Skip to main content
Log in

Tribological study on rapeseed oil with nano-additives in close contact sliding situation

  • Original Article
  • Published:
Applied Nanoscience Aims and scope Submit manuscript

Abstract

The present work deals with the tribological evaluation of three types of nano-additives, i.e., copper oxide (CuO; ≈ 151.2 nm), cerium oxide (CeO2; ≈ 80 nm) and polytetrafluoroethylene (PTFE; ≈ 90.4 nm) with rapeseed oil under steel–steel sliding contacts. The nano-additives concentrations in the base oil were 0.1, 0.25 and 0.5% w/v for the lubricant formulation. Further, the rapeseed oil was also epoxidized by a chemical method and the tribological behavior was compared with the base oil (unmodified oil) at similar nano-additives concentrations. The ASTM standards were followed for the study of wear preventive and extreme-pressure analysis of nanolubricants, and it was carried out using four-ball tester. In the antiwear test, CeO2 and PTFE nano-additives have shown the significant reduction in the wear scar diameter at the concentration of 0.1% w/v. In the extreme-pressure test, 0.5% w/v concentration was optimum for oxide nanoparticles; however, PTFE nanoparticles did not show positive effect with both the base oils. Different characterization techniques were employed to confirm the oil modification and for the study of the worn surfaces.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13

Similar content being viewed by others

References

  • Abdullah BM, Salimon J (2010) Epoxidation of vegetable oils and fatty acids: catalysts, method and advantages. J Appl Sci 10(15):1545–1553

    Article  Google Scholar 

  • Adhvaryu A, Erhan SZ (2002) Epoxidized soybean oil as a potential source of high temperature lubricants. Ind Crops Prod 15(3):247–254

    Article  Google Scholar 

  • Alves SM, Barros BS, Trajano MF, Ribeiro KSB, Moura E (2013) Tribological behavior of vegetable oil-based lubricants with nanoparticles of oxides in boundary lubrication conditions. Tribol Int 65:28–36

    Article  Google Scholar 

  • Arumuam S, Sriram G (2013) Preliminary study of nano- and microscale TiO2 additives on the tribological behavior of chemically modified rapeseed oil. Tribol Trans 56(5):797–805

    Article  Google Scholar 

  • ASTM D2783 (Reapproved 2009) Standard test method for measurement of extreme-pressure properties of lubricating fluids (Four-ball method). ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States

  • ASTM D4172 (Reapproved 2010) Standard test method for wear preventive characteristics of Lubricating fluid (four-ball method). ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States

  • Barry PR, Chiu PY, Perry SS, Sawyer WG, Sinnott SB, Phillpot SR (2015) Effect of temperature on the friction and wear of PTFE by atomic-level simulation. Tribol Lett 58(50):1–13

    Google Scholar 

  • Battez AH, González R, Viesca JL, Fernández JE, Fernández JMD, Machado A, Chou R, Riba J (2008) CuO, ZrO2 and ZnO nanoparticles as antiwear additive in oil lubricants. Wear 265:422–428

    Article  Google Scholar 

  • Biswas SK, Kalyani V (1992) Friction and wear of PTFE—a review. Wear 158:193–211

    Article  Google Scholar 

  • Campanella A, Rustoy E, Baldessari A, Baltanás MA (2010) Lubricants from chemically modified vegetable oils. Bioresour Technol 101(1):245–254

    Article  Google Scholar 

  • Dai W, Kheireddin B, Gao H, Liang H (2016) Role of nanoparticles in oil lubrication. Tribol Int 102:88–98

    Article  Google Scholar 

  • Dubey MK, Bijwe J, Ramakumar SSV (2013) PTFE based nano-lubricants. Wear 306:80–88

    Article  Google Scholar 

  • Fox NJ, Stachowiak GW (2007) Vegetable oil-based lubricants—a review of oxidation. Tribol Int 40(7):1035–1046

    Article  Google Scholar 

  • Gao Y, Chen G, Oli Y, Zhang Z, Xue Q (2002) Study on tribological properties of oleic acid-modified TiO2 nanoparticle in water. Wear 252(5–6):454–458

    Article  Google Scholar 

  • Ghaednia H, Jackson RL (2013) The effect of nanoparticles on the real area of contact, friction, and wear. J Tribol 135(4):041603

    Article  Google Scholar 

  • Ghaednia H, Jackson RL, Khodadadi JM (2015) Experimental analysis of stable CuO nanoparticle enhanced lubricants. J Exp Nanosci 10(1):1–18

    Article  Google Scholar 

  • Gupta RN, Harsha AP (2017a) Synthesis, characterization, and tribological studies of calcium–copper–titanate nanoparticles as a biolubricant additive. J Tribol 139(2):021801

    Article  Google Scholar 

  • Gupta RN, Harsha AP (2017b) Antiwear and extreme pressure performance of castor oil with nano-additives. Proc IMechE Part J. https://doi.org/10.1177/1350650117739159

    Google Scholar 

  • Harris KL, Pitenis AA, Sawyer WG, Krick BA, Blackman GS, Kasprzak DJ, Junk CP (2015) PTFE tribology and the role of mechanochemistry in the development of protective surface films. Macromolecules 48(11):3739–3745

    Article  Google Scholar 

  • Hu KH, Hu XG, Xu YF, Huang F, Liu JS (2010) The effect of morphology on the tribological properties of MoS2 in liquid paraffin. Tribol Lett 40:155–165

    Article  Google Scholar 

  • Hwang Y, Lee C, Choi Y, Cheong S, Kim D, Lee K, Lee J, Kim SH (2011) Effect of the size and morphology of particles dispersed in nano-oil on friction performance between rotating discs. J Mech Sci Technol 25(11):2853–2857

    Article  Google Scholar 

  • Ilyas SU, Pendyala R, Marneni N (2017) Stability of nanofluids (Chapter 1), engineering applications of nanotechnology: from energy to drug delivery. In: Topics in mining, metallurgy and materials engineering. Springer, Cham, pp 1–31. https://doi.org/10.1007/978-3-319-29761-3

  • Jang I, Burris DL, Dickrell PL, Barry PR, Santos C, Perry SS, Phillpot SR, Sinnott SB, Sawyer WG (2007) Sliding orientation effects on the tribological properties of polytetrafluoroethylene. J Appl Phys 102:123509

    Article  Google Scholar 

  • Jintang G, Hongxin D (1988) Molecule structure variations in friction of stainless steel/PTFE and its composite. J Appl Polym Sci 36(1):73–85

    Article  Google Scholar 

  • Kalyani JV, Rastogi RB, Kumar D (2017) The investigation of different particle size magnesium-doped zinc oxide (Zn0.92Mg0.08O) nanoparticles on the lubrication behavior of paraffin oil. Appl Nanosci 7:275–281

    Article  Google Scholar 

  • Laura P-P, Jaime T-T, Andrés G, Demófilo M, Jesús AG, David M, Eduardo P, Pablo C (2014) Antiwear and extreme pressure properties of nanofluids for industrial applications. Tribol Trans 57(6):1072–1076

    Article  Google Scholar 

  • Lee C-G, Hwang Y-J, Choi Y-M, Lee J-K, Choi C, Oh J-M (2009) Tribological study on the tribological characteristics of graphite nanolubricants. Int J Precis Eng Manuf 10(1):85–90

    Article  Google Scholar 

  • Lovell MR, Kabir MA, Menezes PL, Higgs CF III (2010) Influence of boric acid additive size on green lubricant performance. Philos Trans R Soc A 368:4851–4868

    Article  Google Scholar 

  • Mall S, Buckton G, Rawlins DA (1996) Dissolution behaviour of sulphonamides into sodium dodecyl sulfate micelles: a thermodynamic approach. J Pharm Sci 85(1):75–78

    Article  Google Scholar 

  • Marko M, Kyle J, Branson B, Terrell E (2015) Tribological improvements of dispersed nanodiamond additives in lubricating mineral oil. J Tribol 137:011802

    Article  Google Scholar 

  • Nagendramma P, Kaul S (2012) Development of ecofriendly/biodegradable lubricant: an overview. Renew Sustain Energy Rev 16(1):764–774

    Article  Google Scholar 

  • Padgurskas J, Rukuiza R, Prosyčevas I, Kreivaitis R (2013) Tribological properties of lubricant additives of Fe, Cu and Co nanoparticles. Tribol Int 60:224–232

    Article  Google Scholar 

  • Raina A, Anand A (2017) Tribological investigation of diamond nanoparticles for steel/steel contacts in boundary lubrication regime. Appl Nanosci 7:371–388

    Article  Google Scholar 

  • Salih N, Salimon J, Yousif E (2011) The physicochemical and tribological properties of oleic acid based trimester biolubricants. Ind Crops Prod 34:1089–1096

    Article  Google Scholar 

  • Sharma BK, Adhvaryu A, Liu Z, Erhan SZ (2006) Chemical modification of vegetable oils for lubricant applications. J Am Oil Chem Soc 83(2):129–136

    Article  Google Scholar 

  • Snežana S-F, Milovan J, Olga B (2012) Epoxidation of castor oil with peracetic acid formed in situ in the presence of an ion exchange resin. Chem Eng Process 62:106–113

    Article  Google Scholar 

  • Soomro RA, Sherazi STH, Memon N, Shah MR, Kalwar NH, Hallam KR, Shah A (2014) Synthesis of air stable copper nanoparticles and their use in catalysis. Adv Mater Lett 5(4):191–198

    Article  Google Scholar 

  • Sui T, Song B, Zhang F, Yang Q (2016) Effects of functional groups on the tribological properties of hairy silica nanoparticles as an additive to polyalphaolefin. RSC Adv 6:393–402

    Article  Google Scholar 

  • Wäsche R, Hartelt M, Hodoroaba V-D (2015) Analysis of nanoscale wear particles from lubricated steel-steel contacts. Tribol Lett 58(49):1–10

    Google Scholar 

  • Wei Y, Huaqing X (2012) A review on nanofluids: preparation, stability mechanism, and applications. J Nanomater 2012:1–17. https://doi.org/10.1155/2012/435873

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. P. Harsha.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gupta, R.N., Harsha, A.P. & Singh, S. Tribological study on rapeseed oil with nano-additives in close contact sliding situation. Appl Nanosci 8, 567–580 (2018). https://doi.org/10.1007/s13204-018-0670-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13204-018-0670-7

Keywords

Navigation