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Production and characterization of Fe3O4@SiO2@TMEDA-Pd as a very effectual interphase catalyst for the rapid preparation of di-aryl sulfides and pyrido-dipyrimidines

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Abstract

In this study, the synthesis and detection of magnetic interphase nanocatalyst Fe3O4@SiO2@TMEDA-Pd is described as a heterogeneous catalyst highly efficient for the rapid preparation of di-aryl sulfides and pyrido-dipyrimidine derivatives. The catalyst was characterized using various techniques including ICP-OES (inductively coupled plasma optical emission spectrometry), Fourier transform infrared (FT-IR), FE-SEM (field emission scanning electron microscopy), TEM (transmission electron microscopy), XRD (X-ray diffraction analysis), Elemental mapping, EDS (energy-dispersive X-ray spectroscopy), VSM (vibrating sample magnetometry), TGA (thermal gravimetric analysis) and BET (Brunauer–Emmett–Teller). The synthesis of the mentioned derivatives with our catalyst was accompanied by the following advantages, which all showed our good idea for designing this catalyst: performing reactions in mild conditions with excellent efficiency, short reaction times, simple work-up, appropriate values of turnover frequency (TOF) and turnover number (TON), possibility to use external magnets to accelerate the separation of the catalyst from the reaction mixture and its reusability without considerable diminish in selectivity and activity.

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Acknowledgements

We are grateful to acknowledge the Research Council of Technical and Vocational University (TVU), Ilam-Iran.

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The authors declare that no funds, grants, or other support were received during the preparation of this manuscript.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, Ilam Branch, Technical and Vocational University (TVU), Ilam, Iran

    Alireza Kohzadian

  2. Young Researchers Club, Ilam Branch, Islamic Azad University, Ilam, Iran

    Hossein Filian

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  1. Alireza Kohzadian
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  2. Hossein Filian
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Contributions

Alireza Kohzadian: synthesized the catalyst, all derivatives and editing the manuscript.

Hossein Filian: writing and reviewing the manuscript.

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Correspondence to Alireza Kohzadian.

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12633_2023_2372_MOESM1_ESM.docx

Supplementary information of this article which includes the spectral data and the original spectrums of di-aryl sulfides and pyrido-dipyrimidines is accessible to allowed users in the online version. (DOCX 6653 KB)

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Kohzadian, A., Filian, H. Production and characterization of Fe3O4@SiO2@TMEDA-Pd as a very effectual interphase catalyst for the rapid preparation of di-aryl sulfides and pyrido-dipyrimidines. Silicon 15, 4539–4554 (2023). https://doi.org/10.1007/s12633-023-02372-z

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