Abstract
The present paper deals with major and trace elements geochemistry of the groundwater from Nalgonda district, Telangana. The study area is very important in terms of anthropogenic activity like rapid industrial, urban development, pesticides, pharmaceutical, granite polishing and agro based industries. Inductively coupled plasma mass spectrometer (ICPMS) was employed to determine the concentration of trace elements in collected groundwater samples (bore well). These probe elements were further categorized as toxic elements (Pb, As, Cd, and V), alkaline earths (Sr and Ba), alkali metals (Li, Rb), transition metals (Cr, Mo and Ni), metallic elements (Cu, Fe, Zn, Al, Co), and other non-metallic elements (Se and Si). The groundwater quality was examined in perspective of Indian as well as World Health Organization drinking water standards. Based on the analytical results, groundwater in the study area is found to be slightly alkaline in nature and very hard, the average abundance of the major cations and anions is in the order of Ca+<Na+<Mg+<K+ and Cl-<HCO3 −<CO3 −<SO4 −<NO3 −<F– respectively. The dominant hydro chemical facies of groundwater is Na+ - HCO –3 – Cl– and Na+ - Cl– – HCO– 3 types.
The results of trace elements shows that concentration of Pb, As, Cd, V in collected samples exceeding the desirable limits, and in the case of alkaline, alkali, transition, non-metallic elements, seventy per cent of the samples crossed the desirable limits, but all metallic elements viz. Cu, Fe, Zn, Al, Co is within the limits as per Indian as well as World Health Organizations drinking water standards. Factor analysis results shows that seven factors emerged as a significant contributor to the groundwater contamination is about 65.32 per cent. The spatial variation maps decipher trace elemental concentrations both geogenic and anthropogenic origin, by three zones i.e. ‘low’, ‘moderate’ and ‘high’ of the study area based on environment using Arc-GIS. High concentrations of trace elements are indicative of phenomenal rise in chemical composition and likely to have its origin from silicate weathering reactions and dissolution/precipitation processes supported by rainfall and anthropogenic activities, indiscriminate use of fertilizers/pesticides, and disposal of waste and sewage, release of reactive pollutants into the atmosphere by industries. Hence, this work is of immense societal benefit in terms of prevailing human health hazards in the study area with a direct relevance to such industrially populated regions elsewhere.
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References
Abumrad, N.N., Schneider, A.J., Steel, D., Rogers, LS. (1981) Amino acid intolerance during prolonged total potential nutrition reversed by molybdate therapy. Is Jour. Clin. Nutr., v.34, pp. 2551–2559.
Agency for Toxic substances and Disease Registry (ATSDR) (2005) Toxicological Profile. Atlanta, GA: U.S. Department of Health and Human Services, Public Health Service.
Barzilay, J.I. (1999) The water we drink: Water quality and its effect on health, New Brunswick New Jersey, Rutgers University Press, 152p.
Bates, M.H. (1988) Land farming of reserve pit fluids and sludges: Fates of selected contaminants. Water Res., v.22, pp. 793–797.
BIS (2014) Bureau of Indian Standards, New Delhi, India.
Brindha et al. (2010) Natural and Anthropogenic influence on the Fluoride and Nitrate concentration of groundwater in parts of Nalgonda District, Andhra Pradesh, India Jour. Appld. Geochem., v.12(2), pp. 1–241.
Chapman, D. (1992) Water Quality Assessment: A Guide to the Use of Biota, Sediments and Water in Environmental Monitoring. Chapman and Hall, London, U.K.
Craig, E. and Anderson, M.P. (1979) The effect of urbanization on groundwater quality - a case study. Groundwater, v.17(5), pp.456–462.
Craun, G.F. (1990) Review of epidemiological studies of aluminum and neurological disorders. Environ. Geochem. Health, v.12, pp. 125–135.
Cherry, N.M., Burges, G.L., Turner, S. (1997) Cohort studies of Staffordshire pottery workers (II) nested casereference analysis of lung cancer. Ann. Occup. Hyg., v.41 (Suppl. 1), pp. 408–411
Cherry, N.M., Burge, G.L., Turner, S., McDonald, J.C. (1998) Crystalline silica and risk of lung cancer in the potteries. Jour. Occup. Environ. Medic., v.58, pp. 779–785.
Cui, Y., Zhu, Y. G., Zhai, R., Huang, Y., Qiu, Y. and Liang, J. (2005) Exposure to metal mixtures and human health impacts in a contaminated area in Nanning, China. Environ.t Internat., v.31, pp. 784–790.
Dart, F.J. (1974) “The Hazard of Iron, “Water and Pollution Control, Ottawa.
Epstein, S.G. (1990) Human exposure to aluminum, Environ. Geochem. Health, v.12, pp. 65–70.
Flaten, T.P. (1990) Geographical associations between aluminum in drinking water and death rates with dementia (including Alzheimer’s disease), Parkinson’s disease and amyotrophic lateral sclerosis in Norway. Environ. Geochem. Health, v.12, pp. 152–167.
Freeze, R.A. and Cherry, J.A. (1979) Groundwater. Prentice Hall, Englewood Cliffs, Geneva, pp.130.
Goel, P.K. (1997) Water Pollution causes effect and control, New Age International Publishers, p.269.
Greve K, Nielsen E, Ladefoged O (2007) Evaluation of health hazards by exposure to strontium in drinking water. Toxicol. Lett., v.172(1-7), pp.S210.
GSI (1995) Geological Survey of India’s geology and minerals map of Nalgonda district, Andhra Pradesh, India.
Hem, J.D. (1985) Study and interpretation of the chemical characteristics of natural waters (3d ed.): USGS Water-Supply Paper 2254, 26 p.
ICMR (2003) Manual of Standards of Quality of Drinking Water Supplies. Indian Council of Medical Research, New Delhi.
Jansen, N., Hartmann, J., Lauerwald, R., Dürr, H.H., Kempe, S., Loos, S. and Middelkoop, H., (2010) Dissolved Silica mobilization in the Conterminous USA. Chemical Geol., v.270(14), pp. 90–109.
Johnson, J.L. et al. (1980) Inborn errors of molybdenum metabolism: combined deficiencies of sulfite oxidase and xanthine dehydrogenize in a patient lacking the Molybdenum cofactor. Proc. Natl. Acad.f Sci., v.7, pp. 3715–3719.
Karanth, K.R. (1987) Groundwater Assessment, Development and Management, Tata McGraw Hills Publication Company Limited. New Delhi.
Khan M.Q.M.A., Umar, R, Latch, H. (2010) Study of trace elements in groundwater of Uttar Pradesh, India. Sci. Res. Essays, v.5(20), pp. 3175–3182.
Khan, M.M.A. and Umar, R. (2010) Significance of silica analysis in groundwater in parts of Central Ganga Plain, Uttar Pradesh, India. Curr. Sci., v.98(9), pp. 1237–1240.
Kumar G (2005) Geology of Uttar Pradesh and Uttaranchal. Geological Society of India, Bangalore, pp. 267–291.
Khan, K., Lu, Y., Khan, H., Ishtiaq, M., Khan, S., Waqas, M., Wei, L. and Wang, T. (2013) Heavy metals in agricultural soils and crops and their health risks in Swat District, northern Pakistan. Food Chemistry and Toxicology, v.58, pp. 449–458.
Kanungo, D.N., Rama Rao, P., Murthy, D.S.N. anf Ramana Rao, A.V. (1975) Structural features of granites around Hyderabad, Andhra Pradesh. Geophys. Res. Bull., v.13(3–4), pp. 337–357.
Krishna, A.K. and Govil, P.K. (2004) Heavy metal contamination of soil around Pal. Industrial area, Rajasthan, India. Environ. Geol., v.47, pp. 38–44.
Lagas, P., Loch, J.P.G. and Bom, C.M. (1984) The behavior of barium in landfill and the underlying soil. Water, Air, Soil Pollute, v.22, pp. 121–129.
Lall, U. and Sharma, A. (1996) A nearest neighbor bootstrap for re-sampling hydrologic time series, Water Resour. Res., v.32(3), pp. 679–694.
Langaneger, O. (1987) Groundwater quality an important factor for selecting hand pumps, BP1850, 01 Abidjan, Cote d’Ivoire.
Moore, C.V. (1973). Iron: Modern nutrition in health and disease, Philadelphia. Lea and Fiibeger, p.297.
National Academy of Sciences (1989) Recommended dietary allowances, 10th ed. Washington, DC, National Academy Press, pp. 243–246. 284.
Negrel, P., Petelet-Graud, E. and Widory, D. (2004) Strontium isotope geochemistry of alluvial groundwater: a tracer for groundwater resources characterization. Hydrol. Earth Syst. Sci., v.8(5), pp. 959–972.
Pandey, O.P., Agrawal, P.K. and Chetty, T.R.K. (2002) Unusual Lithospheric structure beneath the Hyderabad granitic region, eastern Dharwar craton, south India. Physics Earth Planet. Inter., v.30, pp.59–69.
Rantsman, E. Ya, Chetty, T. R. K., Rao, M. N., Glasko, M.P., Zhidkov, M. P. and Gorshkov, A.I. (1995) Explanatory broacher map of Morphostructural zoning of the Himalayan belt, Himalayan fore-deep and the Indian shield (Vol. 29). New Delhi, India/Moscow, Russia: DST/Russian Academy of Sciences.
Robards, M. and Worsfold, P. (1991) Cadmium toxicology and analysis - A review. Analyst, v.116, pp. 549–560.
Singh, K.P. and Bhayana, N. (1986) Geochemistry of groundwater of Ludhiana area, Punjab with special reference to its use for India. Geol. Cong., pp. 579–594.
Sitaramayya, S. (1971) The pyroxene-bearing grandiosities and granites of Hyderabad area (the Osmania granite). Quart. Jour. Geol. Min. Metall. Soc. India, v.43, pp. 117–129.
Soares, H.M.V.M., Boaventura, R.A.R., Machado, A.A.S.C. and Esteves Da Silva, J.C.G. (1999) Sediments as Monitors of Heavy Metal Contamination in the Ave River Basin (Portugal): Multivariate Analysis of Data. Environmental Pollution, v.10(3), pp. 311–323.
Tiwari, R.N. and Dubey, D.P. (2013) A study of Bauxite deposit of Tikar Plateau Rewa district, M.P. Gond. Geol. Soc. Spec. vol.13, pp. 111–118.
Todd, D.K. (1980) Groundwater, Hydrology, 2nd Edition, John Willey and Sons, pp. 267–315.
U.S. Environmental Protection Agency (1976) Quality criteria for water: Washington, D.C., U.S. Environmental Protection Agency, 256p.
Van Zinderen Bakker, E.M. and Jaworski, J.F. (1980) Effects of vanadium in the Canadian environment. National Research Council of Canada, Associate Committee on Scientific Criteria for Environmental Quality, Subcommittee on Heavy Metals and Certain Other Compounds. NRCC No.18132.
Vigneswaran, S. and Viswanathan, C. (1995) Water treatment process: Simple options, New York: CRC, 11p.
Yang, H. and Rose, N. (2005) Trace Element Pollution Records in Some UKLake Sediments, Their History, Influence Factors and Regional Differences. Environment International, v.31(1), pp. 63–75.
World Health Organization (WHO) (2011) Guidelines for drinking water quality, Fourth edition, v.1. Recommendations, WHO, Geneva Zaporozec.
Zhao, Q., Wang, Y., Cao, Y., Chen, A., Ren, M., Ge, Y., Yu, Z., Wan, S., Hu, A., Bo, Q., Ruan, L., Chen, H., Qin, S., Chen, W., Hu, C., Tao, F., Xu, D., Xu, J., Wen, L. and Li, L. (2014) Potential health risks of heavy metals in cultivated top soil and grain, including correlations with human primary liver, lung and gastric cancer, in Anhui province, Eastern China. Science of the Total Environment, v.470–471, pp. 340–347.
Zheng, N., Wang, Q., Zhang, X., Zheng, D., Zhang, Z. and Zhang, S. (2007) Population health risk due to dietary intake of heavy metals in the industrial area of Huludao City, China. Science of the Total Environment, v.387, pp.96–104.
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Purushotham, D., Linga, D., Sagar, N. et al. Groundwater contamination in parts of Nalgonda district, Telangana, India as revealed by trace elemental studies. J Geol Soc India 90, 447–458 (2017). https://doi.org/10.1007/s12594-017-0738-0
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DOI: https://doi.org/10.1007/s12594-017-0738-0