Vertical variation in groundwater chemistry of Penna-Chitravathi river basin in Southern India

Abstract

Study on geochemistry of groundwater occurring at different depths is rarely attempted due to inherent difficulties in sample isolation and lack of significant species variations. Three-dimensional (spatial, temporal and depth-wise) evaluation of water chemistry variations would give holistic picture of aquatic chemistry. In order to fill the knowledge gap the vertical hydrogeochemistry of Penna-Chitravati inter-stream sub-basin is studied.Water samples are segregated into different groups based on water levels of source wells. The group samples pertaining to granite terrain (A to C) does not show much variation for tested parameters as most of the samples fall within 20m water level. In shale aquifers groundwater is progressively less ionized as depth to levels increases (Group D to G). Reduction of EC and Na-Cl along with falling water levels indicates deeper aquifers are free from contamination. Gradual decrease in HCO ^-₃ with depth substantiates that deeper aquifers are getting less fresh water due to lack of inter connectivity in shale formations. Sodium in groundwater of both the granite and shale aquifers is contributed by weathering of silicate rocks as the Na⁺/Cl^- molar ratio is >1 in many samples. Majority of the samples in both the geological terrains have Ca²⁺/Mg²⁺ ratio between 1 to < 2 indicating dolomite dissolution is responsible for Ca²⁺-Mg²⁺ contribution. The chemistry of tested water indicate aquifer matrix is responsible for chemical make-up of pore water which was obliterated due to extraneous sources like anthropogenic contamination as Na⁺, Cl^-, NO ^-₃ and SO ^2-₄ /HCO ^-₃ is high in many samples belonging to shallow aquifers. Thermodynamic action in deep aquifers could be responsible for dissimilar water chemistry in aquifers belonging to same geological domain.