Abstract
The anomalous structure and related properties of liquid KPb alloy are presented through an ab initio evaluated ordering potential as a function of concentration. It appears that considerable ordering occurs and it maximizes at the stoichiometric composition (ck∼0.5). We then use the model to obtain the Bhatia-Thornton(BT) structure factors at different compositions (ck=0.1,0.3,0.5 and 0.8). The calculations of concentration fluctuation and other related thermodynamic properties show that this ordering potential approach works reasonably for this compound forming liquid alloy.
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Nath, P.P., Joarder, R.N. Ordering potential: the anomalous structure and properties of liquid KPb alloy. Indian J Phys 84, 125–132 (2010). https://doi.org/10.1007/s12648-010-0031-1
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DOI: https://doi.org/10.1007/s12648-010-0031-1