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Optimizing first-, second- and third-order optical traits of zinc tris-thiourea sulphate (ZTS) crystal by l-tyrosine for photonic device applications

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Abstract

Up-gradation of modern era photonic devices encourages modelling of nonlinear optical crystal that embraces excellent linear–nonlinear optical properties. Hence, this is the first effort in the literature to improve the optical performance of zinc tris-thiourea sulphate (ZTS) crystal using l-tyrosine (Ty). The energy-dispersive spectroscopy is used to determine the incorporation of Ty. Single-crystal XRD analysis is employed to determine the structural parameters. The 5% increase in transmittance of ZTS crystal due to Ty has been evaluated by UV–visible study. Kurtz–Perry test confirmed that frequency doubling ability of Ty-ZTS crystal is 1.71 times higher than ZTS. The occurrence of photoluminescence nature has been investigated within visible region. The noticeable change in third-order nonlinear optical refraction (from negative to positive) and absorption (from reverse saturable absorption to saturable absorption) profile of ZTS crystal facilitated due to Ty has been explored. The Z-scan data has been accessed for comparative evaluation of n2, β and χ3 of pure and Ty-ZTS crystal. The n2, β and χ3 of Ty-ZTS crystal is of order 10–8, 10–4, 10–3 while that of ZTS is 10–12, 10–4, 10–4, respectively.

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Acknowledgements

The author Ehab El Sayed Massoud would like to express his gratitude to the Deanship of Scientific Research at King Khalid University, Abha, Saudi Arabia, for funding through Research Groups Program under Grant No. R.G.P.2/7/43.

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Authors and Affiliations

  1. Department of Physics and Electronics, Maulana Azad College of Arts, Science and Commerce, Aurangabad, Maharashtra, 431001, India

    Mohd Anis

  2. Department of Physics, Sant Gadge Baba Amravati University, Amravati, Maharashtra, 444602, India

    G. G. Muley & S. P. Ramteke

  3. Prof Ram Meghe College of Engineering and Management, Amravati, Maharashtra, 444701, India

    M. I. Baig

  4. Dr. RG. Bhoyar Art’s, Commerce and Science College, Seloo, Wardha, Maharashtra, 442104, India

    Waseem Ahmed Khan

  5. Biology Department, Faculty of Science and Arts in Dahran Aljnoub, King Khalid University, Abha, Kingdom of Saudi Arabia

    Ehab El Sayed Massoud

  6. Research Center for Advanced Materials Science (RCAMS), King Khalid University, Abha, Kingdom of Saudi Arabia

    Ehab El Sayed Massoud

  7. Agriculture Research Centre, Soil, Water and Environment Research Institute, Giza, Egypt

    Ehab El Sayed Massoud

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  1. Mohd Anis
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  2. G. G. Muley
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  3. M. I. Baig
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Correspondence to Mohd Anis.

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Anis, M., Muley, G.G., Baig, M.I. et al. Optimizing first-, second- and third-order optical traits of zinc tris-thiourea sulphate (ZTS) crystal by l-tyrosine for photonic device applications. Indian J Phys 97, 251–254 (2023). https://doi.org/10.1007/s12648-022-02381-5

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  • DOI: https://doi.org/10.1007/s12648-022-02381-5

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