Abstract
To investigate the impacts of relative humidity (RH) on secondary organic aerosol (SOA) concentrations and chemical reactions, the carbonaceous aerosol components [i.e., organic carbon (OC) and element carbon (EC)] were quantified in daily PM2.5 samples collected at a background site in East China during summer 2015. Based on the method of EC-tracer, the concentration of secondary organic carbon (SOC) demonstrated an obvious negative relationship with RH higher than 60%. Moreover, the ratio of SOC/EC also exhibited obvious decreasing trends with increasing RH, indicating negative effects for chemical production of SOA under high RH conditions. Due to high RH, photochemistry was weakened, gaseous oxidant concentrations was lowered (e.g., significantly decreased O3 levels), and the production rates of SOA were relatively low. On the other hand, because of more water uptake under higher RH conditions, the aerosol droplet acidity was reduced and enhancement of SOA formation by acidity was accordingly absent. In addition, high RH also plays an important role in changing viscosity of pre-existing aerosol coatings, which can affect reactive uptake yield of SOA. Overall, the results from this study imply that SOA production may be more associated with photochemical processes, while aqueous-phase chemistry is not very important for some SOA formation in a moist ambient environment. In the ambient atmosphere, oxidant concentrations, reaction rates, airborne species, etc., are highly variable. How do these factors affect SOA yields under given ambient environment warrants further detailed investigations.
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References
Bougiatioti, A., P. Nikolaou, I. Stavroulas, et al., 2016: Particle water and pH in the eastern Mediterranean: Source variability and implications for nutrient availability. Atmos. Chem. Phys., 16, 4579–4591, doi: https://doi.org/10.5194/acp-16-4579-2016.
Boyd, C. M., J. Sanchez, L. Xu, et al., 2015: Secondary organic aerosol formation from the β-pinene+NO3 system: Effect of humidity and peroxy radical fate. Atmos. Chem. Phys., 15, 7497–7522, doi: https://doi.org/10.5194/acp-15-7497-2015.
Chen, C.-L., S. J. Chen, L. M. Russell, et al., 2018: Organic aerosol particle chemical properties associated with residential burning and fog in wintertime San Joaquin Valley (Fresno) and with vehicle and firework emissions in summertime South Coast Air Basin (Fontana). J. Geophys. Res. Atmos., 123, 10707–10731, doi: https://doi.org/10.1029/2018JD028374.
Cheng, Y., K. B. He, Z. Y. Du, et al., 2015: Humidity plays an important role in the PM2.5 pollution in Beijing. Environ. Pollut., 197, 68–75, doi: https://doi.org/10.1016/j.envpol.2014.11.028.
Chow, J. C., J. G. Watson, Z. Q. Lu, et al., 1996: Descriptive analysis of PM2.5 and PM10 at regionally representative locations during SJVAQS/AUSPEX. Atmos. Environ., 30, 2079–2112, doi: https://doi.org/10.1016/1352-2310(95)00402-5.
Ding, X., M. Zheng, L. P. Yu, et al., 2008: Spatial and seasonal trends in biogenic secondary organic aerosol tracers and water-soluble organic carbon in the southeastern United States. Environ. Sci. Technol., 42, 5171–5176, doi: https://doi.org/10.1021/es7032636.
Dominguez-Taylor, P., L. G. Ruiz-Suarez, I. Rosas-Perez, et al., 2007: Monoterpene and isoprene emissions from typical tree species in forests around Mexico City. Atmos. Environ., 41, 2780–2790, doi: https://doi.org/10.1016/j.atmosenv.2006.11.042.
Ervens, B., and R. Volkamer, 2010: Glyoxal processing by aerosol multiphase chemistry: Towards a kinetic modeling framework of secondary organic aerosol formation in aqueous particles. Atmos. Chem. Phys., 10, 8219–8244, doi: https://doi.org/10.5194/acp-10-8219-2010.
Ervens, B., B. J. Turpin, and R. J. Weber, 2011: Secondary organic aerosol formation in cloud droplets and aqueous particles (aqSOA): A review of laboratory, field and model studies. Atmos. Chem. Phys., 11, 11069–11102, doi: https://doi.org/10.5194/acp-11-11069-2011.
Ervens, B., A. Sorooshian, Y. B. Lim, et al., 2014: Key parameters controlling OH-initiated formation of secondary organic aerosol in the aqueous phase (aqSOA). J. Geophys. Res. Atmos., 119, 3997–4016, doi: https://doi.org/10.1002/2013JD021021.
Gaston, C. J., T. P. Riedel, Z. F. Zhang, et al., 2014: Reactive uptake of an isoprene-derived epoxydiol to submicron aerosol particles. Environ. Sci. Technol., 48, 11178–11186, doi: https://doi.org/10.1021/es5034266.
Ge, X. L., Q. Zhang, Y. L. Sun, et al., 2012: Effect of aqueousphase processing on aerosol chemistry and size distributions in Fresno, California, during wintertime. Environ. Chem., 9, 221–235, doi: https://doi.org/10.1071/EN11168.
Ge, X. L., L. Li, Y. F. Chen, et al., 2017: Aerosol characteristics and sources in Yangzhou, China resolved by offline aerosol mass spectrometry and other techniques. Environ. Pollut., 225, 74–85, doi: https://doi.org/10.1016/j.envpol.2017.03.044.
Grayson, J. W., Y. Zhang, A. Mutzel, et al., 2016: Effect of varying experimental conditions on the viscosity of α-pinene derived secondary organic material. Atmos. Chem. Phys., 16, 6027–6040, doi: https://doi.org/10.5194/acp-16-6027-2016.
Guo, H., L. Xu, A. Bougiatioti, et al., 2015: Fine-particle water and pH in the southeastern United States. Atmos. Chem. Phys., 15, 5211–5228, doi: https://doi.org/10.5194/acp-15-5211-2015.
Hallquist, M., J. C. Wenger, U. Baltensperger, et al., 2009: The formation, properties and impact of secondary organic aerosol: Current and emerging issues. Atmos. Chem. Phys., 9, 5155–5236, doi: https://doi.org/10.5194/acp-9-5155-2009.
He, Q. F., X. Ding, X. X. Fu, et al., 2018: Secondary organic aerosol formation from isoprene epoxides in the Pearl River Delta, South China: IEPOX- and HMML-derived tracers. J. Geophys. Res. Atmos., 123, 6999–7012, doi: https://doi.org/10.1029/2017JD028242.
Heald, C. L., and D. V. Spracklen, 2009: Atmospheric budget of primary biological aerosol particles from fungal spores. Geophys. Res. Lett., 36, L09806, doi: https://doi.org/10.1029/2009GL037493.
Hennigan, C. J., J. Izumi, A. P. Sullivan, et al., 2015: A critical evaluation of proxy methods used to estimate the acidity of atmospheric particles. Atmos. Chem. Phys., 15, 2775–2790, doi: https://doi.org/10.5194/acp-15-2775-2015.
Jia, L., and Y. F. Xu, 2016: Ozone and secondary organic aerosol formation from Ethylene-NOx-NaCl irradiations under different relative humidity conditions. J. Atmos. Chem., 73, 81–100, doi: https://doi.org/10.1007/s10874-015-9317-1.
Kanakidou, M., J. H. Seinfeld, S. N. Pandis, et al., 2005: Organic aerosol and global climate modelling: A review. Atmos. Chem. Phys., 5, 1053–1123, doi: https://doi.org/10.5194/acp-5-1053-2005.
Kaul, D. S., T. Gupta, S. N. Tripathi, et al., 2011: Secondary organic aerosol: A comparison between foggy and nonfoggy days. Environ. Sci. Technol., 45, 7307–7313, doi: https://doi.org/10.1021/es201081d.
Liang, L. L., G. Engling, Z. Y. Du, et al., 2016: Seasonal variations and source estimation of saccharides in atmospheric particulate matter in Beijing, China. Chemosphere, 150, 365–377, doi: https://doi.org/10.1016/j.chemosphere.2016.02.002.
Liang, L. L., G. Engling, X. Y. Zhang, et al., 2017: Chemical characteristics of PM2.5 during summer at a background site of the Yangtze River Delta in China. Atmos. Res., 198, 163–172, doi: https://doi.org/10.1016/j.atmosres.2017.08.012.
Lim, H. J., and B. J. Turpin, 2002: Origins of primary and secondary organic aerosol in Atlanta: Results of time-resolved measurements during the Atlanta Supersite Experiment. Environ. Sci. Technol., 36, 4489–4496, doi: https://doi.org/10.1021/es0206487.
Lim, Y. B., Y. Tan, M. J. Perri, et al., 2010: Aqueous chemistry and its role in secondary organic aerosol (SOA) formation. Atmos. Chem. Phys., 10, 10521–10539, doi: https://doi.org/10.5194/acp-10-10521-2010.
Lin, Y. H., Z. F. Zhang, K. S. Docherty, et al., 2012: Isoprene epoxydiols as precursors to secondary organic aerosol formation: Acid-catalyzed reactive uptake studies with authentic compounds. Environ. Sci. Technol., 66, 250–258, doi: https://doi.org/10.1021/es202554c.
Liu, M. X., Y. Song, T. Zhou, et al., 2017: Fine particle pH during severe haze episodes in northern China. Geophys. Res. Lett., 44, 5213–5221, doi: https://doi.org/10.1002/2017GL073210.
Monson, R. K., P. C. Harley, M. E. Litvak, et al., 1994: Environmental and developmental controls over the seasonal pattern of isoprene emission from aspen leaves. Oecologia, 99, 260–270, doi: https://doi.org/10.1007/BF00627738.
Nguyen, T. B., P. J. Roach, J. Laskin, et al., 2011: Effect of humidity on the composition of isoprene photooxidation secondary organic aerosol. Atmos. Chem. Phys., 11, 6931–6944, doi: https://doi.org/10.5194/acp-11-6931-2011.
Paulot, F., J. D. Crounse, H. G. Kjaergaard, et al., 2009: Unexpected epoxide formation in the gas-phase photooxidation of isoprene. Science, 325, 730–733, doi: https://doi.org/10.1126/science.1172910.
Renbaum-Wolff, L., J. W. Grayson, A. P. Bateman, et al., 2013: Viscosity of α-pinene secondary organic material and implications for particle growth and reactivity. Proc. Natl. Acad. Sci. USA, 110, 8014–8019, doi: https://doi.org/10.1073/pnas.1219548110.
Riedel, T. P., Y. H. Lin, S. H. Budisulistiorini, et al., 2015: Heterogeneous reactions of isoprene-derived epoxides: Reaction probabilities and molar secondary organic aerosol yield estimates. Environ. Sci. Technol. Lett., 2, 38–42, doi: https://doi.org/10.1021/ez500406f.
Sun, Y. L., Z. F. Wang, P. Q. Fu, et al., 2013: The impact of relative humidity on aerosol composition and evolution processes during wintertime in Beijing, China. Atmos. Environ., 77, 927–934, doi: https://doi.org/10.1016/j.atmosenv.2013.06.019.
Sun, Y. L., Q. Jiang, Z. F. Wang, et al., 2014: Investigation of the sources and evolution processes of severe haze pollution in Beijing in January 2013. J. Geophys. Res. Atmos., 119, 4380–4398, doi: https://doi.org/10.1002/2014JD021641.
Surratt, J. D., A. W. H. Chan, N. C. Eddingsaas, et al., 2010: Reactive intermediates revealed in secondary organic aerosol formation from isoprene. Proc. Natl. Acad. Sci. USA, 107, 6640–6645, doi: https://doi.org/10.1073/pnas.0911114107.
Varutbangkul, V., F. J. Brechtel, R. Bahreini, et al., 2006: Hygroscopicity of secondary organic aerosols formed by oxidation of cycloalkenes, monoterpenes, sesquiterpenes, and related compounds. Atmos. Chem. Phys., 6, 2367–2388, doi: https://doi.org/10.5194/acp-6-2367-2006.
Wang, D. F., B. Zhou, Q. Y. Fu, et al., 2016: Intense secondary aerosol formation due to strong atmospheric photochemical reactions in summer: Observations at a rural site in eastern Yangtze River Delta of China. Sci. Total Environ., 571, 1454–1466, doi: https://doi.org/10.1016/j.scitotenv.2016.06.212.
Wong, J. P. S., S. M. Zhou, and J. P. D. Abbatt, 2015: Changes in secondary organic aerosol composition and mass due to photolysis: Relative humidity dependence. J. Phys. Chem. A, 119, 4309–4316, doi: https://doi.org/10.1021/jp506898c.
Wu, Y. Z., X. L. Ge, J. F. Wang, et al., 2018: Responses of secondary aerosols to relative humidity and photochemical activities in an industrialized environment during late winter. Atmos. Environ., 193, 66–78, doi: https://doi.org/10.1016/j.atmoeenv.2018.09.008.
Zhang, H., J. D. Surratt, Y. H. Lin, et al., 2011: Effect of relative humidity on SOA formation from isoprene/NO photooxidation: Enhancement of 2-methylglyceric acid and its corresponding oligoesters under dry conditions. Atmos. Chem. Phys., 11, 6411–6424, doi: https://doi.org/10.5194/acp-11-6411-2011.
Zhang, H. F., Z. F. Zhang, T. Q. Cui, et al., 2014: Secondary organic aerosol formation via 2-methyl-3-buten-2-ol photooxidation: Evidence of acid-catalyzed reactive uptake of epoxides. Environ. Sci. Technol. Lett, 1, 242–247, doi: https://doi.org/10.1021/ez500055f.
Zhang, Q., J. L. Jimenez, M. R. Canagaratna, et al., 2007: Ubiquity and dominance of oxygenated species in organic aerosols in anthropogenically-influenced Northern Hemisphere midlatitudes. Geophys. Res. Lett., 34, L13801, doi: https://doi.org/10.1029/2007GL029979.
Zhang, X. L., J. M. Liu, E. T. Parker, et al., 2012: On the gasparticle partitioning of soluble organic aerosol in two urban atmospheres with contrasting emissions: 1. Bulk water-soluble organic carbon. J. Geophys. Res. Atmos., 117, D00V16, doi: https://doi.org/10.1029/2012JD017908.
Zhang, Y., Y. Z. Chen, A. T. Lambe, et al., 2018: Effect of the aerosol-phase state on secondary organic aerosol formation from the reactive uptake of isoprene-derived epoxydiols (IEPOX). Environ. Sci. Technol. Lett., 5, 167–174, doi: https://doi.org/10.1021/acs.estlett.8b00044.
Zhao, J., N. P. Levitt, R. Y. Zhang, et al., 2006: Heterogeneous reactions of methylglyoxal in acidic media: Implications for secondary organic aerosol formation. Environ. Sci. Technol., 40, 7682–7687, doi: https://doi.org/10.1021/es060610k.
Zheng, G. J., F. K. Duan, H. Su, et al., 2015: Exploring the severe winter haze in Beijing: The impact of synoptic weather, regional transport and heterogeneous reactions. Atmos. Chem. Phys., 15, 2969–2983, doi: https://doi.org/10.5194/acp-15-2969-2015.
Zhou, Y., H. F. Zhang, H. M. Parikh, et al., 2011: Secondary organic aerosol formation from xylenes and mixtures of toluene and xylenes in an atmospheric urban hydrocarbon mixture: Water and particle seed effects (II). Atmos. Environ., 45, 3882–3890, doi: https://doi.org/10.1016/j.atmosenv.2010.12.048.
Acknowledgment
Financial support was also provided partly by the Ministry of Science and Technology (MOST) of Taiwan, China (MOST 103-2113-M-007-005). We are grateful to Professor Xiaobin Xu for providing the O3 and CO data.
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Supported by the National Key Research and Development Program of China (2016YFC0202300 and 2017YFC0212803), Beijing Natural Science Foundation (8192055), State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex (SCAPC201701), and Basic Research and Operation Funds of Chinese Academy of Meteorological Sciences (2015Y001 and 2017Z011).
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Liang, L., Engling, G., Cheng, Y. et al. Influence of High Relative Humidity on Secondary Organic Carbon: Observations at a Background Site in East China. J Meteorol Res 33, 905–913 (2019). https://doi.org/10.1007/s13351-019-8202-2
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DOI: https://doi.org/10.1007/s13351-019-8202-2