Abstract
The current study aims to synthesize copper alloy and functionally graded Cu-10Sn-5Ni/10Si3N4 composite using horizontal centrifugal casting method and compare their mechanical and adhesive wear characteristics. The fabricated castings have dimensions of Øout100 x Øin70 × 100 mm. Microstructural analysis revealed that inner region of composite possesses higher concentration of reinforcement particles, resulting in better hardness and tensile properties at this region compared to outer regions of both unreinforced alloy and composite. Analysis of dry sliding wear performance and frictional coefficient was performed at inner region of the composite under different sliding conditions using Taguchi’s method on pin-on-disc tribometer. Signal-to-Noise ratio and Analysis of Variance results concluded that applied load had the most influence on wear rate and coefficient of friction followed by sliding distance and sliding velocity. Worn surface morphologies of composite specimens revealed a transition from mild to severe wear at high loads. The fabricated composites are well suitable for sliding tribological applications.
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References
Davis JR (2001) ASM Speciality Handbook: Copper and copper alloys. ASM international, 3-9. https://doi.org/10.1361/caca2001p003
Phani PS, Vishnukanthan V, Sundararajan G (2007) Effect of heat treatment on properties of cold sprayed nanocrystalline copper alumina coatings. Acta Mater 55(14):4741–4751
Radhika N, Raghu R (2015) Mechanical and tribological properties of functionally graded aluminium/zirconia metal matrix composite synthesized by centrifugal casting. Int J Mater Res 106(11):1174–1181
Tjong SC, Lau KC (2000) Tribological behaviour of SiC particle-reinforced copper matrix composites. Mater Lett 43(5–6):274–280
Macke A, Schultz BF, Rohatgi P (2012) Metal matrix composites. Adv Mater Process 170(3):19–23
Cole GS, Sherman AM (1995) Lightweight materials for automotive applications. Mater Charact 35(1):3–9
Gogotsi YG (1994) Particulate silicon nitride-based composites. J Mater Sci 29(10):2541–2556
Tu JP, Wang NY, Yang YZ, Qi WX, Liu F, Zhang XB, Lu HM, Liu MS (2002) Preparation and properties of TiB2 nanoparticle reinforced copper matrix composites by in situ processing. Mater Lett 52(6):448–452
Akhtar F, Askari SJ, Shah KA, Du X, Guo S (2009) Microstructure, mechanical properties, electrical conductivity and wear behavior of high volume TiC reinforced Cu-matrix composites. Mater Charact 60(4):327–336
Zhan Y, Zhang G (2003) Graphite and SiC hybrid particles reinforced copper composite and its tribological characteristic. J Mater Sci 22(15):1087–1089
Wu JY, Zhou YC, Wang JY (2006) Tribological behavior of Ti2SnC particulate reinforced copper matrix composites. Mater Sci Eng A 422(1–2):266–271
Xia L, Jia B, Zeng J, Xu J (2009) Wear and mechanical properties of carbon fiber reinforced copper alloy composites. Mater Charact 60(5):363–369
Kestursatya M, Kim JK, Rohatgi PK (2001) Friction and wear behavior of a centrifugally cast lead-free copper alloy containing graphite particles. Metall Mater Trans A 32(8):2115–2125
Senthil Kumar P, Manisekar K, Subramanian E, Narayanaswamy R (2013) Dry sliding friction and wear characteristics of cu-Sn alloy containing molybdenum disulfide. Tribol T 56(5):857–866
Radhika N, Raghu R (2016) Development of functionally graded Aluminium composites using centrifugal casting and influence of reinforcements on mechanical and Wear properties. Trans Nonferrous Metals Soc China 26(4):905–916
Kieback B, Neubrand A, Riedel H (2003) Processing techniques for functionally graded materials. Mater Sci Eng A 362(1):81–106
Chirita G, Soares D, Silva FS (2008) Advantages of the centrifugal casting technique for the production of structural components with Al–Si alloys. Mater Des 29(1):20–27
Sharma P, Sharma S, Khanduja D (2015) Production and some properties of Si3N4 reinforced aluminium alloy composites. J Asian Ceramic Soc 3(3):352–359
Whalen TJ, Anderson AT (1975) Wetting of SiC, Si3N4, and carbon by Si and binary Si alloys. J Am Ceram Soc 58(9–10):396–399
Ramesh CS, Keshavamurthy R, Channabasappa BH, Ahmed A (2009) Microstructure and mechanical properties of Ni–P coated Si3N4 reinforced Al6061 composites. Mater Sci Eng A 502(1–2):99–106
Amigo V, Ortiz JL, Salvador MD (2000) Microstructure and mechanical behavior of 6061Al reinforced with silicon nitride particles, processed by powder metallurgy. Scr Mater 42(4):383–388
Lee KB, Kwon H (1999) Fabrication and characteristics of AA6061/Si3N4p composite by the pressureless infiltration technique. Metall. Mater. Trans. A 30(11):2999–3007
Kumar NM, Kumaran SS, Kumaraswamidhas LA (2016) Wear behaviour of Al 2618 alloy reinforced with Si3N4, AlN and ZrB2 in situ composites at elevated temperatures. Alex Eng J 55(1):19–36
Robin A, de Santana JCP, Sartori AF (2010) Characterization of copper–silicon nitride composite electrocoatings. J Appl Electrochem 40(3):507–513
Radhika N, Subramaniam R (2013) Wear behaviour of aluminium/alumina/graphite hybrid metal matrix composites using Taguchi's techniques. Ind Lubr Tribol 65(3):166–174
Basavarajappa S, Chandramohan G, Davim JP (2007) Application of Taguchi techniques to study dry sliding wear behaviour of metal matrix composites. Mater Des 28(4):1393–1398
Radhika N, Vaishnavi A, Chandran GK (2014) Optimisation of dry sliding wear process parameters for Aluminium hybrid metal matrix composites. Tribol Ind 36(2):188–194
Theivasanthi T, Alagar M (2010) X-ray diffraction studies of copper nanopowder. arXiv preprint arXiv: 1003.6068
Bai YJ, Bian J, Wang CG, Zhu B, Qi YX, Wang YX, Liu YX, Geng GL (2005) One step convenient synthesis of crystalline β-Si3N4. J Mater Chem 15(45):4832–4837
Mandal A, Maiti R, Chakraborty M, Murty BS (2004) Effect of TiB2 particles on aging response of Al–4Cu alloy. Mater Sci Eng A 386(1–2):296–300
Deshpande PK, Lin RY (2006) Wear resistance of WC particle reinforced copper matrix composites and the effect of porosity. Mater Sci Eng A 418(1–2):137–145
Hong E, Kaplin B, You T, Suh MS, Kim YS, Choe H (2011) Tribological properties of copper alloy-based composites reinforced with tungsten carbide particles. Wear 270:591–597
Zhang L, He XB, Qu XH, Duan BH, Lu X, Qin ML (2008) Dry sliding wear properties of high volume fraction SiCp/Cu composites produced by pressureless infiltration. Wear 265(11–12):1848–1856
Nayak D, Ray N, Sahoo R, Debata M (2014) Analysis of tribological performance of Cu hybrid composites reinforced with graphite and TiC using factorial techniques. Tribol Trans 57:908–918
Sangaravadivel P, Natarajan N, Krishnaraj V (2016) Experimental investigation and optimization of dry sliding Wear parameters on solid lubricant reinforced bronze matrix composites-a Taguchi approach. Appl Mech Mater 852:435–445
Zhan Y, Zhang G (2004) Friction and wear behavior of copper matrix composites reinforced with SiC and graphite particles. Tribol Lett 17(1):91–98
Das Bakshi S, Leiro A, Prakash B, Bhadeshia HK (2015) Dry rolling/sliding wear of nanostructured pearlite. Mater Sci Technol 31(14):1735–1744
Zhang G, Schlarb AK (2009) Morphologies of the wear debris of polyetheretherketone produced under dry sliding conditions: correlation with wear mechanisms. Wear 266(7–8):745–752
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We are so thankful to Defense Research and Development Organization for providing the financial support. [ERIP/ER/1503188/M/01/1587].
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Radhika, N., Thirumalini, S. & Jojith, R. Development and Properties of Centrifugally Cast Silicon Nitride Reinforced Functionally Graded Copper Matrix Composite. Silicon 11, 2103–2116 (2019). https://doi.org/10.1007/s12633-018-0030-y
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DOI: https://doi.org/10.1007/s12633-018-0030-y