Skip to main content
Log in

NO x reduction by coupling combustion with recycling flue gas in iron ore sintering process

  • Published:
International Journal of Minerals, Metallurgy, and Materials Aims and scope Submit manuscript

Abstract

A new process called ‘NO x reduction by coupling combustion with recycling flue gas (RCCRF)’ was proposed to decrease NO x emission during the iron ore sintering process. The simulation test of NO x reduction was performed over sintered ore and in the process of coke combustion. Experimentally, NO x reduction was also carried out by sintering pot test. For sintered ore, the amount of NO x emission is reduced by 15wt%–25wt% at 400–550°C using 2.0vol% H2 or 2.0vol% CO, or reduced by 10wt%–30wt% at 560–720°C using 0.15vol% NH3. NO x reduction is around 10wt% by coupling combustion of pyrolysis gas and coke, or around 16wt% by recycling flue gas into coke combustion. By RCCRF, the maximum NO x reduction ratio is about 23wt% in coke combustion experiment and over 40wt% in sintering pot test.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Y.X. Su, Y.R. Mao, and Z. Xu, Technologies of Controlling NO x Emission during Coal Combustion, Chemical Industry Press, Beijing, 2005, p.11.

    Google Scholar 

  2. M. Fukutome, I. Hanamizu, T. Kodama, and N. TsuboiI, Sintering Method for Decreasing Nitrogen Oxide, Japanese Patent, 55014862(A), 1980-02-01.

  3. M.S. Lee and S.C. Shim, Influence of lime/limestone addition on the SO2 and NO formation during the combustion of coke pellet, ISIJ Int., 44(2004), No.3, p.470.

    Article  Google Scholar 

  4. C.L. Mo, C.S. Teo, I. Hamilton, and J. Morrison, Admixing hydrocarbons in raw mix to reduce NOx emission in iron ore sintering process, ISIJ Int., 37(1997), No.4, p.350.

    Article  Google Scholar 

  5. K. Morioka, S. Inaba, M. Shimizu, K. Ano, and T. Sugiyama, Primary application of the ‘In-bed-deNOx’ process using Ca-Fe oxides in iron ore sintering machines, ISIJ Int., 40(2000), No.3, p.280.

    Article  Google Scholar 

  6. C.G. Jin, H.G. Su, and L.J. Nam, SOx and NOx Reducing Method of Sintering Discharging Gas, Korean Patent, 20020040506(A), 2002-05-30.

  7. J.H. Li, G.W. Xu, L.D. Yang, et al., A Coal Combustion Method of Suppressing NO x Formation and Its Application on Coal Furnace, Chinese Patent, 95102081.1, 1995-10-25.

  8. A.N. Hayhurst and A.D. Lawrence, The reduction of the nitrogen oxides NO and N2O to molecular nitrogen in the presence of iron, its oxides and carbon monoxide in a hot fluidized bed, Combust. Flame, 110(1997), No.3, p.351.

    Article  Google Scholar 

  9. B. Olanders and D. Strömberg, Reduction of nitric oxide over magnesium oxide and dolomite at fluidized bed conditions, Energy Fuels, 9(1995), No.4, p.680.

    Article  Google Scholar 

  10. W. Wittler, K. Schütte, G. Rotzoll, and K. Schügerl, Heterogeneous reduction of nitric oxide by carbon monoxide on quartz surfaces, Fuel, 67(1988), No.3, p.438.

    Article  Google Scholar 

  11. G.J. Zijlma, A.D. Jensen, J.E. Johnsson, and C.M. van den Bleek, NH3 oxidation catalysed by calcined limestone: a kinetic study, Fuel, 81(2002), No.14, p.1871.

    Article  Google Scholar 

  12. T. Furusawa, M. Kyama, and M. Tsujimura, Nitric oxide reduction by carbon monoxide over calcined limestone enhanced by simultaneous sulphur retention, Fuel, 64(1985), No.3, p.413.

    Article  Google Scholar 

  13. J.D. He, W.L. Song, S.Q. Gao, et al., Experimental study of the reduction mechanisms of NO emission in decoupling combustion of coal, Fuel Process. Technol., 87(2006), No.9, p.803.

    Article  Google Scholar 

  14. T. Suzuki, T. Kyotani, and A. Tomita, Study on the carbon-nitric oxide reaction in the presence of oxygen, Ind. Eng. Chem. Res., 33(1994), No.11, p.2840.

    Article  Google Scholar 

  15. M.J. Illán-Gómez, A. Linares-Solano, C. Salinas-Martínez de Lecea, and J.M. Calo, NO reduction by activated carbons: 1. The role of carbon porosity and surface area, Energy Fuels, 7(1993), No.1, p.146.

    Article  Google Scholar 

  16. M.T. Izquierdo and B. Rubio, Influence of char physicochemical features on the flue gas nitric oxide reduction with chars, Environ. Sci. Technol., 32(1998), No.24, p.4017.

    Article  Google Scholar 

  17. C.K.S. Lai, W.A. Peters, and J.P. Longwell, Reduction of nitric oxide by coke over calcium oxide, Energy Fuels, 2(1988), No.4, p.586.

    Article  Google Scholar 

  18. H. Teng, Y.F. Hsu, and Y.T. Tu, Reduction of NO with NH3 over carbon catalysts: the influence of carbon surface structures and the global kinetics, Appl. Catal. B, 20(1999), No.2, p.145.

    Article  Google Scholar 

  19. Y.Q. Hu, N. Kobayashi, and M. Hasatani, The reduction of recycled-NOx in coal combustion with O2/recycled flue gas under low recycling ratio, Fuel, 80(2001), No.13, p.1851.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yan-guang Chen.

Additional information

This work was financially supported by the National Natural Science Foundation of China (No.50574085).

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chen, Yg., Guo, Zc. & Feng, Gs. NO x reduction by coupling combustion with recycling flue gas in iron ore sintering process. Int J Miner Metall Mater 18, 390–396 (2011). https://doi.org/10.1007/s12613-011-0452-7

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12613-011-0452-7

Keywords

Navigation