Abstract
This work described the structural, morphological, temperature-dependent relative permittivity, and magnetic behavior of nickel ferrite (NiFe2O4) nanoparticles prepared via a facile co-precipitation method. A computational analysis, density functional theory (DFT) calculation was carried out to understand the band structure and density of the state of NiFe2O4. The crystallinity and phase purity was analyzed by powder X-ray diffraction, which confirms the polycrystalline nature of the cubic spinel structure of NiFe2O4 belonging to the Fd3m space group. The calculated crystallite size is about 22 nm. Field emission scanning electron micrograph confirms the agglomerated flake-like grains. All the phonon modes (A1g, Eg and T2g) confirm the inverse spinel cubic structure of NiFe2O4. The dielectric study shows that the relative permittivity is varied between 1.2 × 102 and 1.6 × 103 as a function of different temperature. The obtained semicircle arc from the Cole–Cole plot confirms the grain and grain boundaries contribution in the conduction process. The exploration of the magnetic hysteresis loop measured in the temperature between 5 and 300 K over the field strength of ± 2 T, revealed a ferromagnetic behavior. Temperature-dependent magnetization and coercivity were studied using modified Bloch’s law and Kneller’s law, respectively. The increasing magnetic parameters at low temperature may be due to increasing the surface-spin moment in the finite-size nanoparticles.
Similar content being viewed by others
References
Ahlawat A, Sathe VG (2011) Raman study of NiFe2O4 nanoparticles, bulk and films: effect of laser power. J Raman Spectrosc 42:1087–1094. https://doi.org/10.1002/jrs.2791
Ahmad M, Tamoor M, Mustafa GM, Ishaq S, Naseem S, Murtaza G et al (2020) Polymer based nickel ferrite as dielectric composite for energy storage applications. Synth Met 268:1–9. https://doi.org/10.1016/j.synthmet.2020.116507
Arumugam S, Sivaprakash P, Dixit A, Chaurasiya R, Govindaraj L (2019) Complex magnetic structure and magneto capacitance response in a non-oxide NiF2 system. Sci Rep 2019:1–8. https://doi.org/10.1038/s41598-019-39083-8
Askari MB, Salarizadeh P (2020) Binary nickel ferrite oxide (NiFe2O4) nanoparticles coated on reduced graphene oxide as stable and high-performance asymmetric supercapacitor electrode material. Int J Hydrogen Energy 45:27482–27491. https://doi.org/10.1016/j.ijhydene.2020.07.063
Bammannavar BK, Naik LR (2009) Electrical properties and magnetoelectric effect in (x) Ni0.5Zn0.5Fe2O4 + (1−x) BPZT composites. Smart Mater Struct 18:085013
Bao N, Shen L, Wang Y, Padhan P, Gupta A (2007) A facile thermolysis route to monodisperse ferrite nanocrystals. J Am Chem Soc 2007:12374–12375
Bloch F (1931) Spin waves in quantum ferromagnets. Z Phys 61:206–213. https://doi.org/10.1007/BF01012911
Boda N et al (2019) Effect of rare earth elements on low temperature magnetic properties of Ni and Co-ferrite nanoparticles. J Magn Magn Mater 473:228–235. https://doi.org/10.1016/j.jmmm.2018.10.023
Chakradhary VK, Ansari A, Akhtar MJ (2019) Design, synthesis, and testing of high coercivity cobalt doped nickel ferrite nanoparticles for magnetic applications. J Magn Magn Mater 469:674–680. https://doi.org/10.1016/j.jmmm.2018.09.021
Creanga D, Calugaru G (2005) Physical investigations of a ferrofluid based on hydrocarbons. J Magn Magn 289:81–83. https://doi.org/10.1016/j.jmmm.2004.11.023
Egizbek K, Kozlovskiy AL, Ludzik K, Zdorovets MV, Korolkov IV, Marciniak B et al (2020) Stability and cytotoxicity study of NiFe2O4 nanocomposites synthesized by co-precipitation and subsequent thermal annealing. Ceram Int 46:16548–16555. https://doi.org/10.1016/j.ceramint.2020.03.222
El Kiadi I, Lassri H, Benkirane K, Bensassi B (2007) Magnons in ultrahigh vacuum deposited Fe/Ag multilayers. Mater Sci Eng B 137:170–174. https://doi.org/10.1016/j.mseb.2006.11.021
Elain M, Dhahri R, Hnainia N, Benchaabane A (2020) Dielectric spectroscopy study of the Ni0.2Zn0.8Fe2O4 spinel ferrite as a function of frequency and temperature. Mater Sci Eng B 262:114683–114690. https://doi.org/10.21203/rs.3.rs-19698/v1
Fan B, Liu F, Yang G, Li H, Zhang G, Jiang S, Wang Q (2018) Dielectric materials for high-temperature capacitors. IET Nanodielectr 1:32–40. https://doi.org/10.1049/iet-nde.2018.0002
Hajlaoui ME, Dhahri R, Hnainia N, Benchaabane A, Dhahria E, Khirounie K (2019) Conductivity and giant permittivity study of Zn0.5Ni0.5Fe2O4 spinel ferrite as a function of frequency and temperature. RSC Adv 9:32395–32402. https://doi.org/10.1039/C9RA06589J
Heiba ZK, Mohamed MB, Ahmed MA, Moussa MAA, Hamdeh HH (2014) Cation distribution and dielectric properties of nanocrystalline gallium substituted nickel ferrite. J Alloys Compd 586:773–781. https://doi.org/10.1016/j.jallcom.2013.10.137
Hosni N, Zehani K, Brazuna RP, Moscovici J, Bessais L, Maghraoui-Meherzi H (2018) Synthesis of (2D) MNPs nanosheets of nickel ferrite using a low-cost co-precipitation process. Mater Sci Eng B 232–235:48–54. https://doi.org/10.1016/j.mseb.2018.10.012
Hossain MD, Khan MNI, Nahar A, Ali MA, Matin MA, Hoque SM et al (2020) Tailoring the properties of Ni-Zn-Co ferrites by Gd3+ substitution. J Magn Magn Mater 497:165978–216000. https://doi.org/10.1016/j.jmmm.2019.165978
Jacob J, Khadar MA (2010) Investigation of mixed spinel structure of nanostructured nickel ferrite. J Appl Phys 107:114310–114320. https://doi.org/10.1063/1.3429202
Jadhav SS, Shirsath SE, Toksha BG, Patange SM, Shengule DR, Jadhav KM (2010) Structural and electric properties of zinc substituted NiFe2O4 nanoparticles prepared by co-precipitation method. Phys B Condens Matter 405:2610–2614. https://doi.org/10.1016/j.physb.2010.03.008
Joshi S, Kumar M, Chhoker S, Srivastava G, Jewariya M, Singh VN (2014) Structural, magnetic, dielectric and optical properties of nickel ferrite nanoparticles synthesized by co-precipitation method. J Mol Struct 1076:55–62. https://doi.org/10.1016/j.molstruc.2014.07.048
Karimi AA, Sadatlu MAA, Saberi B, Shariatmadar H, Ashjaee M (2015) Experimental investigation on thermal conductivity of water based nickel ferrite nanofluids. Adv Powder Tech 26:1529–1536. https://doi.org/10.1016/j.apt.2015.08.015
Kefeni KK, Mamba BB (2020) Photocatalytic application of spinel ferrite nanoparticle and nanocomposites in wastewater treatment: review. SM&T Sustain Mater Techno 23:140–158
Kefeni KK, Msagati TAM, Mamba BB (2017) Ferrite nanoparticles: Synthesis, characterisation and applications in electronic device. Mater Sci Eng B 215:37–55
Khalid A, Kumail-Abbas S, Mustafaa GM, Atiq S, Hussaina SS, Anwar MS, Naseem S (2019) Analysis of dielectric dispersion and magnetoelectric coupling in BiFeO3 and NiFe2O4 nanocomposite. Ceram Int 45:24453–24460. https://doi.org/10.1016/j.ceramint.2019.08.170
Kneller EF, Luborsky FE (1963) Particle size dependence of coercivity and remanence of single domain particles. J Appl Phys 1963:656. https://doi.org/10.1063/1.1729324
Maaz K, Mumtaz A, Hasanain SK, Bertino MF (2010) Temperature dependent coercivity and magnetization of nickel ferrite nanoparticles. J Magn Magn Mater 322:2199–2202. https://doi.org/10.1016/j.jmmm.2010.02.010
Mahmoodi NM (2013) Magnetic ferrite nanoparticle–alginate composite: synthesis, characterization and binary system dye removal. J Taiwan Inst Chem Eng 44:322–330. https://doi.org/10.1016/j.jtice.2012.11.014
Manohar A, Vijayakanth V, Hong R (2020) Solvothermal reflux synthesis of NiFe2O4 nanocrystals dielectric and magnetic hyperthermia properties. J Mater Sci Mater Electron 31:799–806. https://doi.org/10.1007/s10854-019-02588-z
Morup S (1994) Super-paramagnetism and Spin Glass Ordering in Magnetic Nanocomposites. Euro Phys Lett 28:671–676. https://doi.org/10.1209/0295-5075/28/9/010
Nathani H, Misra RDK (2004) Surface effects on the magnetic behavior of nanocrystalline nickel ferrites and nickel ferrite-polymer nanocomposites. Mater Sci Engg B 113:228–235. https://doi.org/10.1016/j.mseb.2004.08.010
Nongjai R, Khan S, Asokan K, Ahmed H, Khan I (2012) Magnetic and electrical properties of in doped cobalt ferrite nanoparticles. J Appl Phys 2012:112. https://doi.org/10.1063/1.4759436
Patange SM, Shirsath SE, Jangam GS, Lohar KS, Jadhav SS, Jadhav KM (2011) Rietveld structure refinement, cation distribution and magnetic properties of Al3+ substituted NiFe2O4 nanoparticles. J Appl Phys 109:053909–053919. https://doi.org/10.1063/1.3559266
Perron H, Mellier T, Domain C, Roques J, Simoni E, Drot R, Catalette H (2019) Structural investigation and electronic properties of the nickel ferrite NiFe2O4: a periodic density functional theory approach. J Phys Condens Matter 19:346219
Pottker WE, Ono R, Cobos MA, Hernando A, Araujo JFDF, Bruno ACO et al (2018) Influence of order-disorder effects on the magnetic and optical properties of NiFe2O4 nanoparticles. Ceram Int 44:17290–17297. https://doi.org/10.1016/j.ceramint.2018.06.190
Ramakrishna A, Murali N, Margarette SJ, Mammo TW, Joythi NK, Sailaja B, Sailaja-Kumari CC, Samatha K, Veeraiah V (2018) Studies on structural, magnetic, and DC electrical resistivity properties of Co0.5M0.37Cu0.13Fe2O4 (M = Ni, Zn and Mg) ferrite nanoparticle systems. Adv Powder Tech 29:2601–2607. https://doi.org/10.1016/j.apt.2018.07.005
Shirsath SE, Wang D, Jadhav SS, Mane ML, Li S (2018) Ferrites obtained by sol–gel method. Handb Sol-Gel Sci Technol. https://doi.org/10.1007/978-3-319-19454-7_125-3
Sivaprakash P, Ananth AN, Nagarajan V, Jose SP, Arumugam S (2017) Remarkable enhancement of La1-xSmxCrO3 nanoperovskite properties: an influence of its doping concentrations. Mater Res Bull 95:17–22. https://doi.org/10.1016/j.materresbull.2017.07.017
Sivaprakash P, Divya S, Parameshwari R, Saravanan C, Sagadevan S, Arumugam S (2020a) Influence of Zn2+ doping towards the structural, magnetic, and dielectric properties of NiFe2O4 composite. J Mater Sci Mater Electron 31:16369–16378. https://doi.org/10.1007/s10854-020-04187-9
Sivaprakash P, Ananth AN, Nagarajan V, Parameshwari R, Arumugam S, Jose SP, Muthu SE (2020b) Role of Sm3+ dopant in the formation of La(1–x)SmxCrO3 solid state nano perovskites—correlation of its augmented physical properties. Mater Chem Phys 248:122922. https://doi.org/10.1016/j.matchemphys.2020.122922
Topkaya R, Baykal A, Demir A (2013) Yafet-Kittel-type magnetic order in Zn-substituted cobalt ferrite nanoparticles with uniaxial anisotropy. J Nanopart Res 15:1359–1377. https://doi.org/10.1007/s11051-012
Acknowledgements
Author PS would like to thank UGC-BSRRFSMS-SRF for the meritorious fellowship. The author SA acknowledges the funding agencies of DST (SERB, MES, FIST, ASEAN and PURSE), BRNS, RUSA, CEFIPRA and UGC-DAE -CSR (Indore, Kolkata) for their financial support. This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIT) (2019R1A6C1010046). This study was funded by Taif University Researchers Supporting Project number (TURSP-2020/157), Taif University, Taif, Saudi Arabia.
Author information
Authors and Affiliations
Contributions
SD: Conceptualization, Methodology, Writing- Original draft preparation. PS: Conceptualization, Methodology, Investigation, Writing- Original draft preparation. SR: Investigation, Writing-Reviewing and Editing. SEM: Writing-Reviewing and Editing. EME: Research Support. SA: Writing-Reviewing and Editing. THO: Supervision, Project administration.
Corresponding authors
Ethics declarations
Conflict of interests
The authors declare that they have no competing interests.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Divya, S., Sivaprakash, P., Raja, S. et al. Temperature-dependent dielectric and magnetic properties of NiFe2O4 nanoparticles. Appl Nanosci 13, 1327–1336 (2023). https://doi.org/10.1007/s13204-021-02026-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13204-021-02026-9