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Design of h-BN-Filled Cyanate/Epoxy Thermal Conductive Composite with Stable Dielectric Properties

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Abstract

The thermal conductive cyanate ester/epoxy (CE/AG80) composites with hexagonal boron nitride (h-BN) reinforced were manufactured and investigated. The low and stable dielectric constant/loss of the composites with respect to both frequency (500 Hz-100 kHz) and temperature (50-350 °C) were discussed as functions of the content of h-BN. It was found that the low and stable dielectric constant/ loss of the composites can be maintained in the whole frequency range at room temperature, and the mutations of constant/loss at the frequency of 1 kHz occurred above 280 °C for all of the samples. Moreover, a remarkable enhancement of the thermal conductivity (0.54 W/mK a 1.8-fold enhancement) was achieved with the introduction of h-BN and significantly outperformed traditional thermal conductive fillers. The significant improvements of the thermal conductivity of the composites were analyzed by the Agari’s model and the parameters of C1 and C2 were also calculated.

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References

  1. A. Boudenne, L. Ibos, M. Fois, J. Majesté, and E. Géhin, Compos. Part A: Appl. Sci. Manuf., 36, 1545 (2005).

    Article  CAS  Google Scholar 

  2. S. Singha and M. J. Thomas, IEEE Trans. Dielectr. Electr. Insul., 15, 12 (2008).

    Article  CAS  Google Scholar 

  3. H. He, R. Fu, Y. Han, Y. Shen, and X. Song, J. Mater. Sci., 42, 6749 (2007).

    Article  CAS  Google Scholar 

  4. M. J. Meziani, W. L. Song, P. Wang, F. Lu, Z. Hou, A. Anderson, H. Maimaiti, and Y. P. Sun, Chem. Phys. Chem., 16, 1339 (2015).

    Article  CAS  PubMed  Google Scholar 

  5. Z. Shi, M. Radwan, S. Kirihara, Y. Miyamoto, and Z. Jin, Appl. Phys. Lett., 95, 224104 (2009).

    Article  CAS  Google Scholar 

  6. K. Yung and H. Liem, J. Appl. Polym. Sci., 106, 3587 (2007).

    Article  CAS  Google Scholar 

  7. W. Zhou, C. Wang, T. Ai, K. Wu, F. Zhao, and H. Gu, Compos. Part A: Appl. Sci. Manuf., 40, 830 (2009).

    Article  CAS  Google Scholar 

  8. K. Sato, H. Horibe, T. Shirai, Y. Hotta, H. Nakano, H. Nagai, K. Mitsuishi, and K. Watari, J. Mater. Chem., 20, 2749 (2010).

    Article  CAS  Google Scholar 

  9. S. Z. Yu, P. Hing, and X. Hu, Compos. Part A: Appl. Sci. Manuf., 33, 289 (2002).

    Article  Google Scholar 

  10. S. Kemaloglu, G. Ozkoc, and A. Aytac, Polym. Compos., 31, 1398 (2009).

    Google Scholar 

  11. X. Huang, L. Xie, P. Jiang, G. Wang, and F. Liu, J. Phys. D: Appl. Phys., 42, 245407 (2009).

    Article  CAS  Google Scholar 

  12. S. Yu, P. Hing, and X. Hu, Compos. Part A: Appl. Sci. Manuf., 33, 289 (2002).

    Article  Google Scholar 

  13. J. W. Gu, Y. Q. Guo, X. T. Yang, C. B. Liang, W. C. Geng, L. Tang, N. Li, and Q. Y. Zhang, Compos. Part A: Appl. Sci. Manuf., 95, 267 (2017).

    Article  CAS  Google Scholar 

  14. A. Yu, P. Ramesh, M. E. Itkis, E. Bekyarova, and R. C. Haddon, J. Phys. Chem. C, 111, 7565 (2007).

    Article  CAS  Google Scholar 

  15. J. W. Gu, C. B. Liang, X. M. Zhao, B. Gan, H. Qiu, Y. Q. Guo, X. T. Yang, Q. Y. Zhang, and D. Y. Wang, Compos. Sci. Technol., 139, 83 (2017).

    Article  CAS  Google Scholar 

  16. J. W. Gu, Z. Y. Lv, Y. L. Wu, Y. Q. Guo, L, D, Tian, H. Qiu, W. Z. Li, and Q. Y. Zhang, Compos. Part A: Appl. Sci. Manuf., 94, 209 (2017).

    Article  CAS  Google Scholar 

  17. J. P. Eloundou, Eur. Polym. J., 38, 431 (2002).

    Article  CAS  Google Scholar 

  18. Z. Pu, L. Chen, L. Tong, Y. Long, X. Huang, and X. Liu, Mater. Lett., 109, 116 (2013).

    Article  CAS  Google Scholar 

  19. X. Huang, Z. Pu, M. Feng, L. Tong, and X. Liu, Mater. Lett., 96, 139 (2013).

    Article  CAS  Google Scholar 

  20. A. Broido, Polym. Phys., 2, 1761 (1969).

    Article  Google Scholar 

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Authors and Affiliations

  1. Research Branch of Advanced Functional Materials, School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu, 611731, P. R. China

    Yangxue Lei, Zengmao Han, Dengxun Ren, Hai Pan, Mingzhen Xu & Xiaobo Liu

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  1. Yangxue Lei
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  2. Zengmao Han
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  3. Dengxun Ren
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  4. Hai Pan
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  5. Mingzhen Xu
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  6. Xiaobo Liu
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Corresponding authors

Correspondence to Mingzhen Xu or Xiaobo Liu.

Additional information

Acknowledgments: The authors wish to thank for financial support from the National Natural Science Foundation (No. 51373028, No. 51403029), and South Wisdom Valley Innovative Research Team Program.

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Lei, Y., Han, Z., Ren, D. et al. Design of h-BN-Filled Cyanate/Epoxy Thermal Conductive Composite with Stable Dielectric Properties. Macromol. Res. 26, 602–608 (2018). https://doi.org/10.1007/s13233-018-6090-4

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  • DOI: https://doi.org/10.1007/s13233-018-6090-4

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