Skip to main content
SpringerLink
Log in

Structure of V2O5-P2O5-Sb2O3-Bi2O3 glass

  • Published:
International Journal of Minerals, Metallurgy, and Materials Aims and scope Submit manuscript

Abstract

The structure of V2O5-P2O5-Sb2O3-Bi2O3 glass and its state of crystallization were studied by means of infrared spectroscopy and X-ray diffraction analysis. The results indicate that, in this glass, V and P exist mainly in the form of a single-stranded linear (VO3) n and an isolated (PO4) tetrahedral with no double bond. Partial V and P are connected through O, forming an amorphous structure of layered vanadium phosphate. Trivalent Sb3+ and Bi3+ open the V=O bond and appear in interlayers, so a weak three-dimensional structure is connected successfully. Along with the substitution of Sb2O3 for partial V2O5 or that of P2O5 for partial V2O5, the network structure of the glass is reinforced, and the crystallization is reduced.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L.A. Yu, J.P. Du, M.F. Han, and S.P. Peng, Structure and sealing properties of Bi2O3-BaO-SiO2-RxOy glass, J. Univ. Sci. Technol. Beijing (in Chinese), 33(2011), No.12, p.1529.

    CAS  Google Scholar 

  2. A. Mierzejewski, G.A. Saunders, H.A.A. Sidek, and B. Bridge, Vibrational properties of samarium phosphate glasses, J. Non Cryst. Solids, 104(1988), p.323.

    Article  CAS  Google Scholar 

  3. A.X. Lu, J.W. Huang, and R.W. Lu, Structure of glasses and crystals in P2O5-PbO-Bi2O3 system, Chin. J. Nonferrous Met., 1997, No.1, p.88.

  4. V. Soghomonian, Q. Chen, R.C. Haushalter, C.J. O’Connor, C.H. Tao, and J. Zubieta, Hydrothermal syntheses and structural characterization of layered oxovanadium phosphate solids incorporating organic cations: [H2N(C4H8)NH2][(VO)4-(OH)4(PO4)2], [(NH3C3H6)NH(C2H4)2NH(C3H6NH3)][(VO)5-(OH)2(PO4)4]2H2O, [HN(C2H4)3NH]2[(VO)8(HPO4)3(PO4)4-(OH)2]2H2O, and [HN(C2H4)3NH][(VO)3(OH)2(PO4)2], Inorg. Chem., 34(1995), p.3509.

    Article  CAS  Google Scholar 

  5. T. Jermoumi, M. Hafid, and N. Toreis, Thermaland FTIR analysis of(50-x)BaO-xFe2O3-50P2O5 glasses, Phys. Chem. Glasses, 43(2002), No.3, p.129.

    CAS  Google Scholar 

  6. P. Subbalakshimi, P.S. Sastry, and N. Veeraiah, Dielectric relaxation and ac conduction phenomena in PbO-WO3-P2O5 glass system, Phys. Chem. Glasses, 42(2001), No.4–5, p.307.

    Google Scholar 

  7. E.E. Khawaja, S.M.A. Durrani, F.F. Al-Adel, M.A. Salim, and M.S. Hussain, X-ray photoelectron spectroscopy and Fourier transform-infrared studies of transition metal phosphate glasses, J. Mater. Sci., 30(1995), p.225.

    Article  CAS  Google Scholar 

  8. P.Y. Shih and T.S. Chin, Effect of redox state of copper on the properties of P2O5-Na2O-CuO glasses, Mater. Chem. Phys., 60(1999), p.50.

    Article  CAS  Google Scholar 

  9. C. Dayanand, G. Bhikshamaiah, V. Jaya Tyagaraju, M. Salagram, and A.S.R. Krishna Murthy, Structural investigations of phosphate glasses: a detailed infrared study of the x(PbO)-(1−x)P2O5 vitreous system, J. Mater. Sci., 31(1996), p.1945.

    Article  CAS  Google Scholar 

  10. M.R. Pai, B.N. Wani, A.D. Belapurkar, and N. M. Gupta, Role of substitution in catalytic activity of La-Th-V-O mixed oxides for the reaction of methanol, J. Mol. Catal. A, 223(2004), No.1–2, p.275.

    CAS  Google Scholar 

  11. S. Hayakawa, T. Yoko, and S. Sakka, IR and NMR structural studies on lead vanadate glasses, J. Non Cryst. Solids, 183(1995), No.1–2, p.73.

    Article  CAS  Google Scholar 

  12. L. Zan, J.S. Zhong, Q.R. Luo, and L. Huang, Study of new oxysulphied glasses from (Sb2O3)1−x (Sb2S3)x system, J. Funct. Mater., 30(1999), No.3, p.328.

    CAS  Google Scholar 

  13. J.J. Hudgens, R.K. Brow, D.R. Tallant, and S. W. Martin, Raman spectroscopy study of the structure of lithium and sodium ultraphosphate glasses, J. Non Cryst. Solids, 223(1998), No.1–2, p.21.

    Article  CAS  Google Scholar 

  14. A. Moguš-Milanković, M. Raji, A. Drašner, R. Trojko, and D.E. Day, Crystallisation of iron phosphate glasses, Phys. Chem. Glasses, 39(1998), No.2, p.70.

    Google Scholar 

  15. V.C. Famer, The Infrared Spectra of Minerals, Science Press, Beijing, 1982, p.305, 97, 319, 318.

    Google Scholar 

  16. L. Baia, R. Stefan, J. Popp, S. Simon, and W. Kiefer, Vibrational spectroscopy of highly iron doped B2O3-Bi2O3 glass systems, J. Non Cryst. Solids, 324(2003), No.1–2, p.109.

    Article  CAS  Google Scholar 

  17. M. Schindler, F.C. Hawthorne, and W.H. Baur, Crystal chemical aspects of vanadium: polyhedral geometries, characteristic bond valences, and polymerization of (VOn) polyhedra, Chem. Mater., 12(2000), No.5, p.1248.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. National Engineering Research Center for Rare Earth Materials, General Research Institute for Nonferrous Metals, and Grirem Advanced Materials Co., Ltd., Beijing, 100088, China

    Hong-yan Li, Feng-li Yang, Wei-dong Zhuang, Yun-sheng Hu & Xiao-fan Wen

  2. BOE Technology group Co., Ltd., Beijing, 100015, China

    Hong-yan Li

  3. Beijing Asahi Glass Electronics Co., Ltd., Beijing, 100015, China

    Zhi-liang Zhu

Authors
  1. Hong-yan Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zhi-liang Zhu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Feng-li Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Wei-dong Zhuang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yun-sheng Hu
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Xiao-fan Wen
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hong-yan Li.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Li, Hy., Zhu, Zl., Yang, Fl. et al. Structure of V2O5-P2O5-Sb2O3-Bi2O3 glass. Int J Miner Metall Mater 19, 628–635 (2012). https://doi.org/10.1007/s12613-012-0605-3

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12613-012-0605-3

Keywords

Search

Navigation