Abstract
We built a collinear dual-pulse laser-induced breakdown spectroscopy (DP-LIBS) system to study the aluminum (Al) plasma emission by installing a pair of Nd: YAG lasers operating at 266 and 1064 nm. The spectral intensities of selected aluminum doubly-ionized lines were employed to evaluate the optical emission spectra. The influences of the energy ratio of two pulsed lasers on the LIBS intensity for different Al doubly-ionized spectral lines were investigated. The de-excitation rate parameters of the excited ion and the electron impact excitation were computed using the analytical formulas proposed by Smeets and Vriens. The transition probabilities and energy states were computed using Hibbert’s configuration interaction, computer package (CIV3). By solving the coupled rate equations including 1s 22s 22p 6ns (2S), 1s 22s 22p 6np (2P), 1s 22s 22p 6nd (2D) (n = 3–5) and 1s 22s 22p 6nf (2F) (n = 4, 5) states, the level population densities were computed. We also proposed a theoretical population model in order to investigate the effectiveness of the various processes that might affect the population of the upper levels in Al plasma by using the rate coefficients. In addition, the population densities for the 19 upper levels were also computed. Good compatibility between the experimental and the theoretical model data had been observed. Our results might be significant as reference data for the optimization of the DP-LIBS spectrometry and diagnostics of laser produced plasmas.
Similar content being viewed by others
References
A Safi, M Bahreini and S H Tavassoli Optics Spectrosc. 120 367 (2016)
F Colao, V Lazic, R Fantoni and S Pershin Spectrochim. Acta B 57 1167 (2002)
D A C Leon and J Radziemski Laser-induced Plasmas and Application (New York: CRC Press) p 1 (1989)
M S Rafique, M Khaleeq-Ur-Rahman, I Riaz, R Jalil and N Farid Laser Part. Beams 26 217 (2008)
A Hartgers, J Van Dijk, J Jonkers and J Van der Mullen Phys. Commun. 135 199 (2001)
E Clementi, C Roetti Rothman–Hartree–Fock At. Data Nucl. Data Tables 14 177 (1974)
U Feldman, G A Koscheck, J F Seely and A K Bhatia J. Appl. Phys. 58 8 (1985)
A A I Khalil Appl. Phys. A 119 1087 (2015)
P A Benedetti, G Cristoforetti, S Legnaioli, V Palleschi, L Pardini, A Salvetti and E Tognoni Spectrochim. Acta B 60 1392 (2005)
A Kramida, Yu Ralchenko, J Reader and NIST ASD Team NIST Atomic Spectra Database (http://physics.nist.gov/asd) 5.2 5 (2016)
L Vriens Phys. Rev. A 22 940 (1980)
S H Allam (Private communication) (2016)
R Glass and A Hibbert Comput. Phys. Commun. 16 19 (1978)
A A I Khalil Opt. Laser Technol. 45 443 (2013)
A A I Khalil, M Richardson, L Johnson and M Gandol Laser Phys. 19 1981 (2009)
N M Shaikh, S Hafeez, M A Kalyar, R Ali and M A Baig Appl. Phys. 104 103108 (2008)
E Tognoni and G Cristoforetti J. Anal. At. Spectrom. 29 1318 (2014)
S Sai Shiva, Ch Leela, P P Kiran, C D Sijoy and S Chaturvedi Phys. Plasmas 23 053107 (2016)
A A I Khalil, M Richardson, C Barnett and L Johnson J. Appl. Spectrosc. 73 735 (2006)
A A I Khalil Opt. Laser Technol. 75 105 (2015)
M Cirisan, M Cvejic, M R Gavrilovic, S Jovicevic, N Konjevic and J Hermann J. Quant. Spectrosc. Radiat. Transf. 133 652 (2014)
M Burger and J Hermann Spectrochim. Acta B 122 118 (2016)
H R Griem Plasma Spectroscopy (New York: McGraw-Hill) p 1 (1964)
M Sabsabi and P Cielo Appl. Spectrosc. 49 499 (1995)
W T Y Mohamed Prog. Phys. 2 87 (2007)
G Bekefi Principles of Laser Plasmas (New York: Wiley) p 550 (1976)
M H Mahdieh, M A Jafarabadi, S Firozyar and S Hajiani SPIE 8677 867711-1 (2013)
A A I Khalil and M A Morsy Talanta 154 109 (2016)
G Cristoforetti, A De Giacomo, M Dell’Aglio, S Legnaioli, E Tognoni, V Palleschi and N Omenetto Spectrochim. Acta B 65 86 (2010)
Acknowledgments
Authors are thankful to National Institute of Laser Enhanced Sciences (NILES), Cairo University, Giza, Egypt and the deanship of scientific research, University of Dammam, Saudi Arabia for supporting this work through project ID # 2014101. Authors would also like to thank Prof. Sami Allam, Department of Physics, Faculty of Science, Cairo University, Giza, Egypt for his help and improvement of our software code used in this manuscript.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Khalil, A.A.I., Younis, W.O. & Gandol, M.A. A comparative study of highly-ionized Al plasma based on dual pulse laser-induced breakdown spectroscopy. Indian J Phys 91, 327–336 (2017). https://doi.org/10.1007/s12648-016-0926-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12648-016-0926-6
Keywords
- DP-LIBS
- Double-ionized Al spectral lines
- Electron impact excitation coefficient
- De-excitation rate coefficients for Al ions