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Preparation and characterization of expanded graphite intercalation compound/UV-crosslinked acrylic resin pressure sensitive adhesives

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Abstract

The expanded graphite intercalated compound (xGIC)/pressure sensitive adhesives (PSAs) were prepared by syrup process and in situ process. The effects of xGIC filler on the morphology and property of acrylic resin based UV-crosslinked PSA were investigated. The xGICs showed more uniform dispersion in acrylic matrix and the degree of filler connection was more prominent in the syrup process than in situ process. The peel strength and tackiness of UV-crosslinked PSAs were strongly dependent on the amount of the filler and the peel strength decreased with increasing xGIC. The thermal conductivity of PSAs was explained in terms of filler dispersion, wetting, and matrix infiltration. The thermal conductivity of PSA was 0.46 W/mK by adding 20 wt% of xGIC, which was 287% improvement compared to the unfilled PSA. It is speculated that 2-dimensional xGIC fillers effectively formed the thermal pathway.

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Authors and Affiliations

  1. Department of Polymer Science and Engineering, Korea National University of Transportation, Chungju, Chungbuk, 380-702, Korea

    Gyu-Dae Park, Hyun-Ok Jung, Kyung-Min Kim, Jung-Hyurk Lim & Sung-Ryong Kim

  2. R&D Center, Mirae-Nanotech Corporation, Ohchang, Chungbuk, 381-430, Korea

    Ju-Won Lee

  3. Advanced Materials Division, Korea Research Institute of Chemical Technology, Daejeon, 305-600, Korea

    Sung-Goo Lee

  4. Chemical Materials Solutions Process Center, Korea Research Institute of Chemical Technology, Daejeon, 305-600, Korea

    Jae Heung Lee

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  1. Gyu-Dae Park
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  6. Sung-Goo Lee
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Correspondence to Sung-Ryong Kim.

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Park, GD., Jung, HO., Kim, KM. et al. Preparation and characterization of expanded graphite intercalation compound/UV-crosslinked acrylic resin pressure sensitive adhesives. Macromol. Res. 23, 396–401 (2015). https://doi.org/10.1007/s13233-015-3064-7

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  • DOI: https://doi.org/10.1007/s13233-015-3064-7

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