Skip to main content

Advertisement

Log in

Groundwater quality assessment in Oropos–Kalamos basin, Attica, Greece

  • Original Article
  • Published:
Environmental Earth Sciences Aims and scope Submit manuscript

Abstract

Groundwater samples were collected from 25 sampling sites of the Oropos–Kalamos basin aiming to describe the groundwater quality in relation to geology, lithology and anthropogenic activities of the study area. Chromium speciation analysis, factor analysis, GIS database and geochemical data proved successful tools for the identification of natural and anthropogenic factors controlling the geochemical data variability and for the identification of the redox couple controlling Cr speciation. A Durov diagram is used to classify groundwater quality into five types: Ca–HCO3, Mg–HCO3, Na–Cl, Mg–Cl and Ca–Cl. The groundwater quality of Oropos–Kalamos is influenced by various natural and anthropogenic factors. Evaluation of water quality for drinking and irrigation purposes is discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  • Alexakis D (2008) Geochemistry of stream sediments as a tool for assessing contamination by arsenic, chromium and other toxic elements: East Attica region, Greece. Eur Water 21(22):57–72

    Google Scholar 

  • Alexakis D (2010) Diagnosis of stream sediment quality and assessment of toxic element contamination sources in East Attica, Greece. Environ Earth Sci. doi:10.1007/s12665-010-0807-9

  • Alexakis D, Kelepertsis A (1998) The relationship between the chemical composition-quality of groundwaters and the geological environment in the East Attiki area, Greece. Miner Wealth 109:9–20

    Google Scholar 

  • Alloway BJ (1995) Heavy metals in soil, 2nd edn. Blackie Academic Professional, An imprint of Chapman and Hall, London

  • Arumugam K, Elangovan K (2009) Hydrochemical characteristics and groundwater quality assessment in Tirupur Region, Coimbatore District, Tamil Nadu, India. Environ Geol 58:1509–1520. doi:10.1007/s00254-008-1652-y

    Article  Google Scholar 

  • Ball JW, Izbicki JA (2004) Occurrence of hexavalent chromium in groundwater in the western Mojave Desert, California. Appl Geochem 19:1123–1135

    Article  Google Scholar 

  • Ball JW, McCleskey RB (2003) A new cation-exchange method for accurate field speciation of hexavalent chromium. Talanta 61:305–313

    Article  Google Scholar 

  • CCME (1999) Canadian Council of Minister of the Environment. Canadian Water Quality Guidelines for the Protection of Agricultural Water Uses. Canadian Environmental Quality Guidelines. Pub.No. T/528

  • Chatziapostolou A, Kalaitzidis S, Papazisimou S, Christanis K, Vagias D (2006) Mode of occurrence of trace elements in the Pellana lignite (SE Peloponnese, Greece). Int J Coal Geol 65:3–16

    Article  Google Scholar 

  • Davis JC (1986) Statistics and data analysis in geology. Wiley, New York

    Google Scholar 

  • Dimitrakopoulos D, Vassiliou E, Founda M (2007) Impacts of mining activities on water resources to Megalopolis lignite district area. Geophysical Research Abstracts, Vol9.11028. SRef-ID (2007) 1607-7962/gra/EGU2007-A-11028. European Geosciences Union 2007

  • EC (1998) Council Directive 98/83/EC Directive of the European Parliament on the quality of water intended for human consumption. The European Parliament and the Council of the European Union. Off J L 330

  • Espinosa E, Aurora Armienta M, Cruz O, Aguayo A, Ceniceros N (2009) Geochemical distribution of arsenic, cadmium, lead and zinc in river sediments affected by tailings in Zimapan, a historical polymetalic mining zone of Mexico. Environ Geol 58:1467–1477. doi:10.1007/s00254-008-1649-6

    Article  Google Scholar 

  • Fang WX, Huang ZY, Wu PW (2003) Contamination of the environmental ecosystems by trace elements from mining activities of Badao bone coal mine in China. Environ Geol 44:373–378

    Article  Google Scholar 

  • Fantoni D, Brozzo G, Canepa M, Cipolli F, Marini L, Ottonello G, Zuccolini M (2002) Natural hexavalent chromium in groundwaters interacting with ophiolitic rocks. Environ Geology 42:871–882

    Article  Google Scholar 

  • Fehdi Ch, Aek Rouabhia, Baali F, Boudoukha A (2009) The hydrogeochemical characterization of Morsott-El Aouinet aquifer, Northeastern Algeria. Environ Geol 58:1611–1620. doi:10.1007/s00254-008-1667-4

    Article  Google Scholar 

  • Gascoyne (1989) High levels of uranium and radium in groundwaters at Canada’s Underground Research Laboratory, Lac du Bonnet, Manitoba, Canada. Appl Geochem 4:577–591

    Article  Google Scholar 

  • Hoell K (1979) Wasser: Untersuchung, Beurteilung, Aufbereitung, Chemie, Bakteriologie, Virologie, Biologie. Walter de Gruyter, Berlin

    Google Scholar 

  • IGME (2000) Eretria sheet. Geological Map 1:50,000. Department of Geological Maps. Institute of Geology and Mineral Exploration, Athens 2000

    Google Scholar 

  • Kabata-Pendias A (1995) Agricultural problems related to excessive trace metal contents of soils. In: Salomons W, Forstner U, Mader P (eds) Heavy metals: problems and solutions. Springer, Berlin, pp 3–18

    Google Scholar 

  • Kabata-Pendias A, Pendias H (1995) Trace elements in soils and plants. CRC press, Inc, Boca Raton

    Google Scholar 

  • Kehagia K, Koukouliou V, Bratakos S, Seferlis S, Tzoumerkas F, Potiriadis C (2007) Radioactivity monitoring in drinking water of Attica, Greece. Desalination 213:98–103

    Article  Google Scholar 

  • Kelepertsis A, Alexakis D, Skordas K (2006) Arsenic, antimony and other toxic elements in the drinking water of Eastern Thessaly in Greece and its possible effects on human health. Env Geol 50:76–84. doi:10.1007/s00254-006-0188-2

    Article  Google Scholar 

  • Khan R, Israili SH, Ahmad H, Mohan A (2005) Heavy metal pollution assessment in surface water bodies and its suitability for irrigation around the Neyevli Lignite Mines and Associated Industrial Complex, Tamil Nadu, India. Mine Water Environ 24:155–161

    Article  Google Scholar 

  • Lambrakis N (2006) Multicomponent heterovalent chromatography in aquifers. Modelling salinization and freshening phenomena in field conditions. J Hydrol 323:230–243

    Article  Google Scholar 

  • Liou T-S, Lu H-Y, Lin C-K, Lin W, Chang Y-T, Chien J-M, Chen W-F (2009) Geochemical investigation of groundwater in a Granitic Island: a case study from Kinmen Island, Taiwan. Environ Geol 58:1575–1585. doi:10.1007/s00254-008-1664-7

    Article  Google Scholar 

  • Nalbantis I, Tsakiris G (2009) Assessment of hydrological drought revisited. Water Resour Manag 23:881–897

    Article  Google Scholar 

  • Orloff KG, Mistry K, Charp P, Metcalf S, Marino R, Shelly T, Melaro E, Danohoe A, Jones R (2004) Human exposure to uranium in groundwater. Environ Res 94:319–326

    Article  Google Scholar 

  • Papanikolaou DJ, Mariolakos ID, Lekkas EL, Lozios SG (1988) Morphotectonic observations on the Asopos basin and the Coastal zone of Oropos. Contribution to the Neotectonics of Northern Attica. Bulletin Geological Society, Greece, pp 251–267

    Google Scholar 

  • Pe-Piper G, Piper D (2002) The igneous rocks of Greece. The anatomy of an orogen. Beitrage zur regionalen geologie der erde. Band 30. Berlin-Stuttgart

  • Richard FC, Bourg AC (1991) Aqueous geochemistry of chromium: a review. Wat. Res. 25(7):807–816

    Article  Google Scholar 

  • Robles-Camacho J, Armienta MA (2000) Natural chromium contamination of groundwater at Leon Valley, Mexico. J Geoch Explor 68:167–181

    Article  Google Scholar 

  • Shomar BH, Muller G, Yahya A (2005) Geochemical features of topsoils in the Gaza Strip: natural occurrence and anthropogenic inputs. Environ Res 98:372–382

    Article  Google Scholar 

  • Simsek C (2008) Assessment of natural radioactivity in aquifer medium bearing uranium ores in Koprubasi, Turkey. Environ Geol 55:1637–1646. doi:10.1007/s00254-007-1113-z

    Article  Google Scholar 

  • Singh P, Rana NP, Azam A, Naqvi AH, Srivastava DS (1996) Levels of uranium in waters from some Indian cities determined by fission track analysis. Radiation Measurements 26(5):683–687

    Article  Google Scholar 

  • Skeppstrom K, Olofsson B (2007) Uranium and radon in groundwater. an overview of the problem. Eur Water 17(18):51–62

    Google Scholar 

  • Stamatis G, Gartzos E (1999) The silica supersaturated waters of northern Evia and eastern central Greece. Hydrol Process 13:2833–2845

    Article  Google Scholar 

  • Stamatis G, Lambrakis N, Alexakis D, Zagana E (2006) Groundwater quality in eastern Attica (Greece). Hydrolol Process 20:2803–2818

    Article  Google Scholar 

  • Tsakiris G, Spiliotis M, Paritsis S, Alexakis D (2009) Assessing the water potential of karstic saline springs by applying a fuzzy approach: the case of Almyros (Heraklion, Crete). Desalination 237:54–64

    Article  Google Scholar 

  • Venkataraman BV, Sudha S (2005) Vanadium Toxicity. Asian J Exp Sci 2:127–134

    Google Scholar 

  • Voreadis G (1952) The tertiary lignite basin of Malakasa-Oropos. Geol Geophys Sur 2: 141–180

    Google Scholar 

  • WHO (2004) Guidelines for drinking water quality, vol 1. World Health Organisation, Geneva, pp 1–494

    Google Scholar 

  • Zamora ML, Tracy BL, Zielinski JM, Meyerhof DP, Moss MA (1998) Chronic ingestion of uranium in drinking water: a study of kidney bioeffects in humans. Toxicol Sci 43:68–77

    Article  Google Scholar 

Download references

Acknowledgments

We thank N. Voutsis and S. Peppas for the assistance rendered during the fieldwork of this study. We would like to thank the staff of the Department of Economic Geology and Geochemistry, National and Kapodistrian University of Athens, for cooperation during the chromium chemical analyses by using AAS. The authors are thankful to the anonymous reviewer for giving valuable suggestions for improving the quality of the paper.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to D. Alexakis.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Stamatis, G., Alexakis, D., Gamvroula, D. et al. Groundwater quality assessment in Oropos–Kalamos basin, Attica, Greece. Environ Earth Sci 64, 973–988 (2011). https://doi.org/10.1007/s12665-011-0914-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12665-011-0914-2

Keywords

Navigation