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Dynamic Covalent Polymerization of Chalcogenide Hybrid Inorganic/Organic Polymer Resins with Norbornenyl Comonomers

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Abstract

Elemental sulfur (S8) is an inexpensive chemical feedstock for polymeric materials but has the disadvantages of poor solubility in organic media and inferior physical properties in the elemental form. We report on the preparation of organosulfur chalcogenide hybrid inorganic/organic polymer (CHIPs) based on bifunctional norbornene comonomers using dynamic covalent polymerization (DCP). A poly(sulfur-random-styrene) (p(S-r-Sty)) resin was utilized to address the limited solubility/ miscibility of norbornene-containing comonomers in liquid sulfur. This report demonstrated the ability to expand the scope of organic comonomers to prepare organosulfur CHIPs from elemenatal sulfur using a combination of inverse vulcanization and dynamic covalent polymerization.

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Authors and Affiliations

  1. Department of Polymer Science, Pusan National University, Pusan, 46241, Korea

    Minho Kwon, Hongchan Lee & Hyun-jong Paik

  2. Department of Chemistry, Kwangwoon University, Seoul, 01897, Korea

    Seo-Hui Lee & Heung Bae Jeon

  3. Department of Electronics Engineering, Pusan National University, Pusan, 46241, Korea

    Min-Cheol Oh

  4. Department of Chemistry & Biochemistry, University of Arizona, Tucson, Arizona, USA

    Jeffrey Pyun

Authors
  1. Minho Kwon
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  2. Hongchan Lee
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  3. Seo-Hui Lee
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  4. Heung Bae Jeon
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  5. Min-Cheol Oh
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  6. Jeffrey Pyun
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  7. Hyun-jong Paik
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Corresponding authors

Correspondence to Jeffrey Pyun or Hyun-jong Paik.

Additional information

Supporting information: Information is available regarding the 1H NMR spectra, elemental analysis, DSC, and SEC of 4NC and CHIPs. The materials are available via the Internet at http://www.springer.com/13233.

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Acknowledgments: This research was supported by PNU-RENovation (2018-2019) and the Industrial Strategic Technology Development Program (10067128) funded by the Ministry of Trade, Industry and Energy (MOTIE) of Korea and the National Science Foundation (NSF CHE-1807395).

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Kwon, M., Lee, H., Lee, SH. et al. Dynamic Covalent Polymerization of Chalcogenide Hybrid Inorganic/Organic Polymer Resins with Norbornenyl Comonomers. Macromol. Res. 28, 1003–1009 (2020). https://doi.org/10.1007/s13233-020-8136-7

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  • DOI: https://doi.org/10.1007/s13233-020-8136-7

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