Skip to main content
Log in

Assessment of the potential occurrence of acid rock drainage through a geochemical stream sediment survey

  • Original Article
  • Published:
Environmental Earth Sciences Aims and scope Submit manuscript

Abstract

During large constructions of roads or structures, unexpected acid rock drainage (ARD) can be caused by local mineralization containing sulfides in the geology. The potential of ARD occurrence of a certain area sometimes must be assessed before initiation of any engineering earth works. However, it is difficult to assess the entire area through collecting rock samples and predicting the potential by laboratory tests, such as the acid–base accounting method. In this study, a new prediction protocol using a geochemical exploration survey technique of stream sediment is proposed. Sediment samples were collected at the case study area where a large development is expected in the future, and the contents of some major and heavy metal elements were compared according to the major geologies of the sampling points. The modified geoaccumulation indices (I geo) of Fe, Pb and As could indicate a possible zone of pyrophyllite mineralization, which may cause the occurrence of ARD at the study area. Using the enrichment index of the three elements relative to the median values of the area, a high potential zone of ARD could be designated, which was in agreement with the laboratory ARD prediction tests of the rock samples. In the other areas with different mineralization processes, other metallic elements can be selected as indicators of the ARD potential. Likewise, the potential of the occurrence of ARD at an area can be assessed by evaluating the geochemical distributions and drawing the indicator elements for ARD through a stream sediment survey.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  • Albanese S, De Vivo B, Lima A, Cicchella D (2007) Geochemical background and baseline values of toxic elements in stream sediments of Campania region (Italy). J Geochem Explor 93:21–34

    Article  Google Scholar 

  • AMIRA (2002) ARD test handbook. Project P387A prediction and kinetic control of acid mine drainage, Ian Wark Research Institute and Environmental Geochemistry International Pty Ltd

  • De Vivo B, Lima A, Catalano G, Chersicla A (1993) Detailed geochemical survey in the Peloritani Arc (northeastern Sicily, Italy): evidence of gold anomalies. J Geochem Explor 46:309–324

    Article  Google Scholar 

  • Förstner U, Müller G (1981) Concentrations of heavy metals and polycyclic aromatic hydrocarbons in river sediments: geochemical background, man’s influence and environmental impact. GeoJournal 5:417–432

    Article  Google Scholar 

  • Fox DL (1999) Prediction of acid rock drainage (ARD) from sulphidic slates using GIS analysis of mineralogical, geochemical, magnetic and geological parameters: a test case in southern Nova Scotia. Thesis for Doctor’s Degree, Dalhousie University, Halifax, Nova Scotia, Canada, p 282

  • Hammarstrom JM, Brady K, Cravotta CA (2005) Acid-rock drainage at Skytop, Centre County, Pennsylvania, 2004. USGS Open-File Report 2005-1148, p 45

  • Hesketh AH, Broadhurst JL, Harrison STL (2010) Mitigating the generation of acid mine drainage from copper sulfide tailings impoundments in perpetuity: a case study for an integrated management strategy. Miner Eng 23:225–229

    Article  Google Scholar 

  • KIGAM (1978) Geological map of Korea, Donrae and Weolnae sheets 1:50000. Korea Institute of Geoscience and Mineral Resources

  • Lawrence RW, Jaffe S, Broughton LM (1988) In-house development of the net acid production test method. Coastech Research Inc

  • Lee GH, Kim JG, Lee JS, Chon CM, Park SG, Kim TH, Ko KS, Kim TK (2005) Generation characteristics and prediction of acid rock drainage (ARD) of cut slopes. Econ Environ Geol 38:91–99 (in Korean with English abstract)

    Google Scholar 

  • Li Z, Ma Z, van der Kuijp TJ, Yuan Z, Huang J (2014) A review of soil heavy metal pollution from mines in China: pollution and health risk assessment. Sci Tot Environ 468–469:843–853

    Article  Google Scholar 

  • Lima A, De Vivo B, Cicchella D, Cortini M, Albanese S (2003) Multifractal IDW interpolation and fractal filtering method in environmental studies: an application on regional stream sediments of (Italy), Campania region. Appl Geochem 18:1853–1865

    Article  Google Scholar 

  • Loska K, Wiechula D, Korus D (2004) Metal contamination of farming soils affected by industry. Environ Int 30:159–165

    Article  Google Scholar 

  • Miller SD, Stewart WS, Rusdinar Y, Schumann RE, Ciccarelli JM, Li J, Smart RStC (2010) Methods for estimation of long-term non-carbonate neutralization of acid rock drainage. Sci Tot Environ 408:2129–2135

    Article  Google Scholar 

  • Naseem S, Sheikh SA, Qadeeruddin M, Shirin K (2002) Geochemical stream sediment survey in Winder Valley, Balochistan, Pakistan. J Geochem Explor 76:1–12

    Article  Google Scholar 

  • Ohta A, Imai N, Terashima S, Tachibana Y, Ikehara K, Nakajima T (2004) Geochemical mapping in Hokuriku, Japan: influence of surface geology, mineral occurrences and mass movement from terrestrial to marine environments. Appl Geochem 19:1453–1469

    Article  Google Scholar 

  • Ohta A, Imai N, Terashima S, Tachibana Y, Ikehara K, Katayama H, Noda A (2010) Factors controlling regional spatial distribution of 53 elements in coastal sea sediments in northern Japan: comparison of geochemical data derived from stream and marine sediments. Appl Geochem 25:357–376

    Article  Google Scholar 

  • Pokrovski GS, Kara S, Roux J (2002) Stability and solubility of arsenopyrite, FeAsS, in crustal fluids. Geochim Cosmochim Acta 66:2361–2378

    Article  Google Scholar 

  • Schumann R, Stewart W, Miller S, Kawashima N, Li J, Smart R (2012) Acid-base accounting assessment of mine wastes using the chromium reducible sulfur method. Sci Tot Environ 424:289–296

    Article  Google Scholar 

  • Servida D, Grieco G, De Capitani L (2009) Geochemical hazard evaluation of sulphide-rich iron mines: the Rio Marina district (Elba Island, Italy). J Geochem Explor 100:75–89

    Article  Google Scholar 

  • Sima M, Dold B, Frei L, Senila M, Balteanu D, Zobrist J (2011) Sulfide oxidation and acid mine drainage formation within two active tailings impoundments in the Golden Quadrangle of the Apuseni Mountains, Romania. J Hazard Mater 189:624–639

    Article  Google Scholar 

  • Sobek AA, Schuller WA, Freeman JR, Smith RM (1978) Field and laboratory methods applicable to overburdens and mine soils. EPA-600/2-78-054

  • USEPA (1994) Acid mine drainage prediction. US Environmental Protection Agency, EPA 530-R-94-036, p 48

  • Weber PA, Stewart WA, Skinner WM, Weisener CG, Thomas JE, Smart RStC (2004) Geochemical effects of oxidation products and framboidal pyrite oxidation in acid mine drainage prediction techniques. Appl Geochem 19:1953–1974

    Article  Google Scholar 

  • Wedepohl KH (1995) The composition of the continental crust. Geochem Cosmochim Acta 59:1217–1232

    Article  Google Scholar 

  • Wilhelm HJ, Zhang H, Chen FL, Elsenbroek JH, Lombard M, de Bruin D (1997) Geochemical exploration for platinum-group elements in the Bushveld Complex, South Africa. Miner Deposita 32:349–361

    Article  Google Scholar 

  • Yeheyis MB, Shang JQ, Yanful EK (2009) Long-term evaluation of coal fly ash and mine tailings co-placement: a site-specific study. J Environ Manage 91:237–244

    Article  Google Scholar 

Download references

Acknowledgments

This research was supported by the Basic Research Project of the Korea Institute of Geoscience and Mineral Resources (KIGAM) funded by the Ministry of Science, ICT and Future Planning of Korea.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Joo Sung Ahn.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ahn, J.S., Ji, SW., Cho, YC. et al. Assessment of the potential occurrence of acid rock drainage through a geochemical stream sediment survey. Environ Earth Sci 73, 3375–3386 (2015). https://doi.org/10.1007/s12665-014-3625-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12665-014-3625-7

Keywords

Navigation