the electrochemical and corrosion behaviour of 304 stainless steel in H2SO4 solution. J. Appl. Electrochem. 34, 95–102 (2004)

    Article  Google Scholar 

  51. Tang L., Li X., Li L., Mu G., Liu G.: The effect of 1-(2-pyridylazo)-2-naphthol on the corrosion of cold rolled steel in acid media: part 2: inhibitive action in 0.5 M sulfuric acid. Mater. Chem. Phys. 97, 301–307 (2006)

    Article  Google Scholar 

  52. Popova A., Christov M., Raicheva S., Sokolova E.: Adsorption and inhibitive properties of benzimidazole derivatives in acid mild steel corrosion. Corros. Sci. 46, 1333–1350 (2004)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Applied Chemistry, Indian Institute of Technology, Banaras Hindu University, Varanasi, 221 005, India

    Sudheer & M. A. Quraishi

Authors
  1. Sudheer
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. A. Quraishi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. A. Quraishi.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sudheer, Quraishi, M.A. Thermodynamic and Electrochemical Investigation of Pantoprazole: {(RS)-6-(difluoromethoxy)-2- [(3,4-dimethoxypyridin-2-yl)methylsulfinyl]-1H-benzo[d]-imidazole} as Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Solution. Arab J Sci Eng 38, 99–109 (2013). https://doi.org/10.1007/s13369-012-0408-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13369-012-0408-x

Keywords

Search

Navigation