Skip to main content
SpringerLink
Log in

Oxidation Behaviors of Si/Al Pack Cementation Coated Mo–3Si–1B Alloys at Various Temperatures

  • Published:
Metals and Materials International Aims and scope Submit manuscript

Abstract

In this study, we tried to improve the oxidation resistance of Mo–3Si–1B (wt%) alloy at intermediate (800 °C) and high temperature (1300 °C) after applying Si/Al pack cementation coatings. In addition, we examined structural changes and phase change in the intermediate and high temperature oxidizing atmospheres to observe oxidation behaviors. The diffusion pack coatings were carried out with an NH4F activator and both Si and Al powder mixtures. Mo–Si–B alloys were subjected to diffusion coatings of Si/Al powders at various temperatures in various time conditions at a temperature of 1100 °C. When the pack coatings were carried out for 48 h, Mo(Si, Al)2 and Mo3Al8 layers together with a T2 (Mo5SiB2) layer were successfully synthesized on the substrate. After oxidation tests, an Al2O3 protective oxide layer was formed by the diffusion of Al in an ambient atmosphere. The Si/Al pack cementation coatings provided excellent oxidation resistance through the formation of an Al2O3 oxide layer. The enhanced oxidation behaviors are discussed in terms of microstructural evolution at high temperatures.

Graphic Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Z. Tang, A.J. Thom, M.J. Kramer, M. Akinc, Intermetallics 16, 1125 (2008)

    CAS  Google Scholar 

  2. J.-C. Zhao, J.H. Westbrook, MRS Bull. 28, 622 (2003)

    CAS  Google Scholar 

  3. M. Yamaguchi, H. Inui, K. Ito, Acta Mater. 48, 307 (2000)

    CAS  Google Scholar 

  4. X. Chen, D. Gao, J.X. Hu, Y. Liu, C.P. Tang, Met. Mater. Int. 25, 1135 (2019)

    CAS  Google Scholar 

  5. V. Behrani, A.J. Thom, M.J. Kramer, M. Akinc, Intermetallics 14, 24 (2006)

    CAS  Google Scholar 

  6. J. Cheng, S. Yi, J.S. Park, Intermetallics 23, 12 (2012)

    CAS  Google Scholar 

  7. F. Rioult, N. Sekido, R. Sakidja, J.H. Perepezko, J. Elctrochem. Soc. 154(11), C692 (2007)

    CAS  Google Scholar 

  8. O.N. Senkov, G.B. Wilks, J.M. Scott, D.B. Miracle, Intermetallics 19, 698 (2011)

    CAS  Google Scholar 

  9. O.N. Senkov, J.K. Jensen, A.L. Pilchak, D.B. Miracle, H.L. Fraser, Mater. Des. 139, 498 (2018)

    CAS  Google Scholar 

  10. M.G. Mendiratta, T.A. Parthasarathy, D.M. Dimiduk, Intermetallics 10, 225 (2002)

    CAS  Google Scholar 

  11. J.H. Perepezko, Science 326, 1068 (2009)

    CAS  Google Scholar 

  12. G. Song, S.J. Hong, J.K. Lee, S.H. Song, S.H. Hong, K.B. Kim, P.K. Liaw, Scr. Mater. 161, 18 (2019)

    CAS  Google Scholar 

  13. E. Jumaev, S.H. Hong, J.T. Kim, H.J. Park, Y.S. Kim, S.C. Mun, J.Y. Park, G. Song, J.K. Lee, B.H. Min, T. Lee, K.B. Kim, J. Alloys Compd. 777, 828 (2019)

    CAS  Google Scholar 

  14. I. Grammenos, P. Tsakiropoulos, Intermetallics 18, 242 (2010)

    CAS  Google Scholar 

  15. I. Grammenos, P. Tsakiropoulos, Intermetallics 19, 1612 (2011)

    CAS  Google Scholar 

  16. S. Mathieu, S. Knittel, P. Berthod, S. Mathieu, M. Vilasi, Corros. Sci. 60, 181 (2012)

    CAS  Google Scholar 

  17. K. Ito, K. Ihara, K. Tanaka, M. Fujikura, M. Yamaguchi, Intermetallics 9, 591 (2001)

    CAS  Google Scholar 

  18. J.H. Schneibel, M.J. Kramer, D.S. Easton, Scr. Mater. 46, 217 (2002)

    CAS  Google Scholar 

  19. K. Yoshimi, S. Nakatani, N. Nomura, S. Hanada, Intermetallics 11, 787 (2003)

    CAS  Google Scholar 

  20. A.P. Alur, K.S. Kumar, Acta Mater. 54, 385 (2006)

    CAS  Google Scholar 

  21. V. Supatarawanich, D.R. Johnson, C.T. Liu, Mater. Sci. Eng. A 344, 328 (2003)

    Google Scholar 

  22. V. Supatarawanich, D.R. Johnson, C.T. Liu, Intermetallics 12, 721 (2004)

    CAS  Google Scholar 

  23. P. Jain, A.P. Alur, K.S. Kumar, Scr. Mater. 54, 13 (2006)

    CAS  Google Scholar 

  24. T.J. Nijdam, W.G. Sloof, Acta Mater. 55, 5980 (2007)

    CAS  Google Scholar 

  25. M. Krüger, S. Franz, H. Saage, M. Heilmaier, J.H. Schneibel, P. Jèhanno, M. Böning, H. Kestler, Intermetallics 16, 933 (2008)

    Google Scholar 

  26. F.A. Rioult, S.D. Imhoff, R. Sakidja, J.H. Perepezko, Acta Mater. 57, 4600 (2009)

    CAS  Google Scholar 

  27. K. Choi, W. Yang, K.-H. Baik, Y. Kim, S. Lee, S. Lee, J.S. Park, Appl. Surf. Sci. 489, 668 (2019)

    CAS  Google Scholar 

  28. C.L. Fu, J.H. Schneibel, Acta Mater. 51, 5083 (2003)

    CAS  Google Scholar 

  29. Z. Li, L.M. Peng, Mater. Lett. 62, 2229 (2008)

    CAS  Google Scholar 

  30. D.M. Dimiduk, J.H. Perepezko, MRS Bull. 28, 639 (2003)

    CAS  Google Scholar 

  31. R. Sakidja, J.S. Park, J. Hamann, J.H. Perepezko, Scr. Mater. 53, 723 (2005)

    CAS  Google Scholar 

  32. B. Roy, J. Das, R. Mitra, Corros. Sci. 68, 231 (2013)

    CAS  Google Scholar 

  33. M.K. Meyer, A.J. Thom, M. Akinc, Intermetallics 7, 15 (1999)

    Google Scholar 

  34. S. Majumdar, B. Donges, B. Gorr, H.-J. Christ, D. Schliephake, M. Heilmaier, Corros. Sci. 90, 76 (2015)

    CAS  Google Scholar 

  35. K. Choi, Y.J. Kim, M.K. Kim, M.K. Kim, S. Lee, S. Lee, J.S. Park, Coatings 8(6), 218 (2018)

    Google Scholar 

  36. S. Majumdar, B. Gorr, H.-J. Christ, D. Schliephake, M. Heilmaier, Corros. Sci. 88, 36 (2014)

    Google Scholar 

  37. Z. Guo-jun, K. Hao, D. Qian, L. Gang, S. Jun, Int. J. Refract. Met. Hard Mater. 30, 6 (2012)

    Google Scholar 

  38. T. Sossaman, R. Sakidja, J.H. Perepezko, Scr. Mater. 67, 891 (2012)

    CAS  Google Scholar 

  39. T. Sossaman, J.H. Perepezko, Corros. Sci. 98, 406 (2015)

    CAS  Google Scholar 

  40. J. Das, B. Roy, N.K. Kumar, R. Mitra, Intermetallics 83, 101 (2017)

    CAS  Google Scholar 

  41. J.H. Perepezko, R. Sakidja, JOM 62, 13 (2010)

    CAS  Google Scholar 

  42. D. Schliephake, C. Gombola, A. Kauffmann, M. Heilmaier, J.H. Perepezko, Oxid. Met. 88, 267 (2017)

    CAS  Google Scholar 

  43. R. Sakidja, F. Rioult, J. Werner, J.H. Perepezko, Scr. Mater. 55, 903 (2006)

    CAS  Google Scholar 

  44. X. Tian, X. Guo, Z. Sun, M. Li, L. Wang, J. Rare Earths 34, 952 (2016)

    CAS  Google Scholar 

  45. S. Majumdar, I.G. Sharma, Intermetallics 19, 541 (2011)

    CAS  Google Scholar 

  46. P. Zhang, X. Guo, C. Zhang, Q. Tao, C. Shen, Int. J. Refract. Met. Hard Mater. 67, 32 (2017)

    CAS  Google Scholar 

Download references

Acknowledgements

Financial support from Agency for Defense Development (ADD) of Republic of Korea is gratefully acknowledged. Additionally, Joon Sik Park appreciates financial support from the Basic Science Research Program through the National Research Foundation of the Republic of Korea (NRF) funded by the Ministry of Education, Science and Technology (Contract No. 2016R1D1A1A0991905).

Author information

Authors and Affiliations

  1. Department of Materials Science and Engineering, Hanbat National University, Daejeon, 34158, Republic of Korea

    Wonchul Yang, Kwangsu Choi, Jeongmin Kim, Jongwon Lee & Joon Sik Park

  2. R&D Center, Chunji Co. Ltd., Yeoju, 12663, Republic of Korea

    Kwangsu Choi

  3. Department of Materials Science and Engineering, Chungnam National University, Daejeon, 34134, Republic of Korea

    Kyeong-Ho Baik

  4. Agency for Defense Development, Daejeon, 34186, Republic of Korea

    Youngmoo Kim & Seong Lee

Authors
  1. Wonchul Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Kwangsu Choi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Kyeong-Ho Baik
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Youngmoo Kim
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Seong Lee
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Jeongmin Kim
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Jongwon Lee
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Joon Sik Park
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Joon Sik Park.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yang, W., Choi, K., Baik, KH. et al. Oxidation Behaviors of Si/Al Pack Cementation Coated Mo–3Si–1B Alloys at Various Temperatures. Met. Mater. Int. 27, 914–921 (2021). https://doi.org/10.1007/s12540-019-00471-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12540-019-00471-4

Keywords

Search

Navigation