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Risk assessment of metals from groundwater in northeast Rajasthan

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Journal of the Geological Society of India

Abstract

The present study was conducted to investigate trace metal (Li, Be, B, Al, Cr, Mn, Fe, Co, Ni, Cu, Zn, As Se, Mo, Cd, Sb, Ba and Pb) concentrations of drinking water samples in northeast Rajasthan, India. Furthermore, the study aimed to ascertain carcinogenic and non-carcinogenic health risks of metals by ingestion and dermal absorption pathways to the local residents. Metal concentrations were analyzed by using high resolution inductively coupled plasma mass spectrometry and compared with permissible limits set by the Bureau of Indian Standards, United States Environmental Protection Agency and World Health Organization. The results indicate that the concentrations of Be, B, Al, Cr, Fe, Cu, Zn, As, Mo, Sb and Ba were lower than their respective permissible limits, whereas the concentrations of Mn, Ni, Se, Cd and Pb in some samples were higher than their permissible limits.The total hazard index (summing the hazard index through ingestion and dermal routes) at all the sampling sites exceeded or nearing unity, indicating the presence of non-carcinogenic health effects from ingestion of water and dermal contact with water. The results indicate that the total excess lifetime cancer risk (considering both ingestion and dermal exposure pathways) of metals exposure was in accordance to the acceptable lifetime risks for carcinogens in drinking water (10-6–10-4). Both carcinogenic and non-carcinogenic risks were mainly attributed to the ingestion pathways.

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References

  • Agency for Toxic Substances and Disease Registry (ATSDR) (2012) Toxicological Profile for Cadmium, Atlanta, GA: U.S. Department of Public Health and Human Services, Public Health Service.

    Google Scholar 

  • Agency for Toxic Substances and Disease Registry (ATSDR) (2005) Toxicological Profile for Nickel, Atlanta, GA: U.S. Department of Public Health and Human Services, Public Health Service.

    Google Scholar 

  • BIS, IS: 10500(1993) Standards for Drinking water, Bureau of Indian Standards, New Delhi.

    Google Scholar 

  • BIS (2012) Drinking Water–Specification, Second Revision, Bureau of Indian Standards, New Delhi.

    Google Scholar 

  • Donaldson, S.G., Van Oostdam, J., Tikhonov, C., Feeley, M., Armsstrong, B., Ayotte, P., Boucher, O., Bowers, W., Chan, L., Dallaire, F., Dallaire, R., Dewailly, É., Edwards, J., Egeland, G.M., Fontaine, J., Furgal, C., Leech, T., Loring, E., Muckle, G., Nancarrow, T., Pereg, D., Plusquellec, P., Potyrala, M., Receveur, O. and Shearer, R.G. (2010) Environmental contaminants and human health in the Canadian Arctic. Sci. Total Environ., v.408, pp.5165–5234.

    Article  Google Scholar 

  • Duggal, V., Mehra, R. and Rani, A. (2013) Determination of 222RN level in groundwater using a RAD7 detector in the Bathinda district of Punjab, India. Radiat. Prot. Dosim., v.156, pp.239–245.

    Article  Google Scholar 

  • Frisbie, S.H., Ortega, R., Maynard, D.M. and Sarkar, B. (2002) The concentrations of arsenic and other toxic elements in Bangladesh’s drinking water. Environ. Health Prespect., v.110, pp.1147–1153.

    Article  Google Scholar 

  • Giri, S., Mahato, M.K., Singh, G. and Jha, V.N. (2012) Risk assessment due to intake of heavy metals through the ingestion of groundwater around two proposed uranium mining areas in Jharkhand, India. Environ. Monit. Assess., v.184, pp.1351–1358.

    Article  Google Scholar 

  • Harries, S., and Harper, B. (2004) Exposure Scenario for CTUIR traditional Subsistence Lifeways, Confederated Tribes of the Umatilla Indian Reservation, Department of Science and Engineering, Pendleton, Oregon.

    Google Scholar 

  • Iqbal, J., Shah, M.H. and Akhter, G. (2013) Characterization, source apportionment and health risk assessment of trace metals in freshwater Rawal Lake, Pakistan. Jour. Geochem. Explor., v.125, pp.94–101.

    Article  Google Scholar 

  • Islam, Md.S., Ahmed, Md.K., Raknuzzaman, M., Habibullah-Al-Mamun, Md. and Islam, M.K. (2015) Heavy metal pollution in surface water and sediment: A preliminary assessment of an urban river in a developing country. Ecol. Indic., v.48, pp.282–291.

    Article  Google Scholar 

  • Krishna, A.K., Satyanarayanan, M. and Govil, P.K. (2009) Assessment of heavy metal pollution in water using multivariate statistical techniques in an industrial area: a case study from Patancheru, Medak District, Andhra Pradesh, India. Jour. Hazard. Material, v.167, pp.366–373.

    Article  Google Scholar 

  • Kumar, A., Vij, R., Gupta, M., Sharma, S. and Singh, S. (2015) Risk assessment of exposure to radon concentration and heavy metal analysis in drinking water samples in some areas of Jammu & Kashmir, India. Jour. Radioanal. Nucl. Chem., v.304, pp.1009–1016.

    Article  Google Scholar 

  • Kumar, T.B.P., Tiwary, A. and Fahmi, S. (2009) Nature of uranium mineralization in the Kerpura-Tiwari-ka-Bas Area, Sikar district, Rajasthan. Jour. Geol. Soc. India, v.73, pp.220–228.

    Article  Google Scholar 

  • Li, S. and Zhang, Q. (2010) Risk assessment and seasonal variations of dissolved trace elements and heavy metals in the Upper Han River, China. Jour. Hazard. Material, v.181, pp.1051–1058.

    Article  Google Scholar 

  • Miguel, E.De., Iribarren, I., Chacon, E., Ordonez, A. and Charlesworth, S. (2007) Risk-Based evaluation of the exposure of children to trace elements in playgrounds in Madrid (Spain). Chemosphere, v.66, pp.505–513.

    Article  Google Scholar 

  • Muhammad, S., Tahir Shah, M. and Khan, S. (2011) Health risk assessment of heavy metals and their source apportionment in drinking water of Kohistan region, northern Pakistan. Microchem. Jour., v.98, pp.334–343.

    Article  Google Scholar 

  • Ni, T., Diao, W., Xu, J. and Liu, N. (2011) Non-carcinogenic risk assessment of eight metals in the sourcegroundwater of Shaying River Basin. Ecotoxicology, v.20, pp.1117–1123.

    Article  Google Scholar 

  • Rani, A., Mehra, R., Duggal, V. and Balaram, V. (2013) Analysis of uranium concentration in drinking water samples using ICPMS. Health Phys., v.104, pp.251–255.

    Article  Google Scholar 

  • Rodell, M., Velicogna, I. and Famiglietti, J.S. (2009) Satellite-based estimates of groundwater depletion in India. Nature, v.460, pp.999–1002.

    Article  Google Scholar 

  • Rodriguez-Proteau, R. and Grant, R.L. (2005) Toxicity evaluation and human health risk assessment of surface and ground water contaminated by recycled hazardous waste materials. Handbook Environ. Chem., v.2, pp.133–189.

    Google Scholar 

  • Sridhar, R., Thangaradjou, T., Sentnil, S.K. and Kannan L. (2006) Water quality and phytoplankton characteristics in the Palk Bay, Southeast coast of India. Jour. Environ. Biol., v.27, pp.561–566.

    Google Scholar 

  • USDOE (2011) The Risk Assessment Information System (RAIS), U.S. Department of Energy’s Oak Ridge Operations Office (ORO), Washington, DC, USA.

    Google Scholar 

  • US EPA (1989) Risk Assessment Guidance for Superfund Volume I: Human Health Evaluation Manual (Part A) Interim Final. EPA/540/1-89/002. U.S. Environmental Protection Agency, Office of Emergency and Remedial Response, Washington, DC, USA.

    Google Scholar 

  • US EPA (1996) Quantitative Uncertainty Analysis of Superfund Residential Risk Pathway Models for Soil and Groundwater: White Paper. Office of Health and Environmental Assessment, Oak Ridge, TN, USA.

    Google Scholar 

  • US EPA (1997) Exposure factors handbook. Office of research and development. EPA/600/P-95/002Fa. U.S. Environmental Protection Agency, Washington, DC.

    Google Scholar 

  • US EPA (2001) Risk Assessment Guidance for Superfund: Volume III: Part A, process for conducting probabilistic risk assessment. EPA 540-R-02-002. Office of Emergency and Remedial Response. U.S. Environmental Protection Agency, Washington, DC.

    Google Scholar 

  • US EPA (2004) Risk Assessment Guidance for Superfund Volume 1: Human health Evaluation Manual (Part E, Supplemental Guidance for Dermal Risk Assessment) Final. EPA/540/R/99/005 OSWER 9285.7-02EP PB99-963312 July 2004, Office of Superfund Remediation and Technology Innovation U.S. Environmental Protection Agency Washington, DC.

    Google Scholar 

  • US EPA (2011) Edition of the Drinking Water Standards and Health Advisories, EPA 820-R-11-002, Office of Water, U.S. Environmental Protection AgencyWashington, DC.

    Google Scholar 

  • WHO (1996) Guidelines for Drinking-water Quality, vol. 2, Health Criteria and Other Supporting Information, Second ed., Geneva, Switzerland.

    Google Scholar 

  • WHO (2004) Guidelines for Drinking-water Quality, Third ed., Recommendations, vol.1, World Health Organization, Geneva, Switzerland.

    Google Scholar 

  • WHO (2008) Guidelines for Drinking-water Quality, Third ed., Incorporating the first and second addenda, Recommendations, vol.1, World Health Organization, Geneva, Switzerland.

    Google Scholar 

  • WHO (2011) Guidelines for Drinking-water Quality, Fourth ed., Recommendations, vol.1, World Health Organization, Geneva, Switzerland.

    Google Scholar 

  • Wu, B., Zhao, D., Jia, H., Zhang, Y., Zhang, X. and Cheng, S. (2009) Preliminary risk assessment of trace metal pollution in surface water from Yangtze River in Nanjing Section, China. Bull. Environ. Contam. Toxicol. v.82, pp.405–409.

    Google Scholar 

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Correspondence to Vikas Duggal.

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Duggal, V., Rani, A., Mehra, R. et al. Risk assessment of metals from groundwater in northeast Rajasthan. J Geol Soc India 90, 77–84 (2017). https://doi.org/10.1007/s12594-017-0666-z

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  • DOI: https://doi.org/10.1007/s12594-017-0666-z

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