Abstract
Viscosity is an important physical property of blast furnace slags and has a great influence on blast furnace operations. Because of time consumption and difficulties encountered during high temperature experimental measurement, viscosity data are also limited, so a reasonable and accurate estimation model is required to provide the data for controlling and optimizing the blast furnace process. In the present study a viscosity model was proposed for blast furnace slags. In the model the activation energy was calculated by the optical basicity corrected for cations required for the charge compensation of AlO 5−4 , and the temperature dependence was described by the Weymann-Frenkel equation. The estimated viscosity values of the CaO-Al2O3-SiO2, CaO-Al2O3-SiO2-MgO, and CaO-Al2O3-SiO2-MgO-TiO2 systems fit well with experiment data, with the mean deviation less than 25%.
Similar content being viewed by others
References
P.V. Riboud, L.D.L. Roux, and H. Gaye, Improvement of continuous casting powders, Fachber. Hüettenprax. Metallweiterverarb., 19(1981), No.10, p.859.
G. Urbain, Viscosity estimation of slags, Steel Res., 58(1987), No.3, p.111.
D. Sichen, J. Bygdén, and S. Seetharaman, A model for estimation of viscosities of complex metallic and ionic melts, Metall. Mater. Trans. B, 25(1994), p.519.
L. Zhang and S. Jahanshahi, Review and modeling of viscosity of silicate melts: Part I. Viscosity of binary and ternary silicates containing CaO, MgO, and MnO, Metall. Mater. Trans. B, 29(1998), p.177.
A. Kondratiev and E. Jak, Predicting coal ash slag flow characteristics (viscosity model for the Al2O3-CaO-’FeO’-SiO2 system), Fuel, 80(2001), p.1989.
T. Iida, H. Sakal, Y. Kita, and K. Shigeno, An equation for accurate prediction of the viscosities of blast furnace type slags from chemical composition, ISIJ Int., 40(2000), Suppl., p.S110.
K.C. Mills and S. Sridhar, Viscosities of ironmaking and steelmaking slags, Ironmaking Steelmaking, 26(1999), No.4, p.262.
H.S. Ray and S. Pal, Simple method for theoretical estimation of viscosity of oxide melts using optical basicity, Ironmaking Steelmaking, 31(2004), No.2, p.125.
Y. Miyabayashi, M. Nakamoto, T. Tanaka, and T. Yamamoto, A model for estimating the viscosity of molten Aluminosilicate containing calcium fluoride, ISIJ Int., 49(2009), No.3, p.343.
Q.F. Shu, A viscosity estimation model for molten slags in CaO-Al2O3-MgO-SiO2 system, Steel Res. Int., 80(2009), No.2, p.107.
M.J. Toplis and D.B. Dingwell, Shear viscosities of CaO-Al2O3-SiO2 and MgO-Al2O3-SiO2 liquids: implications for the structural role of aluminium and the degree of polymerisation of synthetic and natural aluminosilicate melts, Geochim. Cosmochim. Acta, 68(2004), p.5169.
J.A. Duffy and M.D. Ingram, Optical basicity-IV: influence of electronegativity on the Lewis basicity and solvent properties of molten oxyanion salts and glasses, J. Inorg. Nucl. Chem., 37(1975), p.1203.
G.H. Zhang, K.C. Chou, and F.S. Li, A new model for evaluating the electrical conductivity of nonferrous slag, Int. J. Miner. Metall. Mater., 16(2009), No.5, p.500
J.S. Machin, T.B. Yee, and D.L. Hanna, Viscosity Studies of System CaO-MgO-Al 2O3-SiO2: III. 35, 45, and 50% SiO 2, Illinois State Geological Survey Report of Investigations No.163, 1953
P. Kozakevitch, Viscosite et elements structuraux des aluminosilicates fondus: laitiers CaO-Al2O3-SiO2 entre 1600 et 2100 °C,, Rev. Metall., 57(1960), p.149.
K.C. Mills, L. Chapman, A.B. Fox, and S. Sridhar, ’Round robin’ project on the estimation of slag viscosities, Scand. J. Metall., 30(2001), p.396.
N. Saito, N. Hori, K. Nakashima, and K. Mori, Viscosity of blast furnace type slags, Metall. Mater. Trans. B, 34(2003), p.509.
A. Shankar, M. Görnerup, A.K. Lahiri, and S. Seetharaman, Experimental investigation of viscosities in CaO-SiO2-MgO-Al2O3 and CaO-SiO2-MgO-Al2O3-TiO2 slags, Metall. Mater. Trans. B, 38(2007), p.911.
J.F. Stebbins and Z. Xu, NMR evidence for excess non-bridging oxygen in an aluminosilicate glass, Nature, 390(1997), p.60
V.D. Eisenhüttenleute, Slag Atlas, Verlag Sthaleisen GmbH, Germany, 1995, P.6.
T. Nakamura, K. Morinaga, and T. Yanagase, The viscosity of the molten silicate containing TiO2, J. Jpn. Inst. Met., 41(1977), p.1300.
T. Yasukouchi, K. Nakashima, and K. Mori, Viscosity of ternary CaO-SiO2-Mx(F,O)y and CaO-Al2O3-Fe2O3 melts, Tetsu-to-Hagane, 85(1999), No.8, p.571.
A. Ohno and H.U. Ross, Optimum slag composition for the blast-furnace smelting of titaniferous ores, Can. Metall. Q., 1963, No.3, p.259.
K.H. Sun, Fundamental condition of glass formation, J. Am. Ceram. Soc., 30(1947), No.9, p.227.
Author information
Authors and Affiliations
Corresponding author
Additional information
The work was financially supported by the National Natural Science Foundation of China (No.51090384).
Rights and permissions
About this article
Cite this article
Hu, Xj., Ren, Zs., Zhang, Gh. et al. A model for estimating the viscosity of blast furnace slags with optical basicity. Int J Miner Metall Mater 19, 1088–1092 (2012). https://doi.org/10.1007/s12613-012-0675-2
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12613-012-0675-2