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A model for estimating the viscosity of blast furnace slags with optical basicity

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Abstract

Viscosity is an important physical property of blast furnace slags and has a great influence on blast furnace operations. Because of time consumption and difficulties encountered during high temperature experimental measurement, viscosity data are also limited, so a reasonable and accurate estimation model is required to provide the data for controlling and optimizing the blast furnace process. In the present study a viscosity model was proposed for blast furnace slags. In the model the activation energy was calculated by the optical basicity corrected for cations required for the charge compensation of AlO 5−4 , and the temperature dependence was described by the Weymann-Frenkel equation. The estimated viscosity values of the CaO-Al2O3-SiO2, CaO-Al2O3-SiO2-MgO, and CaO-Al2O3-SiO2-MgO-TiO2 systems fit well with experiment data, with the mean deviation less than 25%.

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References

  1. P.V. Riboud, L.D.L. Roux, and H. Gaye, Improvement of continuous casting powders, Fachber. Hüettenprax. Metallweiterverarb., 19(1981), No.10, p.859.

    CAS  Google Scholar 

  2. G. Urbain, Viscosity estimation of slags, Steel Res., 58(1987), No.3, p.111.

    CAS  Google Scholar 

  3. D. Sichen, J. Bygdén, and S. Seetharaman, A model for estimation of viscosities of complex metallic and ionic melts, Metall. Mater. Trans. B, 25(1994), p.519.

    Article  Google Scholar 

  4. L. Zhang and S. Jahanshahi, Review and modeling of viscosity of silicate melts: Part I. Viscosity of binary and ternary silicates containing CaO, MgO, and MnO, Metall. Mater. Trans. B, 29(1998), p.177.

    Article  Google Scholar 

  5. A. Kondratiev and E. Jak, Predicting coal ash slag flow characteristics (viscosity model for the Al2O3-CaO-’FeO’-SiO2 system), Fuel, 80(2001), p.1989.

    Article  CAS  Google Scholar 

  6. T. Iida, H. Sakal, Y. Kita, and K. Shigeno, An equation for accurate prediction of the viscosities of blast furnace type slags from chemical composition, ISIJ Int., 40(2000), Suppl., p.S110.

    Article  CAS  Google Scholar 

  7. K.C. Mills and S. Sridhar, Viscosities of ironmaking and steelmaking slags, Ironmaking Steelmaking, 26(1999), No.4, p.262.

    Article  CAS  Google Scholar 

  8. H.S. Ray and S. Pal, Simple method for theoretical estimation of viscosity of oxide melts using optical basicity, Ironmaking Steelmaking, 31(2004), No.2, p.125.

    Article  CAS  Google Scholar 

  9. Y. Miyabayashi, M. Nakamoto, T. Tanaka, and T. Yamamoto, A model for estimating the viscosity of molten Aluminosilicate containing calcium fluoride, ISIJ Int., 49(2009), No.3, p.343.

    Article  CAS  Google Scholar 

  10. Q.F. Shu, A viscosity estimation model for molten slags in CaO-Al2O3-MgO-SiO2 system, Steel Res. Int., 80(2009), No.2, p.107.

    CAS  Google Scholar 

  11. M.J. Toplis and D.B. Dingwell, Shear viscosities of CaO-Al2O3-SiO2 and MgO-Al2O3-SiO2 liquids: implications for the structural role of aluminium and the degree of polymerisation of synthetic and natural aluminosilicate melts, Geochim. Cosmochim. Acta, 68(2004), p.5169.

    Article  CAS  Google Scholar 

  12. J.A. Duffy and M.D. Ingram, Optical basicity-IV: influence of electronegativity on the Lewis basicity and solvent properties of molten oxyanion salts and glasses, J. Inorg. Nucl. Chem., 37(1975), p.1203.

    Article  CAS  Google Scholar 

  13. G.H. Zhang, K.C. Chou, and F.S. Li, A new model for evaluating the electrical conductivity of nonferrous slag, Int. J. Miner. Metall. Mater., 16(2009), No.5, p.500

    Article  CAS  Google Scholar 

  14. J.S. Machin, T.B. Yee, and D.L. Hanna, Viscosity Studies of System CaO-MgO-Al 2O3-SiO2: III. 35, 45, and 50% SiO 2, Illinois State Geological Survey Report of Investigations No.163, 1953

  15. P. Kozakevitch, Viscosite et elements structuraux des aluminosilicates fondus: laitiers CaO-Al2O3-SiO2 entre 1600 et 2100 °C,, Rev. Metall., 57(1960), p.149.

    CAS  Google Scholar 

  16. K.C. Mills, L. Chapman, A.B. Fox, and S. Sridhar, ’Round robin’ project on the estimation of slag viscosities, Scand. J. Metall., 30(2001), p.396.

    Article  CAS  Google Scholar 

  17. N. Saito, N. Hori, K. Nakashima, and K. Mori, Viscosity of blast furnace type slags, Metall. Mater. Trans. B, 34(2003), p.509.

    Article  Google Scholar 

  18. A. Shankar, M. Görnerup, A.K. Lahiri, and S. Seetharaman, Experimental investigation of viscosities in CaO-SiO2-MgO-Al2O3 and CaO-SiO2-MgO-Al2O3-TiO2 slags, Metall. Mater. Trans. B, 38(2007), p.911.

    Article  Google Scholar 

  19. J.F. Stebbins and Z. Xu, NMR evidence for excess non-bridging oxygen in an aluminosilicate glass, Nature, 390(1997), p.60

    Article  CAS  Google Scholar 

  20. V.D. Eisenhüttenleute, Slag Atlas, Verlag Sthaleisen GmbH, Germany, 1995, P.6.

    Google Scholar 

  21. T. Nakamura, K. Morinaga, and T. Yanagase, The viscosity of the molten silicate containing TiO2, J. Jpn. Inst. Met., 41(1977), p.1300.

    CAS  Google Scholar 

  22. T. Yasukouchi, K. Nakashima, and K. Mori, Viscosity of ternary CaO-SiO2-Mx(F,O)y and CaO-Al2O3-Fe2O3 melts, Tetsu-to-Hagane, 85(1999), No.8, p.571.

    CAS  Google Scholar 

  23. A. Ohno and H.U. Ross, Optimum slag composition for the blast-furnace smelting of titaniferous ores, Can. Metall. Q., 1963, No.3, p.259.

  24. K.H. Sun, Fundamental condition of glass formation, J. Am. Ceram. Soc., 30(1947), No.9, p.227.

    Google Scholar 

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Correspondence to Xiao-jun Hu.

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The work was financially supported by the National Natural Science Foundation of China (No.51090384).

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Hu, Xj., Ren, Zs., Zhang, Gh. et al. A model for estimating the viscosity of blast furnace slags with optical basicity. Int J Miner Metall Mater 19, 1088–1092 (2012). https://doi.org/10.1007/s12613-012-0675-2

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  • DOI: https://doi.org/10.1007/s12613-012-0675-2

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