Abstract
Novel nickel diselenide (NiSe2) nanoarrays supported on Ni foams are successfully synthesized by an in situ hydrothermal process. Structural characterizations show that the as-obtained NiSe2 nanoarrays belong to the cubic phase and present the white beech mushroom-like appearance, i.e., the stem diameter about 50–70 nm, the length about 500 nm, and the diameter of the umbrella cover about 50 nm. Controlled experiment results show that the typical mushroom-like NiSe2 nanoarrays can deliver a high specific capacity, low resistance and better cycling stability due to the intrinsic physical properties, and special structural features. More importantly, mushroom-like NiSe2 nanoarrays are further assembled into flexible hybrid supercapacitors with commercial activated carbon as the counter electrodes. This hybrid energy-storage device has 33 Wh kg−1 energy density and 90.3% capacity retention. Meanwhile, it also shows a remarkable mechanical flexibility and high commercial value. Therefore, this work not only proves that the NiSe2 nanoarrays are competitive supercapacitor electrode materials, but also provides a new candidate for flexible, smart, and portable electronic devices.
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References
An W, Liu L, Gao Y, Liu Y, Liu J (2016) Ni0.9Co1.92Se4 nanostructures: binder-free electrode of coral-like bimetallic selenide for supercapacitors. RSC Adv 6(79):75251–75257
Bao Q, Wu J, Fan L, Ge J, Dong J, Jia J, Zeng J, Lin J (2017) Electrodeposited NiSe2 on carbon fiber cloth as a flexible electrode for high-performance supercapacitors. J Energy Chem 26(6):1252–1259
Burke A (2000) Ultracapacitors: why, how, and where is the technology. J Power Sources 91:37–50
Cai Q, Li Y, Wang L, Li Q, Xu J, Gao B, Zhang X, Huo K, Chu PK (2017) Freestanding hollow double-shell Se@CNx nanobelts as large-capacity and high-rate cathodes for Li–Se batteries. Nano Energy 32:1–9
Chen H, Jiang J, Zhang L, Xia D, Zhao Y, Guo D, Qi T, Wan H (2014) In situ growth of NiCo2S4 nanotube arrays on Ni foam for supercapacitors: Maximizing utilization efficiency at high mass loading to achieve ultrahigh areal pseudocapacitance. J Power Sources 254:249–257
Conway BE, Birss V, Wojtowicz J (1997) The role and utilization of pseudocapacitance for energy storage by supercapacitors. J Power Sources 66(1–2):1–14
Deka BK, Hazarika A, Kim J, Kim N, Jeong HE, Park Y-B, Park HW (2019) Bimetallic copper cobalt selenide nanowire-anchored woven carbon fiber-based structural supercapacitors. Chem Eng J 355:551–559
Dimesso L, Forster C, Jaegermann W, Khanderi JP, Tempel H, Popp A, Engstler J, Schneider JJ, Sarapulova A, Mikhailova D, Schmitt LA, Oswald S, Ehrenberg H (2012) Developments in nanostructured LiMPO4 (M = Fe Co, Ni, Mn) composites based on three dimensional carbon architecture. Chem Soc Rev 41(15):5068–5080
Du W, Wang Z, Zhu Z, Hu S, Zhu X, Shi Y, Pang H, Qian X (2014) Facile synthesis and superior electrochemical performances of CoNi2S4/graphene nanocomposite suitable for supercapacitor electrodes. J Mater Chem A 2(25):9613–9619
Du L, Du W, Ren H, Wang N, Yao Z, Shi X, Zhang B, Zai J, Qian X (2017) Honeycomb-like metallic nickel selenide nanosheet arrays as binder-free electrodes for high-performance hybrid asymmetric supercapacitors. J Mater Chem A 5(43):22527–22535
Du L, Du W, Zhao Y, Wang N, Yao Z, Wei S, Shi Y, Zhang B (2019) Ternary nickel-cobalt selenide nanosheet arrays with enhanced electrochemical performance for hybrid supercapacitors. J Alloy Compd 778:848–857
Duraisamy N, Numan A, Fatin SO, Ramesh K, Ramesh S (2016) Facile sonochemical synthesis of nanostructured NiO with different particle sizes and its electrochemical properties for supercapacitor application. J Colloid Interface Sci 471:136–144
Gao Y, Chen S, Cao D, Wang G, Yin J (2010) Electrochemical capacitance of Co3O4 nanowire arrays supported on nickel foam. J Power Sources 195(6):1757–1760
Geng P, Zheng S, Tang H, Zhu R, Zhang L, Cao S, Xue H, Pang H (2018) Transition metal sulfides based on graphene for electrochemical energy storage. Adv Energy Mater 8(15):1703259
Gong C, Huang M, Zhou P, Sun Z, Fan L, Lin J, Wu J (2016) Mesoporous Co0.85Se nanosheets supported on Ni foam as a positive electrode material for asymmetric supercapacitor. Appl Surf Sci 362:469–476
Gopalakrishnan A, Kong CY, Badhulika S (2019a) Scalable, large-area synthesis of heteroatom-doped few-layer graphene-like microporous carbon nanosheets from biomass for high-capacitance supercapacitors. New J Chem 43(3):1186–1194
Gopalakrishnan A, Yang D, Ince JC, Truong YB, Yu A, Badhulika S (2019b) Facile one-pot synthesis of hollow NiCoP nanospheres via thermal decomposition technique and its free-standing carbon composite for supercapacitor application. J Energy Storage 25:100893
Guo D, Lai L, Cao A, Liu H, Dou S, Ma J (2015) Nanoarrays: design, preparation and supercapacitor applications. RSC Adv 5(69):55856–55869
Guo K, Cui S, Hou H, Chen W, Mi L (2016) Hierarchical ternary Ni–Co–Se nanowires for high-performance supercapacitor device design. Dalton T 45(48):19458–19465
Hong W, Wang J, Gong P, Sun J, Niu L, Yang Z, Wang Z, Yang S (2014) Rational construction of three dimensional hybrid Co3O4 @NiMoO4 nanosheets array for energy storage application. J Power Sources 270:516–525
Hu C-C, Chang K-H, Lin M-C, Wu Y-T (2006) Design and tailoring of the nanotubular arrayed architecture of hydrous RuO2 for next generation supercapacitors. Nano Lett 6(12):2690–2695
Hu W, Chen R, Xie W, Zou L, Qin N, Bao D (2014) CoNi2S4 nanosheet arrays supported on nickel foams with ultrahigh capacitance for aqueous asymmetric supercapacitor applications. ACS Appl Mater Interfaces 6(21):19318–19326
Huang K, Zhang J, Fan Y (2015) Preparation of layered MoSe2 nanosheets on Ni-foam substrate with enhanced supercapacitor performance. Mater Lett 152:244–247
Huang S, Zhang W, Cui S, Chen W, Mi L (2017) Sequential partial ion exchange synthesis of composite Ni3S2/Co9S8/NiSe nanoarrays with a lavender-like hierarchical morphology. Inorg Chem Front 4(4):727–735
Jiang J, Li Y, Liu J, Huang X, Yuan C, Lou XW (2012) Recent advances in metal oxide-based electrode architecture design for electrochemical energy storage. Adv Mater 24(38):5166–5180
Lee Y-H, Yun Y-H, Hong Vinh Quy V, Kang S-H, Kim H, Vijayakumar E, Ahn K-S (2019) Preparation of nickel selenide by pulsed-voltage electrodeposition and its application as a highly-efficient electrocatalyst at counter electrodes of quantum-dot sensitized solar cells. Electrochim Acta 296:364–371
Lu X, Yu M, Wang G, Tong Y, Li Y (2014) Flexible solid-state supercapacitors: design, fabrication and applications. Energy Environ Sci 7(7):2160–2181
Mai L, Tian X, Xu X, Chang L, Xu L (2014) Nanowire electrodes for electrochemical energy storage devices. Chem Rev 114(23):11828–11862
Manikandan M, Subramani K, Sathish M, Dhanuskodi S (2018) NiTe nanorods as electrode material for high performance supercapacitor applications. ChemistrySelect 3(31):9034–9040
Mei L, Yang T, Xu C, Zhang M, Chen L, Li Q, Wang T (2014) Hierarchical mushroom-like CoNi2S4 arrays as a novel electrode material for supercapacitors. Nano Energy 3:36–45
Naoi K, Naoi W, Aoyagi S, Miyamoto J-i, Kamino T (2013) New generation “nanohybrid supercapacitor". Acc Chem Res 46(5):1075–1083
Nyholm L, Nystrom G, Mihranyan A, Stromme M (2011) Toward flexible polymer and paper-based energy storage devices. Adv Mater 23(33):3751–3769
Pan GX, Xia X, Cao F, Tang PS, Chen HF (2012) Porous Co(OH)2/Ni composite nanoflake array for high performance supercapacitors. Electrochim Acta 63:335–340
Peng H, Ma G, Sun K, Zhang Z, Li J, Zhou X, Lei Z (2015) A novel aqueous asymmetric supercapacitor based on petal-like cobalt selenide nanosheets and nitrogen-doped porous carbon networks electrodes. J Power Sources 297:351–358
Peng H, Zhou J, Sun K, Ma G, Zhang Z, Feng E, Lei Z (2017) High-performance asymmetric supercapacitor designed with a novel NiSe@MoSe2 nanosheet array and nitrogen-doped carbon nanosheet. ACS Sustain Chem Eng 5(7):5951–5963
Pu J, Wang Z, Wu K, Yu N, Sheng E (2014) Co9S8 nanotube arrays supported on nickel foam for high-performance supercapacitors. Phys Chem Chem Phys 16(2):785–791
Song D, Wang H, Wang X, Yu B, Chen Y (2017) NiSe2 nanoparticles embedded in carbon nanowires as highly efficient and stable electrocatalyst for hydrogen evolution reaction. Electrochim Acta 254:230–237
Tan C, Cao X, Wu X, He Q, Yang J, Zhang X, Chen J, Zhao W, Han S, Nam G-H, Sindoro M, Zhang H (2017) Recent advances in ultrathin two-dimensional nanomaterials. Chem Rev 117(9):6225–6331
Tang C, Pu Z, Liu Q, Asiri AM, Sun X (2015a) NiS2 nanosheets array grown on carbon cloth as an efficient 3D hydrogen evolution cathode. Electrochim Acta 153:508–514
Tang C, Pu Z, Liu Q, Asiri AM, Sun X, Luo Y, He Y (2015b) In situ growth of NiSe nanowire film on nickel foam as an electrode for high-performance supercapacitors. ChemElectroChem 2(12):1903–1907
Tang H, Yuan Y, Meng L, Wang W, Lu J, Zeng Y, Huang T, Gao C (2018) Low-resistance porous nanocellular MnSe electrodes for high-performance all-solid-state battery-supercapacitor hybrid devices. Adv Mater Technol 3(7):1800074
Veeralingam S, Sahatiya P, Kadu A, Mattela V, Badhulika S (2019) Direct, one-step growth of NiSe2 on cellulose paper: a low-cost, flexible, and wearable with smartphone enabled multifunctional sensing platform for customized noninvasive personal healthcare monitoring. ACS Appl Electron Mater 1(4):558–568
Vishnu N, Sahatiya P, Kong C, Badhulika S (2019) Large area, one step synthesis of NiSe2 films on cellulose paper for glucose monitoring in bio-mimicking samples for clinical diagnostics. Nanotechnology 30(35):355502
Wang Y, Xia Y (2013) Recent progress in supercapacitors: from materials design to system construction. Adv Mater 25(37):5336–5342
Wang H, Casalongue HS, Liang Y, Dai H (2010) Ni(OH)2 nanoplates grown on graphene as advanced electrochemical pseudocapacitor materials. J Am Chem Soc 132(21):7472–7477
Wang X, Lu X, Liu B, Chen D, Tong Y, Shen G (2014) Flexible energy-storage devices: design consideration and recent progress. Adv Mater 26(28):4763–4782
Wang F, Li Y, Shifa TA, Liu K, Wang F, Wang Z, Xu P, Wang Q, He J (2016) Selenium-enriched nickel selenide nanosheets as a robust electrocatalyst for hydrogen generation. Angew Chem Int Ed 55(24):6919–6924
Wang S, Li W, Xin L, Wu M, Long Y, Huang H, Lou X (2017) Facile synthesis of truncated cube-like NiSe2 single crystals for high-performance asymmetric supercapacitors. Chem Eng J 330:1334–1341
Wei W, Mi L, Gao Y, Zheng Z, Chen W, Guan X (2014) Partial ion-exchange of nickel-sulfide-derived electrodes for high performance supercapacitors. Chem Mater 26(11):3418–3426
Xia C, Jiang Q, Zhao C, Beaujuge PM, Alshareef HN (2016) Asymmetric supercapacitors with metal-like ternary selenides and porous graphene electrodes. Nano Energy 24:78–86
Xu Y, Du W, Du L, Zhu W, Guo W, Chang J, Zhang B, Deng D (2017) Monocrystalline NiS nanowire arrays supported by Ni foam as binder-free electrodes with outstanding performances. RSC Adv 7(36):22553–22557
Yang S, Liu Y, Hao Y, Yang X, Goddard WA, Zhang X, Cao B (2018) Oxygen-vacancy abundant ultrafine Co3O4/graphene composites for high-rate supercapacitor electrodes. Adv Sci 5(4):1700659
Yang X, Wang S, Yu DYW, Rogach AL (2019) Direct conversion of metal-organic frameworks into selenium/selenide/carbon composites with high sodium storage capacity. Nano Energy 58:392–398
Ye B, Huang M, Bao Q, Jiang S, Ge J, Zhao H, Fan L, Lin J, Wu J (2018) Construction of NiTe/NiSe composites on Ni foam for high-performance asymmetric supercapacitor. ChemElectroChem 5(3):507–514
Yu X, Sun W, Chu Y (2014) One-pot solvothermal synthesis and properties of 1D NiSe and NiSe–Ni3S2 alloyed compound nanorod arrays. New J Chem 38(1):70–76
Yu N, Zhu M-Q, Chen D (2015) Flexible all-solid-state asymmetric supercapacitors with three-dimensional CoSe2/carbon cloth electrodes. J Mater Chem A 3:7910–7918
Yu S, Zhang Y, Lou G, Wu Y, Zhu X, Chen H, Shen Z, Fu S, Bao B, Wu L (2018) Synthesis of NiMn-LDH Nanosheet@Ni3S2 nanorod hybrid structures for supercapacitor electrode materials with ultrahigh specific capacitance. Sci Rep 8(1):5246
Zhang LL, Zhao XS (2009) Carbon-based materials as supercapacitor electrodes. Chem Soc Rev 38(9):2520–2531
Zhang Z, Du W, Ren X, Shen Z, Fan X, Wei S, Wei C, Cao Z, Zhang B (2019) Ni(OH)2-Co2(OH)3Cl bilayer nanocomposites supported by Ni foams for binder-free electrodes of high-performance hybrid supercapacitors. Appl Surf Sci 469:624–633
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All the authors sincerely acknowledge the financial support from the China Scholarship Council—Henan Province Local Cooperation Project (201708410285), Plan for Scientific Innovation Talent of Henan Province (174200510017), Basic Research Plan of Key Scientific Research Projects in the Colleges and Universities of Henan Province (20ZX007), and Special Projects of New Energy Vehicle Development of Anyang City (2017-480-15).
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Gu, Y., Du, W., Darrat, Y. et al. In situ growth of novel nickel diselenide nanoarrays with high specific capacity as the electrode material of flexible hybrid supercapacitors. Appl Nanosci 10, 1591–1601 (2020). https://doi.org/10.1007/s13204-019-01234-8
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DOI: https://doi.org/10.1007/s13204-019-01234-8