Skip to main content
Log in

Morphology and properties of polyamide/multi-walled carbon nanotube composites

  • Published:
Macromolecular Research Aims and scope Submit manuscript

Abstract

The effect of van der Waals force interactions between multi-walled carbon nanotubes and the polymer matrix was examined using three different types of polyamides: polyamide 6, polyamide 11 and polyamide 12. A comparison of the degree of dispersion of multi-walled carbon nanotubes in the polymer and the measured physical properties showed that the hydrophobicity of the polymer matrix is an important factor for determining the properties of the polyamide nanocomposite material. Polyamides with longer hydrophobic methylene groups in the repeating unit had a better dispersion of multi-walled carbon nanotubes and correspondingly lower surface resistivity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. H. Baughman, A. A. Zakhidov, and W. A. de Heer, Science, 297, 787 (2002).

    Article  CAS  Google Scholar 

  2. X. L. Xie, Y. W. Mai, and X. P. Zhou, Mater. Sci. Eng. R, 49, 89 (2005).

    Article  Google Scholar 

  3. M. Moniruzzaman and K. I. Winey, Macromolecules, 39, 5194 (2006).

    Article  CAS  Google Scholar 

  4. S. Iijima, Nature, 354, 56 (1991).

    Article  CAS  Google Scholar 

  5. A. J. Crosby and J. Y. Lee, Polym. Rev. Lett., 47, 217 (2007).

    CAS  Google Scholar 

  6. H. Wang, W. Zhou, D. L. Ho, K. I. Winey, J. E. Fischer, C. J. Glinka, and E. K. Hobbie, Nano Lett., 4, 1789 (2004).

    Article  CAS  Google Scholar 

  7. M. F. Islam, E. Rojas, D. M. Bergey, A. T. Johnson, and A. G. Yodh, Nano Lett., 3, 269 (2003).

    Article  CAS  Google Scholar 

  8. K. Saeed, S. Y. Park, H. J. Lee, J. B. Baek, and W. S. Huh, Polymer, 47, 8019 (2006).

    Article  CAS  Google Scholar 

  9. J. N. Coleman, S. Curran, A. B. Dalton, A. P. Davey, B. McCarthy, W. Blau, and R. C. Barklie, Phys. Rev. B, 58, R7492 (1998).

    Article  CAS  Google Scholar 

  10. V. C. Moore, M. S. Strano, E. H. Haroz, R. H. Hauge, and R. E. Smalley, Nano Lett., 3, 1379 (2003).

    Article  CAS  Google Scholar 

  11. S. H. Lee, J. S. Park, C. M. Koo, B. K. Lim, and S. O. Kim, Macromol. Res., 16, 261 (2008).

    CAS  Google Scholar 

  12. A. R. Bhattacharyya, P. Ptschke, L. Häußler, and D. Fischer, Macromol. Chem. Phys., 206, 2084 (2005).

    Article  CAS  Google Scholar 

  13. K. H. Kim and W. H. Jo, Macromol. Res., 16, 749 (2008).

    CAS  Google Scholar 

  14. P. V. Kodgire, Chem. Phys. Lett., 432, 480 (2006).

    Article  CAS  Google Scholar 

  15. I. Park, M. Park, J. Kim, H. Lee, and M. S. Lee, Macromol. Res., 15, 498 (2007).

    CAS  Google Scholar 

  16. M. Wang, K. P. Pramoda, and S. H. Goh, Polymer, 46, 11510 (2005).

    Article  CAS  Google Scholar 

  17. W. K. Park, J. H. Kim, S. S. Lee, J. Kim, G. W. Lee, and M. Park, Macromol. Res., 13, 206 (2005).

    CAS  Google Scholar 

  18. J. Li, Z. Fang, L. Tong, A. Gu, and F. Liu, J. Polym. Sci. Polym. Phys., 44, 1499 (2006).

    Article  CAS  Google Scholar 

  19. H. D. Bao, Z. X. Guo, and J. Yu, Polymer, 49, 3826 (2008).

    Article  CAS  Google Scholar 

  20. H. Ha, K. Ha, and S. C. Kim, Macromol. Res., 18, 512 (2010).

    Article  Google Scholar 

  21. Z. Tuzar, P. Kratochvil, and M. Bohdanecký, J. Polym. Sci. Polym. Sym., 16, 633 (1967).

    Article  CAS  Google Scholar 

  22. C. C. Teran, E. M. Macchi, and R. V. Figini, J. Appl. Polym. Sci., 32, 3847 (1986).

    Article  Google Scholar 

  23. B. Lánská, M. Bohdanecký, J. Šebenda, and Z. Tuzer, Eur. Polym. J., 14, 807 (1978).

    Article  Google Scholar 

  24. T. Liu, I. Y. Phang, L. Shen, S. Y. Chow, and W. D. Zhang, Macromolecules, 37, 7214 (2004).

    Article  CAS  Google Scholar 

  25. E. Logakis, C. Pandis, V. Peoglos, P. Pissis, C. Stergiou, J. Pionteck, P. Ptschke, M. Mièušik, and M. Omastova, J. Polym. Sci. Polym. Phys., 47, 764 (2009).

    Article  CAS  Google Scholar 

  26. I. Y. Phang, J. Ma, L. Shen, T. Liu, and W. D. Zhang, Polym. Int., 55, 71 (2006).

    Article  CAS  Google Scholar 

  27. A. C. Brosse, S. T. Girault, P. M. Piccione, and L. Leibler, Polymer, 49, 4680 (2008).

    Article  CAS  Google Scholar 

  28. M. I. Kohan, Nylon Plastic Handbook, Hanser Gardner Publications, New York, 1995.

    Google Scholar 

  29. J. Li, Z. Fang, Y. Zhu, L. Tong, A. Gu, and F. Liu, J. Appl. Polym. Sci., 105, 3531 (2007).

    Article  CAS  Google Scholar 

  30. S. Dasgupta, W. B. Hammond, and W. A. Goddard III, J. Am. Chem. Soc., 118, 12291 (1996).

    Article  CAS  Google Scholar 

  31. T. D. Fornes and D. R. Paul, Polymer, 44, 3945 (2003).

    Article  CAS  Google Scholar 

  32. H. Zeng, C. Gao, Y. Wnag, P. C. P. Watts, H. Kong, X. Cui, and D. Yan, Polymer, 47, 113 (2006).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Sung Chul Kim.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ha, H., Kim, S.C. & Ha, K. Morphology and properties of polyamide/multi-walled carbon nanotube composites. Macromol. Res. 18, 660–667 (2010). https://doi.org/10.1007/s13233-010-0702-y

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13233-010-0702-y

Keywords

Navigation