Abstract
Polymer composite films based on PVA–PVP with AlCl3 as the dopant at different concentrations were prepared using solution casting technique. XRD patterns reveal the increase in amorphousity of the films with AlCl3 doping. Optical absorption studies exhibit that the values of optical absorption coefficient, direct and indirect optical band gaps are found to decrease with increase in AlCl3 concentration. It confirms the charge transfer in complexes between the polymer and the dopant. The dielectric studies show the increase in dielectric constant at low frequency with increasing AlCl3 concentration and temperature. The ac conductivity and ionic conductivity increase with the AlCl3 content and the maximum value at room temperature is found to be 6.89 × 10−4 and 8.05 × 10−5 S/cm for higher AlCl3 doped PVA–PVP film. The estimated ionic conductivity value is three or four orders of magnitude greater than those obtained in the certain representative polymer-salt complexes as reported earlier. Electrical modulus plots confirm the removal of electrode polarization and the low conductivity relaxation time with Al doping. The activation energy estimated from the temperature dependent dc conductivity plot is agreed well with the migration energy calculated from the temperature dependent electric modulus plot.
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M B Armond Ann. Rev. Mater. Sci. 16 245 (1986)
M A Ratner and D F Shriver Chem. Rev. 88 109 (1988)
M Watanabe, K Sanui, N Ogata, F Inoue, T Kobayashi and Z Ohtaki Polym. J. 16 711 (1984)
L Lee, S Park and S Kim Solid State Ionics 234 19 (2013)
M C Wintergrill, J J Fontanella, M K Smith, S S Greenbaum, K J Adam and C C Andeen Polymer 28 633 (1987)
J Procharski, W Wiecxorek, J Przyluski and K Such Appl. Phys. A. 49 55 (1989)
N Reddeppa, T J R Reddy, V B S Achari, V V R N Rao and A K Sharma Ionics 15 255 (2009)
Y H Liang, C.Y. Hung and C C Wang J. Power Sour. 188 261 (2009)
R Baskaran, S Selvasekarapandian, N Kuwata, J Kawamura and T Hattori Mater. Chem. Phys. 98 55 (2006)
N F Mott and E A Davis Electronic Processes in Non-crystalline Materials, 2nd edn. (Oxford: Clarendon Press) W H Marshall and D H Wilkinson 270 (1972)
S Ramesh and O L Ling Polym. Chem. 1 702 (2010)
B Natesan, N K Karan and R S Katiyar Phys. Rev. E. 74 042801 (2006)
H M Ragab Physica B. 406 3759 (2011)
M Hema, S Selvasekerapandian, A Sakunthala, D Arunkumar and H Nithya Physica B. 403 2740 (2008)
V Krishnakumar and G Shanmugam Ionics 18 403 (2012)
K Kiran Kumar, M Ravi, Y Pavani, S Bhavani, A K Sharma and V V R Narasimha Rao Phys. B. 406 1706 (2011)
M A F Basha Polym. J. 42 728 (2010)
N Imanaka, Y Hasegawa, M Yamaguchi, M Itaya, S Tamura and G Adachi Chem. Mater. 14 4481 (2002)
L Zhang, P Chen, Z Hu and C Chen-hua Chin. J. Chem. Phys. 25 703 (2012)
G K Prajapati and P N Gupta Physica B. 406 3108 (2011)
R M Hodge, G H Edwrd and E P Simon Polymer. 37 1371 (1996)
A A Mohamad, N S Mohamad, M Z A Yahya, R Othman, S Ramesh, Y Alias and A K Aroof Solid State Ionics. 156 171 (2003)
E M Abdelrazek Physica B. 403 2137 (2008)
Y Aydogdu, F Yakuphanoglu, A Aydodu, E Tas and A Cukuraval Solid State Sci. 4 879 (2002)
J R MacCullum and C R Vincent Polymer Electrolytes Reviews-2 (England: Elsevier Science Publishers Ltd) (1989)
A Awadhia, S K Patel and S L Agrawal Prog. Cryst. Growth Charact. Mater. 52 61 (2006)
X Sun, T Fujimoto and H Uyama Polym. J 45 1101 (2013)
P Sharma and D K Kanchan Polym. Int. 63 290 (2014)
M Watanabe, S Nagona, K Sanui and N Ogato J. Power Sour. 20 327 (1987)
D K Pradhan, R N P Choudhary and B K Samantaray Express Polym. Lett. 2 630 (2008)
V Krishnakumar and G Shanmugam Sci. Adv. Mater. 4 1247 (2012)
S- W Ryu Polym. J. 40 688 (2008)
G Hirankumar, S Selvasekarapandian, M S Bhuvaneswari, R Baskaran and M Vijayakumar J. Solid State Electrochem. 10 193 (2006)
S B Aziz, Z H Z Abidin and A K Arof Express Polym. Lett. 4 300 (2010)
Acknowledgements
The authors gratefully acknowledge the financial support from University Grants Commission (UGC), New Delhi, India, to undertake this work (Grant No. F.39-494/2010 (SR)).
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Shanmugam, G., Krishnakumar, V. Effects of anhydrous AlCl3 dopant on the structural, optical and electrical properties of PVA–PVP polymer composite films. Indian J Phys 92, 605–613 (2018). https://doi.org/10.1007/s12648-017-1140-x
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DOI: https://doi.org/10.1007/s12648-017-1140-x