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Assessment of impact of environmental pollution on groundwater and surface water qualities in a heavily industrialized district of Kocaeli (Dilovası), Turkey

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Abstract

The impact of uncontrolled industrialization and urbanization on surface water and groundwater qualities was assessed in a heavily industrialized district of Kocaeli (Turkey) considering source, types and levels of contaminants. A sampling campaign was conducted on both water bodies in dry (September) and wet (May) sampling periods. Water samples were taken from 6 surface water stations and 24 wells distributed from upstream to downstream along Dil stream to determine the degree of deterioration in water quality from background conditions. Results showed that Dil stream was heavily polluted with regard to many parameters including Al, Fe, Mn, Pb, DO, COD, NH4, NO2 and PO4. While sewage discharges, leachates from closed wild landfill and quarries create sources of contamination for Dil stream at upstream, primarily metal industries (mainly iron and steel manufacturing) at downstream contribute markedly to the metal contamination. Contribution of highly polluted Dil stream to the groundwater contamination is also significant in the alluvium aquifer at both upstream and downstream of Dil stream. Microbial pollution indicating fecal contamination and high nutrient levels exist in the groundwater. In addition, relatively high AOX concentrations over background levels were detected in wells at the downstream part of Dil stream where industrial activities were densely distributed. Deep wells located near the Gulf of İzmit were also affected by seawater intrusion. Results suggest that Dil stream contaminated by industrial discharges, sewages, and leachates from old wild landfill negatively influences the groundwater quality in the alluvial aquifer.

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References

  • APHA (2012) Standard methods for the examination of water and wastewater, 22nd edn. American Water Work Association, Washington DC

  • Bingöl D, Ay U, Karayunlu Bozbas S, Uzgoren N (2013) Chemometric evaluation of the heavy metals distribution in waters from the Dilovası region in Kocaeli, Turkey. Mar Pollut Bull 68:134–139

    Article  Google Scholar 

  • Cetin B (2014) Soil concentrations and source apportionment of polybrominated diphenyl ethers (PBDEs) and trace elements around a heavily industrialized area in Kocaeli, Turkey. Environ Sci Pollut Res 21:8284–8293

    Article  Google Scholar 

  • Demiray AD, Yolcubal I, Akyol NH, Cobanoglu G (2012) Biomonitoring of airborne metals using the Lichen Xanthoria parietina in Kocaeli Province, Turkey. Ecol Ind 18:632–643

    Article  Google Scholar 

  • Doğruparmak SC, Ozbay B (2011) Investigating correlations and variations of air pollutant concentrations under conditions of rapid industrialization—Kocaeli (1987–2009). Clean Soil Air Water 39(7):597–604

    Article  Google Scholar 

  • EPA (2002) Environmental assessment of the final effluent guidelines for the iron and steel industry, vol 1, Washington DC, p 93

  • EPA 3015A (2007) Microwave assisted acid digestion of aqueous samples and extracts, Washington DC

  • EPA (2009) National primary drinking water regulations. EPA 816-F-09-0004, Washington DC, p 6

  • Ergenekon P, Özturk NK, Tavsan S (2009) Environmental air levels of volatile organic compounds by thermal desorption-gas chromatography in an industrial region. Fresenius Environ Bull 18(11):1999–2003

    Google Scholar 

  • Gron C (1993) Organic halogen group parameters as indicators of groundwater contamination. Groundw Mon Rem 13(3):148–158

    Article  Google Scholar 

  • Hamzaoglu O, Etiler N, Yavuz CI, Çağlayan C (2011) The causes of deaths in an industry-dense area: example of Dilovası (Kocaeli). Turk J Med Sci 41(3):369–375

    Google Scholar 

  • Hamzaoglu O, Yavuz M, Turker G, Savli H (2014) Heavy metal concentration in colostrum and meconium in two different districts of an industrial city: a preliminary report. Int Med J 21(1):77–82

    Google Scholar 

  • Kara M, Dumanoglu Y, Altiok H, Elbir T, Odabasi M, Bayram A (2015) Spatial variation of trace elements in seawater and sediment samples in a heavily industrialized region. Environ Earth Sci 73:405–421

    Article  Google Scholar 

  • Krishna AK, Mohan KR (2014) Risk assessment of heavy metals and their source distribution in waters of a contaminated industrial site. Environ Sci Pollut Res 21:3653–3669

    Article  Google Scholar 

  • Kuzu SL, Saral A, Demir S, Coltu H, Can M, Beyaz T (2013) Estimation of atmospheric PCB releases from industrial facilities in Turkey. Atmos Pollut Res 4:420–426

    Article  Google Scholar 

  • Naik PK, Dehury BN, Tiwari AN (2007) Groundwater pollution around an industrial area in the coastal stretch of Maharashtra State, India. Environ Monit Assess 132:207–233

    Article  Google Scholar 

  • Ozturk N, Ergenekon P, Ozdemir S, Bayır S (2015) Spatial distribution and temporal trends of VOCs in a highly industrialized town in Turkey. Bull Environ Contam Toxicol 94:653–660

    Article  Google Scholar 

  • Pekey B, Ozaslan U (2012) Spatial distribution of SO2, NO2, and O3 concentrations in an industrial city of Turkey using a passive sampling method. Clean Soil Air Water 41(5):423–428

    Article  Google Scholar 

  • Sponza D, Karaoğlu N (2002) Environmental geochemistry and pollution studies of Aliağa metal industry district. Environ Int 27(7):541–553

    Article  Google Scholar 

  • TBMM (2006) Investigation of the influences of industrial wastes in Dilovası districts of Gebze, Kocaeli on environmental and public health and determination of preventive actions to be taken (in Turkish). 10/254, 258

  • TSE 266 (2005) Regulation for concerning water intended for human consumption (in Turkish). Offi J 25730

  • Yaylalı-Abanuz G (2011) Heavy metal contamination of surface soil around Gebze industrial area, Turkey. Microchem J 99:82–92

    Article  Google Scholar 

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Acknowledgments

This study was funded by Kocaeli Water and Sewerage Department. We thank anonymous reviewers for their constructive comments.

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Correspondence to Irfan Yolcubal.

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Yolcubal, I., Gündüz, Ö.C. & Sönmez, F. Assessment of impact of environmental pollution on groundwater and surface water qualities in a heavily industrialized district of Kocaeli (Dilovası), Turkey. Environ Earth Sci 75, 170 (2016). https://doi.org/10.1007/s12665-015-4986-2

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  • DOI: https://doi.org/10.1007/s12665-015-4986-2

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