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Paired δ13Ccarb13Corg Evolution of the Dengying Formation from Northeastern Guizhou and Implications for Stratigraphic Correlation and the Late Ediacaran Carbon Cycle

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Abstract

This study provides δ13C profiles from a lower-slope (Well ZK102) to basin (Bahuang Section) environment to better understand the temporal and spatial variability in δ13Ccarb13Corg of the Yangtze Block during the Late Ediacaran. Our new δ13C profiles together with the reported data suggest that the Upper Ediacaran successions from different depositional environments are generally bounded by negative δ13Ccarb and/or δ13Corg excursions in the underlying and overlying strata. Moreover, the Upper Ediacaran δ13Ccarb profiles generally can be subdivided into two positive excursions and an interjacent negative excursion, whereas the paired δ13Corg profiles from different depositional environments have individual variation trends. On the other hand, these data show a large surface-to-deep water δ13C gradient (~5‰ variation in δ13Ccarb, >10‰ variation in δ13Corg) which can be reasonably explained by the heterogeneity of the biological activities in the redox-stratified water column. Furthermore, the decoupled δ13Ccarb13Corg pattern with large δ13Corg perturbations at the lower slope precluded the existence of a large dissolved organic carbon reservoir at the Yangtze Block during the Late Ediacaran. Thus, the high δ13Ccarb values in the Upper Ediacaran succession could be balanced by large amounts of buried organic carbon likely associated with high productivity.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 41472089, U1663209), and the Open Research Fund Program of Hunan Provincial Key Laboratory of Shale Gas Resource Utilization, Hunan University of Science and Technology. We would like to thank Wennian Han and Hongwei Li for carbon and oxygen isotope analysis at the Laboratory for Stable Isotope Geochemistry, Institute of Geology and Geophysics, Chinese Academy of Sciences. The final publication is available at Springer via https://doi.org/10.1007/s12583-018-0886-1.

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Ding, Y., Chen, D., Zhou, X. et al. Paired δ13Ccarb13Corg Evolution of the Dengying Formation from Northeastern Guizhou and Implications for Stratigraphic Correlation and the Late Ediacaran Carbon Cycle. J. Earth Sci. 31, 342–353 (2020). https://doi.org/10.1007/s12583-018-0886-1

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